Polymers

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Low Density Nanocellular Polymers Based on PMMA Produced by Gas Dissolution Foaming: Fabrication and Cellular Structure Characterization
Polymers - Tập 8 Số 7 - Trang 265
Judith Martín‐de León, Victoria Bernardo, Miguel Ángel Rodríguez‐Pérez
This paper describes the processing conditions needed to produce low density nanocellular polymers based on polymethylmethacrylate (PMMA) with relative densities between 0.45 and 0.25, cell sizes between 200 and 250 nm and cell densities higher than 1014 cells/cm3. To produce these nanocellular polymers, the foaming parameters of the gas dissolution foaming technique using CO2 as blowing a...... hiện toàn bộ
Study and Characterization of the Dielectric Behavior of Low Linear Density Polyethylene Composites Mixed with Ground Tire Rubber Particles
Polymers - Tập 12 Số 5 - Trang 1075
Marc Marín-Genescà, Jordi García-Amorós, Ramon Maria Mujal-Rosas, Lluís Massagués, X. Colom
The waste rubber vulcanizate, on account of its stable, cross-linked and three-dimensional structural arrangement, is difficult to biodegrade. Thus, the ever-increasing bulk of worn-out tires is a serious environmental issue and its safe disposal is still a challenging task reported widely by the scientific community. The rubber materials, once they end their useful life, may present diffi...... hiện toàn bộ
Novel Copper Photoredox Catalysts for Polymerization: An In Situ Synthesis of Metal Nanoparticles
Polymers - Tập 12 Số 10 - Trang 2293
Haja Tar, Tahani I. Kashar, Noura Kouki, Reema Aldawas, Bernadette Graff, Jacques Lalevée
The copper II complex (HLCuCl) carrying 2,4 dinitrophenylhydrazone (L) is synthesized and evaluated as a new photoredox catalyst/photoinitiator in combination with triethylamine (TEA) and iodonium salt (Iod) for the radical polymerization of ethylene glycol diacrylate during exposure to visible light using a photoreactor at 419 nm. The copper complex reactivity with TEA/Iod salt/gold chlor...... hiện toàn bộ
Preparation and Properties of Inherently Black Polyimide Films with Extremely Low Coefficients of Thermal Expansion and Potential Applications for Black Flexible Copper Clad Laminates
Polymers - Tập 12 Số 3 - Trang 576
Yaoyao Tan, Yan Zhang, Ganglan Jiang, Xin‐xin Zhi, Xiao Xiao, Lin Wu, Jia Yan-jiang, Jingang Liu, Xiumin Zhang
In the current work, a series of black polyimide (PI) films with excellent thermal and dimensional stability at elevated temperatures were successfully developed. For this purpose, two aromatic diamines including 4,4′-iminodianline (NDA) and 2-(4-aminophenyl)-5- aminobenzimidazole (APBI) were copolymerized with pyromellitic dianhydride (PMDA) to afford PIs containing imino groups (–NH–) in...... hiện toàn bộ
Novel Organic Sensitizers Containing 2,6-Difunctionalized Anthracene Unit for Dye Sensitized Solar Cells
Polymers - Tập 4 Số 3 - Trang 1443-1461
Yung‐Sheng Yen, Yung‐Chung Chen, Hsien‐Hsin Chou, Shih-Tang Huang, Jiann T. Lin
A series of new organic dyes comprising different amines as electron donors, 2-(6-substituted-anthracen-2-yl)-thiophene as the π-conjugated bridge, and cyanoacrylic acid group as an electron acceptor and anchoring group, have been synthesized. There exists charge transfer transition from arylamine and anthracene to the acceptor in these compounds, as evidenced from the photophysical measur...... hiện toàn bộ
Influence of Functionalization Degree on the Rheological Properties of Isocyanate-Functionalized Chitin- and Chitosan-Based Chemical Oleogels for Lubricant Applications
