Differentiation of Romanian Wines on Geographical Origin and Wine Variety by Elemental Composition and Phenolic Components

Food Analytical Methods - Tập 7 - Trang 2064-2074 - 2014
Elisabeta Irina Geana1,2, Adrian Marinescu1, Andreea Maria Iordache1, Claudia Sandru1, Roxana Elena Ionete1, Camelia Bala2
1National R&D Institute for Cryogenics and Isotopic Technologies, Valcea, Romania
2Department of Analytical Chemistry, University of Bucharest, Bucharest, Romania

Tóm tắt

Several wines were analyzed by high-performance liquid chromatography (HPLC-PDA), inductively coupled plasma mass spectrometry (ICP-MS), and flame atomic absorption spectroscopy (FAAS) in order to associate the concentration levels of the chemical parameters with the geographical origin of wines and wine varieties. Thus, the concentrations of 22 elements (Li, Be, Co, Ni, Cs, U, Pb, V, As, Ba, Cr, Cu, Zn, Al, Mn, Rb, Sr, Fe, Ca, Mg, Na, and K) and seven phenolic compounds (gallic acid, (+)-catechin, (−)-epicatechin, p-coumaric acid, ferulic acid, trans-cinnamic acid, and resveratrol) were analyzed in 22 wines from two different wine-producing areas of Romania. Among the phenolic compounds, (+)-catechin, (−)-epicatechin, p-coumaric acid, ferulic acid, and resveratrol concentrations were the most useful markers for wine differentiation by geographical origin and wine variety, whereas Ba, Be, Cr, Cs, Li, Mg, Na, Ni, Sr, U, and Zn were the main inorganic parameters selected. To explore the distribution pattern of the samples, aimed at differentiating the wine samples by geographical region and wine variety, principal component analysis (PCA) was applied to the obtained data.

Tài liệu tham khảo

Commission Regulation (EC) no 606/2009 laying down certain detailed rules for implementing Council Regulation (EC) no 479/2008 as regards the categories of grapevine products, oenological practices and the applicable restrictions (2009). Official Journal L 193, P. 0001 - 0059

Geana EI, Ionete RI, Tudorache A, Pasa A, Postolache E, Ranca A (2011) Phenolic contents of Romanian wines with different geographical origins. Asian J Chem 23(12):5197–5201

Hernandez-Orte P, Cacho JF, Ferreira V (2002) Relationship between varietal amino acid profile of grapes and wine aromatic composition. Experiments with model solutions and chemometric study. J Agric Food Chem 50(10):2891–2899

Iordache AM, Geana EI, Ionete RE, Culea M (2010) The optimization of the method for metals content determination in Romanian wines by ICP-MS after microwave mineralization. Prog Cryogenics Isot Sep 13(1):139–148

Obreque-Slier E, Pena-Neira A, Lopez-Solis R, Zamora-Marin F, Ricardo-da-Silva JM, Laureano O (2010) Comparative study of the phenolic composition of seeds and skins from Carmenere and Cabernet sauvignon grape varieties (Vitis vinifera L.) during ripening. J Agric Food Chem 58(6):3591–3599. doi:10.1021/jf904314u

Organisation Internationale de la vigne et du vin, Compendium of international methods of analysis of wine and musts (2008). vol 2

Specifications for the production and marketing of wines with denomination of origin “Dragasani”. http://www.onvpv.ro/?pag=1046

Specifications for the production and marketing of wines with denomination of origin “Recas”. http://www.onvpv.ro/?pag=1028