Volatile Composition of Macedonian and Hungarian Wines Assessed by GC/MS

Springer Science and Business Media LLC - Tập 6 - Trang 1609-1617 - 2012
Violeta Ivanova1, Marina Stefova2, Borimir Vojnoski3, Trajče Stafilov2, Ildiko Bíró4, Anita Bufa4, Attila Felinger5, Ferenc Kilár4,5
1Faculty of Agriculture, University “Goce Delčev”- Štip, Štip, Republic of Macedonia
2Institute of Chemistry, Faculty of Natural Sciences and Mathematics, “Ss Cyril and Methodius” University, Skopje, Republic of Macedonia
3Department for Enology, Institute of Agriculture, Sts “Cyril and Methodius” University, Skopje, Republic of Macedonia
4Institute of Bioanalysis, Faculty of Medicine, University of Pécs, Pécs, Hungary
5Department of Analytical and Environmental Chemistry, Faculty of Sciences, University of Pécs, Pécs, Hungary

Tóm tắt

The volatile composition of eight varietal wines Vranec, Merlot, Cabernet Sauvignon, Temjanika and Chardonnay from the Republic of Macedonia, and Portugieser, Kékfrankos and Tokaji Aszú from Hungary has been characterized by means of gas chromatography/mass spectrometry technique. The wine volatile compounds were extracted in dichloromethane, and the extracts were concentrated under nitrogen. Forty-four volatile compounds have been identified mainly using the NIST mass spectral library and by comparison with the available standards used for quantification as well. Differences between the wines were noted for a number of compounds, such as a higher concentration of 1-pentanol and 2-phenyl ethanol in the red wines. Monoterpenes, linalool and terpineol were detected only in the white wines, Chardonnay and Tokaji. Macedonian red wines were characterized by a higher level of alcohols, while the Hungarian wines contained a higher amount of esters, fatty acids and lactones. A statistical treatment including one-way ANOVA, followed by a Tukey’s test has been performed in order to ascertain possible significant differences between the wines studied, and principal component analysis to study the possible grouping of the wines.

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