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Processes

  2227-9717

 

 

Cơ quản chủ quản:  MDPI , MDPI AG

Lĩnh vực:
Process Chemistry and TechnologyBioengineeringChemical Engineering (miscellaneous)

Các bài báo tiêu biểu

A Review of the Chemistry of Anaerobic Digestion: Methods of Accelerating and Optimizing Process Efficiency
Tập 7 Số 8 - Trang 504
Anthony Anukam, Ali Mohammadi, Muhammad Naqvi, Karin Granström
The anaerobic digestion technology has been in existence for centuries and its underlying theory established for decades. It is considered a useful technology for the generation of renewable energy, and provides means to alleviate problems associated with low access to energy. However, a great deal of current research is targeted towards the optimization of this technology under diverse digestion process conditions. This review presents an in-depth analysis of the chemistry of anaerobic digestion and discusses how process chemistry can be used to optimize system performance through identification of methods that can accelerate syntrophic interactions of different microorganisms for improved methanogenic reactions. Recent advances in addition to old research are discussed in order to offer a general but comprehensive synopsis of accumulated knowledge in the theory of anaerobic digestion, as well as an overview of previous research and future directions and opportunities of the AD technology. Achieving a sustainable energy system requires comprehensive reforms in not just economic, social and policy aspects, but also in all technical aspects, which represents one of the most crucial future investments for anaerobic digestion systems.
Food Waste Composting and Microbial Community Structure Profiling
Tập 8 Số 6 - Trang 723
Kishneth Palaniveloo, Muhammad Azri Amran, Nur Azeyanti Norhashim, Nuradilla Mohamad‐Fauzi, Fang Peng-Hui, Low Hui-Wen, Yap Kai-Lin, Looi Jiale, Melissa Goh Chian-Yee, Lai Jing-Yi, Baskaran Gunasekaran, Shariza Abdul Razak
Over the last decade, food waste has been one of the major issues globally as it brings a negative impact on the environment and health. Rotting discharges methane, causing greenhouse effect and adverse health effects due to pathogenic microorganisms or toxic leachates that reach agricultural land and water system. As a solution, composting is implemented to manage and reduce food waste in line with global sustainable development goals (SDGs). This review compiles input on the types of organic composting, its characteristics, physico-chemical properties involved, role of microbes and tools available in determining the microbial community structure. Composting types: vermi-composting, windrow composting, aerated static pile composting and in-vessel composting are discussed. The diversity of microorganisms in each of the three stages in composting is highlighted and the techniques used to determine the microbial community structure during composting such as biochemical identification, polymerase chain reaction denaturing gradient gel electrophoresis (PCR-DGGE), terminal restriction fragment length polymorphism (T-RFLP) and single strand-conformation polymorphism (SSCP), microarray analysis and next-generation sequencing (NGS) are discussed. Overall, a good compost, not only reduces waste issues, but also contributes substantially to the economic and social sectors of a nation.
Assessment of Wind Energy Potential for the Production of Renewable Hydrogen in Sindh Province of Pakistan
Tập 7 Số 4 - Trang 196
Wasim Iqbal, Yumei Hou, Qaiser Abbas, Muhammad Hafeez, Muhammad Mohsin, Arooj Fatima, Maqsood Ali jamali, Mehwish Jamali, Afroze Siyal, Sohail M. Noman
In this study, we developed a new hybrid mathematical model that combines wind-speed range with the log law to derive the wind energy potential for wind-generated hydrogen production in Pakistan. In addition, we electrolyzed wind-generated power in order to assess the generation capacity of wind-generated renewable hydrogen. The advantage of the Weibull model is that it more accurately reflects power generation potential (i.e., the capacity factor). When applied to selected sites, we have found commercially viable hydrogen production capacity in all locations. All sites considered had the potential to produce an excess amount of wind-generated renewable hydrogen. If the total national capacity of wind-generated was used, Pakistan could conceivably produce 51,917,000.39 kg per day of renewable hydrogen. Based on our results, we suggest that cars and other forms of transport could be fueled with hydrogen to conserve oil and gas resources, which can reduce the energy shortfall and contribute to the fight against climate change and global warming. Also, hydrogen could be used to supplement urban energy needs (e.g., for Sindh province Pakistan), again reducing energy shortage effects and supporting green city programs.
Aeration Process in Bioreactors as the Main Energy Consumer in a Wastewater Treatment Plant. Review of Solutions and Methods of Process Optimization
Tập 7 Số 5 - Trang 311
Jakub Drewnowski, Anna Remiszewska-Skwarek, Sylwia Duda, Grzegorz Łagód