Polymers - Tập 6 Số 7 - Trang 1929-1947
R. Gallego, Mercedes González, Jesús F. Arteaga, C. Valencia, J.M. Franco
This work deals with the influence of functionalization degree on the thermogravimetric and rheological behaviour of NCO-functionalized chitosan- and chitin-based oleogels. Chitosan and chitin were functionalized using different proportions of 1,6-hexamethylene diisocyanate (HMDI) and subsequently dispersed in castor oil to promote the chemical reaction between the –NCO group of the modif...... hiện toàn bộ
Facile Synthesis of Carboxymethyl Cellulose Coated Core/Shell SiO2@Cu Nanoparticles and Their Antifungal Activity against Phytophthora capsici
Polymers - Tập 13 Số 6 - Trang 888 - 2021
Hai, Nguyen Thi Thanh, Cuong, Nguyen Duc, Quyen, Nguyen Tran, Hien, Nguyen Quoc, Hien, Tran Thi Dieu, Phung, Nguyen Thi Thanh, Toan, Dao Khac, Huong, Nguyen Thi Thu, Phu, Dang Van, Hoa, Tran Thai
Cu nanoparticles are a potential material for creating novel alternative antimicrobial products due to their unique antibacterial/antifungal properties, stability, dispersion, low cost and abundance as well as being economical and ecofriendly. In this work, carboxymethyl cellulose coated core/shell SiO2@Cu nanoparticles (NPs) were synthesized by a simple and effective chemical reduction process. T...... hiện toàn bộ
Microwave Assisted Extraction of Raw Alginate as a Sustainable and Cost-Effective Method to Treat Beach-Accumulated Sargassum Algae
Polymers - Tập 15 Số 14 - Trang 2979 - 2023
Nesic, Aleksandra, De Bonis, Maria Valeria, Dal Poggetto, Giovanni, Ruocco, Gianpaolo, Santagata, Gabriella
This paper highlights the potential of Sargassum algae, recovered from raw beach seaweed wastes, as a valid source of valuable sodium alginate. Alginate is a biodegradable, highly attractive polysaccharide widely used in food, pharmaceuticals, and biomedicine applications. The aim of this work is to employ a new eco-sustainable and cost-effective extractive method to obtain alginate as a raw mater...... hiện toàn bộ
Development and Characterization of Pectin Films with Salicornia ramosissima: Biodegradation in Soil and Seawater
Polymers - Tập 13 Số 16 - Trang 2632 - 2021
Pereira, Daniela G. M., Vieira, Jorge M., Vicente, António A., Cruz, Rui M. S.
Pectin films were developed by incorporating a halophyte plant Salicornia ramosissima (dry powder from stem parts) to modify the film’s properties. The films’ physicomechanical properties, Fourier-transform infrared spectroscopy (FTIR), and microstructure, as well as their biodegradation capacity in soil and seawater, were evaluated. The inclusion of S. ramosissima significantly increased the thic...... hiện toàn bộ
Potential of the Liquid Fermentation of Fishery Waste by Paenibacillus elgii for Metalloprotease Production
Polymers - Tập 14 Số 13 - Trang 2741 - 2022
Doan, Chien Thang, Tran, Thi Ngoc, Nguyen, Minh Trung, Nguyen, Huu Kien, Tran, Thi Kim Thi, Nguyen, Thi Hanh, Tran, Thi Phuong Hanh, Nguyen, Van Bon, Nguyen, Anh Dzung, Wang, San-Lang
This study attempted to use fishery processing wastes to produce protease by Paenibacillus elgii TKU051. Of the tested wastes, tuna head powder (THP) was found to be the most effective carbon and nitrogen (C/N) source, and the optimal conditions were as follows: 0.811% THP, 0.052% K2HPO4, 0.073% MgSO4, initial pH of 8.96, incubation temperature of 31.4 °C, and incubation time of 3.092 days to achi...... hiện toàn bộ
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