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Sustainable Chemical Processes

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Các bài báo tiêu biểu

High performance green barriers based on nanocellulose
- 2014
Sandeep S. Nair, Jiaqing Zhu, Yulin Deng, Arthur J. Ragauskas
Abstract With the increasing environmental concerns such as sustainability and end-of-life disposal challenges, materials derived from renewable resources such as nanocellulose have been strongly advocated as potential replacements for packaging materials. Nanocellulose can be extracted from various plant resources through mechanical and chemical ways. Nanocellulose with its nanoscale dimensions, ... hiện toàn bộ
Recent developments in maleic acid synthesis from bio-based chemicals
Tập 3 Số 1 - 2015
Robert Wojcieszak, Francesco Santarelli, Sébastien Paul, Franck Dumeignil, Fabrizio Cavani, Renato V. Gonçalves
Valorisation of food waste to biofuel: current trends and technological challenges
Tập 2 - Trang 1-4 - 2014
Sanjib Kumar Karmee, Carol Sze Ki Lin
Demand for biofuels is rapidly growing worldwide as petroleum based fuels are finite reserves. In this context, biodiesel and bioethanol are popular biofuels that are commercially available in various countries. Biofuels can be prepared from edible biomass. However, this is already generating food versus fuel debate among the members of civil societies. Therefore, there are needs to synthesize bio... hiện toàn bộ
Experimental and modelling studies on the uncatalysed thermal conversion of inulin to 5-hydroxymethylfurfural and levulinic acid
- 2015
Boy Arief Fachri, Ria M. Abdilla, Carolus Borromeus Rasrendra, Hero Jan Heeres
Recent advances on biobutanol production
Tập 2 - Trang 1-9 - 2014
Luiz J Visioli, Heveline Enzweiler, Raquel C Kuhn, Marcio Schwaab, Marcio A Mazutti
Recent studies have shown that butanol is a potential gasoline replacement that can also be blended in significant quantities with conventional diesel fuel. However, biotechnological production of butanol has some challenges such as low butanol titer, high cost feedstocks and product inhibition. The present work reviewed the technical and economic feasibility of the main technologies available to ... hiện toàn bộ
Using metrics and sustainability considerations to evaluate the use of bio-based and non-renewable Brønsted acidic ionic liquids to catalyse Fischer esterification reactions
Tập 1 - Trang 1-13 - 2013
James H Clark, Thomas J Farmer, Duncan J Macquarrie, James Sherwood
Ionic liquids have found uses in many applications, one of which is the joint solvation and catalysis of chemical transformations. Suitable Brønsted acidic ionic liquids can be formed by combining lactams with sulphonic acids. This work weighs up the relative benefits and disadvantages of applying these Brønsted acidic ionic liquid catalysts in esterifications through a series of comparisons using... hiện toàn bộ
Recent advances in application of chitosan in fuel cells
Tập 1 - Trang 1-12 - 2013
Hamideh Vaghari, Hoda Jafarizadeh-Malmiri, Aydin Berenjian, Navideh Anarjan
Fuel cells are electrochemical devices which convert chemical energy into electrical energy. Fuel cells have attracted attention due to their potential as a promising alternative to traditional power sources. More recently, efficient and environmentally benign biopolymer “chitosan” have been extensively investigated as a novel material for its application in fuel cells. This biopolymer can be used... hiện toàn bộ
An astute synthesis of locked nucleic acid monomers
Tập 3 - Trang 1-6 - 2015
Vivek K Sharma, Pallavi Rungta, Vipin K Maikhuri, Ashok K Prasad
Novel attributes of Locked Nucleic Acid (LNA) makes it preferable over most of the other classes of modified nucleic acid analogues and therefore, it has been extensively explored in different synthetic oligonucleotide based therapeutics. In addition to five oligonucleotides of this class undergoing clinical trials, a healthy pipeline in pre-clinical studies validates the tenacity of LNA. Due to t... hiện toàn bộ
Microwave-assisted catalytic esterification of α-glucoisosaccharino-1,4-lactone with tall oil fatty acids
Tập 4 - Trang 1-5 - 2016
Hemanathan Kumar, Raimo Alén
Carbohydrates-rich materials are partly degraded during alkaline kraft pulping into a complex mixture of aliphatic carboxylic acids consisting of α-glucoisosaccharinic acid as one of the main acids. On the other hand, crude tall oil, containing significant amounts fatty acids, is obtained as a by-product from kraft pulping. One interesting novel approach is to utilize chemically both these side-st... hiện toàn bộ
Carbamoylation of primary, secondary and aromatic amines by dimethyl carbonate in a flow system over solid catalysts
Tập 3 - Trang 1-7 - 2015
Magdalena Litwinowicz, Jacek Kijeński
Carbamate esters represent an important class of organic compounds which find wide application in chemical industry. Classical procedures for the preparation of carbamates are based on the reaction with a very risky compound - phosgene or phosgene derivatives. A phosgene-free flow-system synthesis of eight carbamates in the reaction of various amines with dimethyl carbonate has been presented. The... hiện toàn bộ