Due to the key role of the biological decomposition process of organic compounds in wastewater treatment, a very important thing is appropriate aeration of activated sludge, because microorganisms have to be supplied with an appropriate amount of oxygen. Aeration is one of the most energy-consuming processes in the conventional activated sludge systems of wastewater treatment technology (may consume from 50% to 90% of electricity used by a plant), which makes it the most cost-generating process incurred by treatment plants. The paper presents the construction of aeration systems, their classification as well as parameters and factors that significantly affect the aeration process e.g., oxygen transfer efficiency, diffuser fouling, methods of dealing with diffuser fouling, diffuser selection. Additionally, there are briefly presented “smart control” systems in wastewater treatment and effect of application control strategy based on Supervisory Control and Data Acquisition system connected with the decrease in the energy consumption for aeration of bioreactors with activated sludge. It is noted that before the process is optimized, the system should be equipped with suitable metering devices. Only when relevant data is available, the improvements can be carried out. However, it’s important, that the operator should regularly maintain good condition and high efficiency of diffusers.
Flotation in Water and Wastewater Treatment
Tập 6 Số 8 - Trang 116
George Z. Kyzas, K. A. Matis
Flotation constitutes a separation process that originated from mineral processing. Nowadays, wider applications have been found and compared to flotation for water and wastewater treatment. Stress in the present review paper was mainly applied to heavy metal ions recovery by flotation and the respective mechanism followed, being either ion, precipitate, or sorptive flotation. In the latter case, the use of adsorbents is included (such as powdered activated carbon, zeolites, and goethite), as well as various biosorbents. The flotation of the following metals was reviewed: copper, zinc, nickel, lead, iron, chromium, arsenic, gold, and others. The bubble generation method could be applied for typical dispersed-air flotation column, electroflotation, or dissolved-air flotation; the latter being the most appropriate established technique in water treatment. The role of particle size (for example, studying flotation of salt-type mineral fines) was also examined.
Advanced Bioethanol Production: From Novel Raw Materials to Integrated Biorefineries
Tập 9 Số 2 - Trang 206
Aleta Duque, Cristina Álvarez, Pablo Doménech, Paloma Manzanares, Antonio D. Moreno
The production of so-called advanced bioethanol offers several advantages compared to traditional bioethanol production processes in terms of sustainability criteria. This includes, for instance, the use of nonfood crops or residual biomass as raw material and a higher potential for reducing greenhouse gas emissions. The present review focuses on the recent progress related to the production of advanced bioethanol, (i) highlighting current results from using novel biomass sources such as the organic fraction of municipal solid waste and certain industrial residues (e.g., residues from the paper, food, and beverage industries); (ii) describing new developments in pretreatment technologies for the fractionation and conversion of lignocellulosic biomass, such as the bioextrusion process or the use of novel ionic liquids; (iii) listing the use of new enzyme catalysts and microbial strains during saccharification and fermentation processes. Furthermore, the most promising biorefinery approaches that will contribute to the cost-competitiveness of advanced bioethanol production processes are also discussed, focusing on innovative technologies and applications that can contribute to achieve a more sustainable and effective utilization of all biomass fractions. Special attention is given to integrated strategies such as lignocellulose-based biorefineries for the simultaneous production of bioethanol and other high added value bioproducts.
Measuring Energy Efficiency and Environmental Performance: A Case of South Asia
Tập 7 Số 6 - Trang 325
Yumei Hou, Wasim Iqbal, Ghulam Muhammad Shaikh, Nadeem Iqbal, Yasir Ahmed Solangi, Arooj Fatima
When assessing energy efficiency, most studies have frequently ignored environmental aspects even though the concept has been widely used in the past. This study evaluates the energy efficiency and environmental performance of South Asia by using DEA (data envelopment analysis) like mathematical composite indicator. We construct a comprehensive set of indicators, including an energy self-sufficiency ratio, energy production over consumption ratio, energy imports, diversification index of energy imports, energy reserve ratio, GDP productivity, energy intensity, per capita energy consumption index, carbon emission index, carbon emission index per unit of energy consumption and share of renewable energy in order to develop an energy efficiency and environmental performance index. Unlike other studies, this study first examines each indicator and then estimates a combined score for each country. The results reveal that Bhutan as a more secure country and Pakistan showed a decreasing trend, while Sri Lanka and India performed satisfactorily. Remarkably, Bangladesh, Nepal and Afghanistan showed a decreasing trend. This study proposes a policy that increases the cross-border trade of renewable energy for long term energy efficiency and environmental performance.
Preparation of KOH and H3PO4 Modified Biochar and Its Application in Methylene Blue Removal from Aqueous Solution
