Processes
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Technology for the Remediation of Water Pollution: A Review on the Fabrication of Metal Organic Frameworks The ineffective control of the release of pollutants into water has led to serious water pollution. Compared with conditions in the past, the polluting components in aquatic environments have become increasingly complex. Some emerging substances have led to a new threat to the safety of water. Therefore, developing cost-effective technologies for the remediation of water pollution is urgently needed. Adsorption has been considered the most effective operational unit in water treatment processes and thus adsorption materials have gained wide attention. Among them, metal organic frameworks (denoted as MOFs) have been rapidly developed in recent years due to their unique physicochemical performance. They are characterized by larger porosity and larger specific surface area, easier pore structure designing, and comfortable structural modification. In many fields such as adsorption, separation, storage, and transportation, MOFs show a better performance than conventional adsorption materials such as active carbon. Their performance is often dependent on their structural distribution. To optimize the use of MOFs, their fabrication should be given more attention, without being limited to conventional preparation methods. Alternative preparation methods are given in this review, such as diffusion, solvent thermal, microwave, and ion thermal synthesis. Furthermore, developing functionalized MOFs is an available option to improve the removal efficiencies of a specific contaminant through pre-synthetic modification and post-synthesis modification. Post-synthesis modification has become a recent research hotspot. The coupling of MOFs with other techniques would be another option to ameliorate the remediation of water pollution. On one hand, their intrinsic drawbacks may be reduced. On the other hand, their performance may be enhanced due to their interaction behaviors. Overall, such coupling technologies are able to enhance the performance of an individual material. Because the excellent performance of MOF materials has been widely recognized and their developments have received wide attention, especially in environmental fields, in the present work we provide a review of fabrication of MOFs so as to motivate readers to deepen their understanding of the use of MOFs.
Processes - Tập 6 Số 8 - Trang 122
Optimal Control Strategy for TB-HIV/AIDS Co-Infection Model in the Presence of Behaviour Modification A mathematical model for a transmission of TB-HIV/AIDS co-infection that incorporates prevalence dependent behaviour change in the population and treatment for the infected (and infectious) class is formulated and analyzed. The two sub-models, when each of the two diseases are considered separately are mathematically analyzed. The theory of optimal control analysis is applied to the full model with the objective of minimizing the aggregate cost of the infections and the control efforts. In the numerical simulation section, various combinations of the controls are also presented and it has been shown in this part that the optimal combination of both prevention and treatment controls will suppress the prevalence of both HIV and TB to below 3% within 10 years. Moreover, it is found that the treatment control is more effective than the preventive controls.
Processes - Tập 6 Số 5 - Trang 48
Effects of Swirl and Boiling Heat Transfer on the Performance Enhancement and Emission Reduction for a Medium Diesel Engine Fueled with Biodiesel In order to improve the accuracy of numerical simulation, a new heat transfer model is developed by using a modular approach in the Anstalt für Verbrennungskraftmaschinen (AVL)-Boost software. The improved heat transfer model mainly considers the effects of the swirl and boiling heat transfer inside the engine. In addition, a chemical kinetics mechanism including 475 reactions and 134 species is employed to predict the combustion of diesel engines fueled with biodiesel. The result shows that the boiling heat transfer will occur, especially in the high-temperature area. Analysis shows that the improved model is reliable and its precision is increased. Finally, the perturbation method is employed to investigate the relatively important inputs as the complex nonlinear function with a lot of output data and input data produced by the improved model. The relative effects of different parameters such as EGR, injection mass, injection timing, compression ratio, inlet air pressure, fuel injection pressure, exhaust pressure and inlet air temperature on performance and emission characteristics are compared. The eight parameters are investigated on four outputs of brake power, Brake Specific Fuel Consumption (BSFC), NOx and HC. The injected fuel mass plays an important role in emissions and performance. The EGR, compression ratio and inlet air pressure have a great effect on the HC and NOx emission.
Processes - Tập 9 Số 3 - Trang 568
Aeration Process in Bioreactors as the Main Energy Consumer in a Wastewater Treatment Plant. Review of Solutions and Methods of Process Optimization Due to the key role of the biological decomposition process of organic compounds in wastewater treatment, a very important thing is appropriate aeration of activated sludge, because microorganisms have to be supplied with an appropriate amount of oxygen. Aeration is one of the most energy-consuming processes in the conventional activated sludge systems of wastewater treatment technology (may consume from 50% to 90% of electricity used by a plant), which makes it the most cost-generating process incurred by treatment plants. The paper presents the construction of aeration systems, their classification as well as parameters and factors that significantly affect the aeration process e.g., oxygen transfer efficiency, diffuser fouling, methods of dealing with diffuser fouling, diffuser selection. Additionally, there are briefly presented “smart control” systems in wastewater treatment and effect of application control strategy based on Supervisory Control and Data Acquisition system connected with the decrease in the energy consumption for aeration of bioreactors with activated sludge. It is noted that before the process is optimized, the system should be equipped with suitable metering devices. Only when relevant data is available, the improvements can be carried out. However, it’s important, that the operator should regularly maintain good condition and high efficiency of diffusers.
Processes - Tập 7 Số 5 - Trang 311
The Application of Supercritical Fluids Technology to Recover Healthy Valuable Compounds from Marine and Agricultural Food Processing By-Products: A Review Food by-products contain a remarkable source of bioactive molecules with many benefits for humans; therefore, their exploitation can be an excellent opportunity for the food sector. Moreover, the revalorization of these by-products to produce value-added compounds is considered pivotal for sustainable growth based on a circular economy. Traditional extraction technologies have several drawbacks mainly related to the consumption of hazardous organic solvents, and the high temperatures maintained for long extraction periods which cause the degradation of thermolabile compounds as well as a low extraction efficiency of desired compounds. In this context, supercritical fluid extraction (SFE) has been explored as a suitable green technology for the recovery of a broad range of bioactive compounds from different types of agri-food wastes. This review describes the working principle and development of SFE technology to valorize by-products from different origin (marine, fruit, vegetable, nuts, and other plants). In addition, the potential effects of the extracted active substances on human health were also approached.
