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Selective Void Deposition by Continuous, Ultrathin Ag Film Enabled Stable, High‐Performance AgNWs‐Based Transparent Heaters (Small 3/2025)
Small - Tập 21 Số 3 - 2025
Sanh Vo Thi, Thanh Tai Nguyen, Malkeshkumar Patel, P. K. Bhatnagar, Chanhyuk Choi, Junghyun Lee, Vinh Ai Dao, Joondong Kim
Fabrication of Stretchable Single-Walled Carbon Nanotube Logic Devices
Small - Tập 10 Số 14 - Trang 2910-2917 - 2014
Jangyeol Yoon, Gunchul Shin, Joonsung Kim, Young Sun Moon, Seung-Jung Lee, Goangseup Zi, Jeong Sook Ha
#SWCNT #stretchable #logic device #wavy configuration
Fabrication of Stretchable Single‐Walled Carbon Nanotube Logic Devices
Small - Tập 10 Số 14 - Trang 2910-2917 - 2014
Jangyeol Yoon, Gunchul Shin, Joonsung Kim, Young Sun Moon, Seung‐Jung Lee, Goangseup Zi, Jeong Sook Ha

The fabrication of a stretchable single‐walled carbon nanotube (SWCNT) complementary metal oxide semiconductor (CMOS) inverter array and ring oscillators is reported. The SWCNT CMOS inverter exhibits static voltage transfer characteristics with a maximum gain of 8.9 at a supply voltage of 5 V. The fabricated devices show stable electrical performance under the maximum strain of 30% via forming wavy configurations. In addition, the 3‐stage ring oscillator demonstrates a stable oscillator frequency of ∼3.5 kHz at a supply voltage of 10 V and the oscillating waveforms are maintained without any distortion under cycles of pre‐strain and release. The strains applied to the device upon deformation are also analyzed by using the classical lamination theory, estimating the local strain of less than 0.6% in the SWCNT channel and Pd electrode regions which is small enough to keep the device performance stable under the pre‐strain up to 30%. This work demonstrates the potential application of stretchable SWCNT logic circuit devices in future wearable electronics.

Selective Void Deposition by Continuous, Ultrathin Ag Film Enabled Stable, High‐Performance AgNWs‐Based Transparent Heaters
Small -
Sanh Vo Thi, Thanh Tai Nguyen, Malkeshkumar Patel, P. K. Bhatnagar, Chanhyuk Choi, Junghyun Lee, Vinh Ai Dao, Joondong Kim
Abstract

Metallic nanowire‐based transparent conductors (MNTCs) are essential to various technologies, including displays, heat‐regulating windows, and photo‐communication. Hybrid configurations are primarily adopted to design stable, high‐functioning MNTCs. Although hybrid MNTCs enhance electrical performance, they often suffer from optical degradation due to losses associated with the hybrid layers. Highly conductive hybrid MNTCs with minimal reduction in transparency are achieved with AgNWs/Ag(O)/Al‐doped ZnO (AZO) design. The design provides a high visible light transmittance of 95.1%, representing a minimized optical loss of 3% compared to pristine AgNWs by optimizing optical interference between the AZO and Ag(O) layers. Furthermore, it allows for enhanced mobility of metallic nanowires by controlling the selective formation of conductive layers in the voids of the nanowire networks. The oxygen additive enables a continuous Ag ultrathin film of 6 nm in the macro‐voids of AgNWs system, corresponding to 25 times higher mobility for AgNWs/Ag(O)/AZO than that of sole AgNWs. The significant enhancement in the mobility of AgNWs/Ag(O)/AZO induces a reduction of sheet resistance of MNTCs by 73%. The AgNWs/Ag(O)/AZO, with an optimized sheet resistance of 24 Ω sq−1, is explored for transparent heater applications, demonstrating a fast thermal response with reliable stability, as evidenced by consistent high‐temperature profiles during prolonged operation.

Subjecting a Graphene Monolayer to Tension and Compression
Small - Tập 5 Số 21 - Trang 2397-2402 - 2009
Georgia Tsoukleri, F. Schedin, K. Papagelis, R. Jalil, Andrea C. Ferrari, A. K. Geǐm, Kostya S. Novoselov, Costas Galiotis
Reusable Localized Surface Plasmon Sensors Based on Ultrastable Nanostructures
Small - Tập 6 Số 1 - Trang 104-109 - 2010
Nicolas Vogel, Mathieu Jung, Noelia L. Bocchio, Markus Retsch, Maximilian Kreiter, Ingo Köper
Abstract

Nanoparticle arrays created by nanosphere lithography are widely used in sensing applications since their localized surface plasmon resonances are extremely sensitive to changes in the local dielectric environment. A major drawback for any biologically oriented sensing application of conventionally produced particle arrays is the lack of stability of the nanoparticles in aqueous media and buffer solutions. Here, a robust and reusable nanoscale sensing platform based on localized surface plasmon resonances of gold nanoparticles embedded in a silicon dioxide matrix is presented. The architecture exhibits extremely high stability in aqueous environments and can be regenerated several times by simple mechanical cleaning of the surface. The platforms surface is ultraflat by design, thus making it an ideal substrate for any bio‐oriented sensing application.