Tập 7 Số 12 - Trang 891
Li Liu, Yang Li, Shisuo Fan
Improperly treated or directly discharged into the environment, wastewater containing dyes can destroy the quality of water bodies and pollute the ecological environment. The removal of dye wastewater is urgent and essential. In this study, corn stalk was pyrolyzed to pristine biochar (CSBC) in a limited oxygen atmosphere and modified using KOH and H3PO4 (KOH-CSBC, H3PO4-CSBC, respectively). The biochars were characterized by surface area and pore size, X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), as well as their behavior in adsorbing methylene blue (MB). Results indicated that the pore structure of CSBC became more developed after modification by KOH. Meanwhile, H3PO4-CSBC contained more functional groups after activation treatment. The pseudo-second-order kinetic and the Langmuir adsorption isotherm represented the adsorption process well. The maximum MB adsorption capacity of CSBC, KOH-CSBC, and H3PO4-CSBC was 43.14 mg g−1, 406.43 mg g−1 and 230.39 mg g−1, respectively. Chemical modification significantly enhanced the adsorption of MB onto biochar, especially for KOH-CSBC. The adsorption mechanism between MB and biochar involved physical interaction, electrostatic interaction, hydrogen bonding and π–π interaction. Hence, modified CSBC (especially KOH-CSBC) has the potential for use as an adsorbent to remove dye from textile wastewater.
A DEA Approach for Assessing the Energy, Environmental and Economic Performance of Top 20 Industrial Countries
Tập 7 Số 12 - Trang 902
Wasim Iqbal, Ali Altalbe, Arooj Fatima, Amjad Ali, Yumei Hou
Due to growing concerns of global warming, reducing carbon emissions has become one of the major tasks for developing countries to meet the national demand for energy policies. The objective of this study is to measure the energy consumption, carbon emission and economic-environmental efficiency in terms of the environmental performance of the top 20 industrial countries by employing a data envelopment analysis (DEA) model from 2013 to 2017. This study used the trilemma of energy efficiency, CO2 emission efficiency, and environmental efficiency, and also the contribution included the quantitative analysis of 20 industrial countries The results show that the energy efficiency of Australia, China, Japan, Saudi Arabia, and Poland are the best performing countries, whereas Mexico, Indonesia, Russia, and Brazil are identified as least efficient among all 20 countries. Furthermore, Russia’s energy intensity has a maximum score while Poland has a minimum score. Additionally, in the case of CO2 emission efficiency, Brazil, France, and Saudi Arabia are considered as efficient while nine country’s scores were less than 0.5. The results show that most countries exhibit higher performance in economic efficiency than environmental efficiency. The study provides valuable information for energy policy-makers.
Technology for the Remediation of Water Pollution: A Review on the Fabrication of Metal Organic Frameworks
Tập 6 Số 8 - Trang 122
Yongning Bian, Nana Xiong, Guocheng Zhu
The ineffective control of the release of pollutants into water has led to serious water pollution. Compared with conditions in the past, the polluting components in aquatic environments have become increasingly complex. Some emerging substances have led to a new threat to the safety of water. Therefore, developing cost-effective technologies for the remediation of water pollution is urgently needed. Adsorption has been considered the most effective operational unit in water treatment processes and thus adsorption materials have gained wide attention. Among them, metal organic frameworks (denoted as MOFs) have been rapidly developed in recent years due to their unique physicochemical performance. They are characterized by larger porosity and larger specific surface area, easier pore structure designing, and comfortable structural modification. In many fields such as adsorption, separation, storage, and transportation, MOFs show a better performance than conventional adsorption materials such as active carbon. Their performance is often dependent on their structural distribution. To optimize the use of MOFs, their fabrication should be given more attention, without being limited to conventional preparation methods. Alternative preparation methods are given in this review, such as diffusion, solvent thermal, microwave, and ion thermal synthesis. Furthermore, developing functionalized MOFs is an available option to improve the removal efficiencies of a specific contaminant through pre-synthetic modification and post-synthesis modification. Post-synthesis modification has become a recent research hotspot. The coupling of MOFs with other techniques would be another option to ameliorate the remediation of water pollution. On one hand, their intrinsic drawbacks may be reduced. On the other hand, their performance may be enhanced due to their interaction behaviors. Overall, such coupling technologies are able to enhance the performance of an individual material. Because the excellent performance of MOF materials has been widely recognized and their developments have received wide attention, especially in environmental fields, in the present work we provide a review of fabrication of MOFs so as to motivate readers to deepen their understanding of the use of MOFs.