Phân tích ảnh hưởng
Thông tin về tạp chí
Các bài báo tiêu biểu
Graphene Nanosheets to Improve Physico-Mechanical Properties of Bioactive Calcium Silicate Cements Bioactive calcium silicate cements are widely used to induce mineralization, to cement prosthetic parts, in the management of tooth perforations, and other areas. Nonetheless, they can present clinical disadvantages, such as long setting time and modest physico-mechanical properties. The objective of this work was to evaluate the potential of graphene nanosheets (GNS) to improve two bioactive cements. GNS were obtained via reduction of graphite oxide. GNS were mixed (1, 3, 5, and 7 wt %) with Biodentine (BIO) and Endocem Zr (ECZ), and the effects on setting time, hardness, push-out strength, pH profile, cell proliferation, and mineralization were evaluated. Statistics were performed with two-way ANOVA and Tukey test (α = 0.05). GNS has not interfered in the composition of the set cements as confirmed by Raman, FT-IR and XRD. GNS (1 and 3 wt %) shortened the setting time, increased hardness of both materials but decreased significantly the push-out strength of ECZ. pH was not affected but 1 wt % and 7 wt % to ECZ and 5 wt % to BIO increased the mineralization compared to the controls. In summary, GNS may be an alternative to improve the physico-mechanical properties and bioactivity of cements. Nonetheless, the use of GNS may not be advised for all materials when effective bonding is a concern.
Tập 10 Số 6 - Trang 606
Effect of Exposed Surface Area, Volume and Environmental pH on the Calcium Ion Release of Three Commercially Available Tricalcium Silicate Based Dental Cements Tricalcium silicate cements (TSC) are used in dental traumatology and endodontics for their bioactivity which is mostly attributed to formation of calcium hydroxide during TSC hydration and its subsequent release of calcium and hydroxide ions. The aim of this study was to determine the effect of volume (Vol), exposed surface area (ESA) and pH of surrounding medium on calcium ion release. Three commercially available hydraulic alkaline dental cements were mixed and condensed into cylindrical tubes of varying length and diameter (n = 6/group). For the effect of ESA and Vol, tubes were immersed in 10 mL of deionized water. To analyze the effect of environmental pH, the tubes were randomly immersed in 10 mL of buffer solutions with varying pH (10.4, 7.4 or 4.4). The solutions were collected and renewed at various time intervals. pH and/or calcium ion release was measured using a pH glass electrode and atomic absorption spectrophotometer respectively. The change of pH, short-term calcium ion release and rate at which calcium ion release reaches maximum were dependent on ESA (p < 0.05) while maximum calcium ion release was dependent on Vol of TSC (p < 0.05). Maximum calcium ion release was significantly higher in acidic solution followed by neutral and alkaline solution (p < 0.05).
Tập 11 Số 1 - Trang 123
Phosphorus-based Flame Retardancy Mechanisms—Old Hat or a Starting Point for Future Development? Different kinds of additive and reactive flame retardants containing phosphorus are increasingly successful as halogen-free alternatives for various polymeric materials and applications. Phosphorus can act in the condensed phase by enhancing charring, yielding intumescence, or through inorganic glass formation; and in the gas phase through flame inhibition. Occurrence and efficiency depend, not only on the flame retardant itself, but also on its interaction with pyrolysing polymeric material and additives. Flame retardancy is sensitive to modification of the flame retardant, the use of synergists/adjuvants, and changes to the polymeric material. A detailed understanding facilitates the launch of tailored and targeted development.
Tập 3 Số 10 - Trang 4710-4745
Biodegradable Materials for Bone Repair and Tissue Engineering Applications This review discusses and summarizes the recent developments and advances in the use of biodegradable materials for bone repair purposes. The choice between using degradable and non-degradable devices for orthopedic and maxillofacial applications must be carefully weighed. Traditional biodegradable devices for osteosynthesis have been successful in low or mild load bearing applications. However, continuing research and recent developments in the field of material science has resulted in development of biomaterials with improved strength and mechanical properties. For this purpose, biodegradable materials, including polymers, ceramics and magnesium alloys have attracted much attention for osteologic repair and applications. The next generation of biodegradable materials would benefit from recent knowledge gained regarding cell material interactions, with better control of interfacing between the material and the surrounding bone tissue. The next generations of biodegradable materials for bone repair and regeneration applications require better control of interfacing between the material and the surrounding bone tissue. Also, the mechanical properties and degradation/resorption profiles of these materials require further improvement to broaden their use and achieve better clinical results.
Tập 8 Số 9 - Trang 5744-5794
Anaerobic Biodegradation of Detergent Surfactants Detergent surfactantscan be found in wastewater in relevant concentrations. Most of them are known as ready degradable under aerobic conditions, as required by European legislation. Far fewer surfactants have been tested so far for biodegradability under anaerobic conditions. The natural environment is predominantly aerobic, but there are some environmental compartments such as river sediments, sub-surface soil layer and anaerobic sludge digesters of wastewater treatment plants which have strictly anaerobic conditions. This review gives an overview on anaerobic biodegradation processes, the methods for testing anaerobic biodegradability, and the anaerobic biodegradability of different detergent surfactant types (anionic, nonionic, cationic, amphoteric surfactants).