Synergistic Effect of Electron Scattering and Space Charge Transfer Enabled Unprecedented Room Temperature NO2 Sensing Response of SnO2
Small - Tập 19 Số 48 - 2023
Yajie Zhang, Yadong Jiang, Zhen Yuan, Bohao Liu, Qiuni Zhao, Qi Huang, Ziteng Li, Wen Zeng, Zaihua Duan, Huiling Tai
Abstract

Metal oxide gas sensors have long faced the challenge of low response and poor selectivity, especially at room temperature (RT). Herein, a synergistic effect of electron scattering and space charge transfer is proposed to comprehensively improve gas sensing performance of n‐type metal oxides toward oxidizing NO2 (electron acceptor) at RT. To this end, the porous SnO2 nanoparticles (NPs) assembled from grains of about 4 nm with rich oxygen vacancies are developed through an acetylacetone‐assisted solvent evaporation approach combined with precise N2 and air calcinations. The results show that the as‐fabricated porous SnO2 NPs sensor exhibits an unprecedented NO2‐sensing performance, including outstanding response (Rg/Ra = 772.33 @ 5 ppm), fast recovery (<2 s), an extremely low detection limit (10 ppb), and exceptional selectivity (response ratio >30) at RT. Theoretical calculation and experimental tests confirm that the excellent NO2 sensing performance is mainly attributed to the unique synergistic effect of electron scattering and space charge transfer. This work proposes a useful strategy for developing high‐performance RT NO2 sensors using metal oxides, and provides an in‐depth understanding for the basic characteristics of the synergistic effect on gas sensing, paving the way for efficient and low power consumption gas detection at RT.

Bioinspired, Ultrastrong, Highly Biocompatible, and Bioactive Natural Polymer/Graphene Oxide Nanocomposite Films
Small - Tập 11 Số 34 - Trang 4298-4302 - 2015
Wenkun Zhu, Huai‐Ping Cong, Hong‐Bin Yao, Li‐Bo Mao, Abdullah M. Asiri, Khalid A. Alamry, Hadi M. Marwani, Shu‐Hong Yu
A Freestanding Stretchable and Multifunctional Transistor with Intrinsic Self‐Healing Properties of all Device Components
Small - Tập 15 Số 2 - 2019
Muhammad Khatib, Tan‐Phat Huynh, Yunfeng Deng, Yehu David Horev, Walaa Saliba, Weiwei Wu, Hossam Haick
Abstract

A flexible and stretchable field‐effect transistor (FET) is an essential element in a number of modern electronics. To realize the potential of this device in harsh real‐world conditions and to extend its application spectrum, new functionalities are needed to be introduced into the device. Here, solution‐processable elements based on carbon nanotubes that empower flexible and stretchable FET with high hole‐mobility (µh ≈ 10 cm2 V−1 s−1) and relatively low operating voltages (<8 V) and that retain self‐healing properties of all FET components are reported. The device has repeatable intrinsic and autonomic self‐healing ability, namely without use of any external trigger, enabling the restoration of its electrical and mechanical properties, both after microscale damage or complete cut of the device—for example by a scissor. The device can be repeatedly stretched for >200 cycles of up to 50% strain without a significant loss in its electrical properties. The device is applicable in the form of a ≈3 µm thick freestanding skin tattoo and has multifunctional sensing properties, such as detection of temperature and humidity. With this unprecedented biomimetic transistor, highly sustainable and reliable soft electronic applications can be introduced.

Drastic Enhancement of Photocatalytic Activities over Phosphoric Acid Protonated Porous g‐C3N4 Nanosheets under Visible Light
Small - Tập 12 Số 32 - Trang 4431-4439 - 2016
Li Shi, Kun Chang, Huabin Zhang, Xiao Hai, Liuqing Yang, Tao Wang, Jinhua Ye

A simple method is developed to fabricate protonated porous graphitic carbon nitride nanosheets (P‐PCNNS) by protonation–exfoliation of bulk graphitic carbon nitride (BCN) with phosphoric acid (H3PO4). The H3PO4 treatment not only helps to exfoliate the BCN into 2D ultrathin nanosheets with abundant micro‐ and mesopores, endowing P‐PCNNS with more exposed active catalytic sites and cross‐plane diffusion channels to facilitate the mass and charge transport, but also induces the protonation of carbon nitride polymer, leading to the moderate removal of the impurities of carbon species in BCN for the optimization of the aromatic π‐conjugated system for better charge separation without changing its chemical structure. As a result, the P‐PCNNS show much higher photocatalytic performance for hydrogen evolution and CO2 conversion than bare BCN and graphitic carbon nitride nanosheets.

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