Processes - Tập 9 Số 2 - Trang 357
Evaluation of Water Hammer for Seawater Treatment System in Offshore Floating Production Unit Water hammer can result in the rupture of pipes, and significant damage to pipe supports is inevitable during the operation of an offshore plant. In this study, the dynamic behaviors of the water hammer caused by closing valves and starting pumps for the seawater treatment system were evaluated by using the 1D numerical simulation model based on the method of characteristics. Before conducting an analysis of a complex piping network, the 1D numerical simulation tools were validated by a comparison between the numerical results and the results from both static and transient experiments that have been conducted in other studies. For the case study, the effects of valve flow characteristics and valve closing time on surge pressure were investigated, and the equal percentage butterfly valve was recommended in order to reduce the surge pressure with a shorter valve closure time and lower weight compared to other valve types.
Processes - Tập 8 Số 9 - Trang 1041
Experimental Study on Pressure Distribution and Flow Coefficient of Globe Valve In this study, the pressure distribution and flow coefficient of a globe valve are investigated with a series of experiments conducted in a flow test loop. The experiments are performed on a three-inch model test valve from an eight-inch ANSI (American National Standards Institute) B16.11—Class 2500# prototype globe valve with various pump speeds and full range of valve openings. Both inherent and installed flow characteristics are measured, and the results show that the flow coefficient depends not only on the valve geometry and valve opening but also on the Reynolds number. When the Reynolds number exceeds a certain value, the flow coefficients are stable. In addition, the pressures at different positions in the upstream and the downstream of the valve are measured and compared with recommendation per ANSI/ISA-75.01 standard. The results show that, in single-phase flow, the discrepancies in pressure between different measurement locations within close range of 10 nominal diameter from the valve are inconsiderable.
Processes - Tập 8 Số 7 - Trang 875
Pressure Drop and Cavitation Analysis on Sleeve Regulating Valve The sleeve regulating valve is widely used in the pipeline systems of process industries to control fluid flow. When flowing through the sleeve regulating valve, the water is easy to reach cavitation because of the pressure drop in the partial region, which may cause serious damage to pipeline system. In this paper, the pressure drop and cavitation characteristics in the sleeve regulating valve for different pressure differences and valve core displacements are investigated using a multiphase cavitation model. The pressure drop, velocity and vapor volume distribution in the regulating valves are obtained and analyzed. The total vapor volumes are also predicted and compared. The results show that the decrease of the valve core displacement induces the enlargement of the vapor distribution region and the increase of the vapor density. The increase of the pressure difference induces a more serious cavitation. The pressure difference has a slight influence on the cavitation intensity and density in the regulating valve when the valve core displacement is 60 mm. With the decrease of the valve core displacement, the effects of the pressure difference on the cavitation intensity are enhanced. This work is of significance for the cavitation control of the sleeve regulating valves.
Processes - Tập 7 Số 11 - Trang 829
Antioxidant Molecules from Plant Waste: Extraction Techniques and Biological Properties The fruit, vegetable, legume, and cereal industries generate many wastes, representing an environmental pollution problem. However, these wastes are a rich source of antioxidant molecules such as terpenes, phenolic compounds, phytosterols, and bioactive peptides with potential applications mainly in the food and pharmaceutical industries, and they exhibit multiple biological properties including antidiabetic, anti-obesity, antihypertensive, anticancer, and antibacterial properties. The aforementioned has increased studies on the recovery of antioxidant compounds using green technologies to value plant waste, since they represent more efficient and sustainable processes. In this review, the main antioxidant molecules from plants are briefly described and the advantages and disadvantages of the use of conventional and green extraction technologies used for the recovery and optimization of the yield of antioxidant naturals are detailed; finally, recent studies on biological properties of antioxidant molecules extracted from plant waste are presented here.
Processes - Tập 8 Số 12 - Trang 1566
Preparation of KOH and H3PO4 Modified Biochar and Its Application in Methylene Blue Removal from Aqueous Solution Improperly treated or directly discharged into the environment, wastewater containing dyes can destroy the quality of water bodies and pollute the ecological environment. The removal of dye wastewater is urgent and essential. In this study, corn stalk was pyrolyzed to pristine biochar (CSBC) in a limited oxygen atmosphere and modified using KOH and H3PO4 (KOH-CSBC, H3PO4-CSBC, respectively). The biochars were characterized by surface area and pore size, X-ray diffraction (XRD), Fourier transform infrared (FTIR) spectroscopy, X-ray photoelectron spectroscopy (XPS), as well as their behavior in adsorbing methylene blue (MB). Results indicated that the pore structure of CSBC became more developed after modification by KOH. Meanwhile, H3PO4-CSBC contained more functional groups after activation treatment. The pseudo-second-order kinetic and the Langmuir adsorption isotherm represented the adsorption process well. The maximum MB adsorption capacity of CSBC, KOH-CSBC, and H3PO4-CSBC was 43.14 mg g−1, 406.43 mg g−1 and 230.39 mg g−1, respectively. Chemical modification significantly enhanced the adsorption of MB onto biochar, especially for KOH-CSBC. The adsorption mechanism between MB and biochar involved physical interaction, electrostatic interaction, hydrogen bonding and π–π interaction. Hence, modified CSBC (especially KOH-CSBC) has the potential for use as an adsorbent to remove dye from textile wastewater.
Processes - Tập 7 Số 12 - Trang 891
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