Tập 2 Số 1 - Trang 181-206
Facile Fabrication of Magnetic Metal-Organic Framework Composites for the Highly Selective Removal of Cationic Dyes In this work, we show a novel magnetic composite material Fe3O4@HPU-9 (HPU-9 = {[Cd(L)0.5(H2O)](DMA)(CH3CN)}n) (H4L = 1,1′-di(3,5-dicarbonylbenzyl)-2,2′bimidazoline, DMA = N,N-dimethylacetamide) constructed by in situ growth of HPU-9 on Fe3O4, which has excellent absorption of cationic dyes from aqueous solution. The Fe3O4@HPU-9 particle possesses a well-defined core-shell structure consisting of a Fe3O4 core (diameter: 190 nm) and a HPU-9 shell (thickness: 10 nm). In the composite, the HPU-9 shell contributes to the capsulation of cationic dyes through electrostatic attractions between HPU-9 and cationic dyes, while the Fe3O4 core serves as magnetic particle. The maximum absorption capacity of Fe3O4@HPU-9 for R6G was 362.318 mg·g−1. The absorption kinetics data were well described by a psedo-second-order model (R2 > 0.99), and the equilibrium data were also well fitted to Langmuir isotherm model (R2 > 0.99). Our data confirmed that the proposed magnetic composite could be recycled and reused several times without centrifugal separation, making it more convenient, economic and efficient than common adsorbents.
Tập 11 Số 5 - Trang 744
Profile Features of Emulsified Asphalt Mixture Containing Steel Slag Based on Laser Scanning Micro-surfacing (MS), made of emulsified asphalt, is the most commonly used preventive maintenance technology in asphalt pavement. However, the studies on profile features of MS based on aggregate morphology are few. This study evaluated the profile features of MS and its effect on skid resistance. The aggregate morphologies were first characterized and modified emulsified asphalt was prepared. The three-dimensional profile features of four kinds of MS samples were captured by laser texture scanner. Results illustrate that steel slag aggregate can be used to enhance the skid resistance of pavement surface and bring about larger profile indexes than basalt and limestone due to its angularity index and flatness values. Further aging of steel slag to eliminate free calcium oxide (f-CaO) is recommended before being used in pavement surface layer.
Tập 13 Số 12 - Trang 2679
Effect of Macro-, Micro- and Nano-Calcium Carbonate on Properties of Cementitious Composites—A Review Calcium carbonate is wildly used in cementitious composites at different scales and can affect the properties of cementitious composites through physical effects (such as the filler effect, dilution effect and nucleation effect) and chemical effects. The effects of macro (>1 mm)-, micro (1 μm–1 mm)- and nano (<1 μm)-sizes of calcium carbonate on the hydration process, workability, mechanical properties and durability are reviewed. Macro-calcium carbonate mainly acts as an inert filler and can be involved in building the skeletons of hardened cementitious composites to provide part of the strength. Micro-calcium carbonate not only fills the voids between cement grains, but also accelerates the hydration process and affects the workability, mechanical properties and durability through the dilution, nucleation and even chemical effects. Nano-calcium carbonate also has both physical and chemical effects on the properties of cementitious composites, and these effects behave even more effectively than those of micro-calcium carbonate. However, agglomeration of nano-calcium carbonate reduces its enhancement effects remarkably.
Tập 12 Số 5 - Trang 781
Rare-Earth Activated Nitride Phosphors: Synthesis, Luminescence and Applications Nitridosilicates are structurally built up on three-dimensional SiN4 tetrahedral networks, forming a very interesting class of materials with high thermomechanical properties, hardness, and wide band gap. Traditionally, nitridosilicates are often used as structural materials such as abrasive particles, cutting tools, turbine blade, etc. Recently, the luminescence of rare earth doped nitridosilicates has been extensively studied, and a novel family of luminescent materials has been developed. This paper reviews the synthesis, luminescence and applications of nitridosilicate phosphors, with emphasis on rare earth nitrides in the system of M-Si-Al-O-N (M = Li, Ca, Sr, Ba, La) and their applications in white LEDs. These phosphors exhibit interesting luminescent properties, such as red-shifted excitation and emission, small Stokes shift, small thermal quenching, and high conversion efficiency, enabling them to use as down-conversion luminescent materials in white LEDs with tunable color temperature and high color rendering index.
Tập 3 Số 6 - Trang 3777-3793
Cyclic Behavior of Low Rise Concrete Shear Walls Containing Recycled Coarse and Fine Aggregates In this study, the cyclic behaviors of low rise concrete shear walls using recycled coarse or fine aggregates were investigated. Eight low rise Recycled Aggregates Concrete (RAC) shear wall specimens were designed and tested under a cyclic loading. The following parameters were varied: replacement percentages of recycled coarse or fine aggregates, reinforcement ratio, axial force ratio and X-shaped rebars brace. The failure characteristics, hysteretic behavior, strength and deformation capacity, strain characteristics and stiffness were studied. Test results showed that the using of the Recycled Coarse Aggregates (RCA) and its replacement ratio had almost no influence on the mechanical behavior of the shear wall; however, the using of Recycled Fine Aggregates (RFA) had a certain influence on the ductility of the shear wall. When the reinforcement ratio increased, the strength and ductility also increased. By increasing the axial force ratio, the strength increased but the ductility decreased significantly. The encased brace had a significant effect on enhancing the RAC shear walls. The experimental maximum strengths were evaluated with existing design codes, it was indicated that the strength evaluation of the low rise RAC shear walls can follow the existing design codes of the conventional concrete shear walls.
Tập 10 Số 12 - Trang 1400