Total Synthesis of Indole and Dihydroindole Alkaloids. XV. Further Chemistry of VindolineHelvetica Chimica Acta - Tập 61 Số 5 - Trang 1554-1564 - 1978
James P. Kutney, Ursula Bünzli-Trepp, Toshio Honda, Junki Katsube, Brian R. Worth
AbstractThe general reactivity of various sites in the vindoline series has been investigated. The facility of electrophilic substitution at C(15) and the effect of steric crowding on reactions at C(4) are discussed. At the basic nitrogen sites, oxidations with mercuric acetate and potassium permanganate are also discussed.
Microbial Transformation of Sesquiterpenes, (−)‐Ambrox® and (+)‐SclareolideHelvetica Chimica Acta - Tập 87 Số 10 - Trang 2685-2694 - 2004
M. Iqbal Choudhary, Syed Ghulam Musharraf, Amtul Jamil Sami, Atta‐ur Rahman
AbstractThe microbial transformation of (−)‐Ambrox® (1), a perfumery sesquiterpene, by a number of fungi, by means of standard two‐stage‐fermentation technique, afforded ambrox‐1α‐ol (2), ambrox‐1α,11α... hiện toàn bộ
Desorption/Chemical Ionization Mass Spectrometry of Naturally Occurring GlycosidesHelvetica Chimica Acta - Tập 64 Số 1 - Trang 297-303 - 1981
Kurt Hostettmann, J. Doumas, Michel Hardy
AbstractDesorption/chemical ionization mass spectrometry (D/CI.‐MS.) is a recently developed technique especially indicated for highly polar and non volatile compounds. Various naturally occurring glycosides such as saponins, iridoid and secoiridoid glycosides, cardenolides and flavone‐O‐glycosides have been investigated by this method. A...... hiện toàn bộ
Linear‐Reactor‐IR.‐Matrix and Microwave Spectroscopy of the System O3/NO2/(Z)‐2‐ButeneHelvetica Chimica Acta - Tập 65 Số 2 - Trang 504-520 - 1982
J. Dommen, Martin Förster, Heidi Ruprecht, A. Bauder, Hans‐Heinrich Günthard
AbstractInvestigation of the formation of complex reaction products in the gas‐phase system O3/NO2/(Z)‐2‐butene by combination of linear reactors with IR. matrix and microwave Stark Spectroscopy is reported. Besides the polyatomic products observed earlier in the gas‐pha...... hiện toàn bộ
Novel Naamidine‐Type Alkaloids and Mixed‐Ligand Zinc(II) Complexes from a Calcareous Sponge, Leucetta sp., of the Coral SeaHelvetica Chimica Acta - Tập 78 Số 5 - Trang 1178-1184 - 1995
Ines Mancini, Graziano Guella, Cécile Debitus, Francesco Pietra
AbstractAs compounds from a calcareous sponge, Leucetta sp., of the Coral Sea, we isolated a series of novel naamidine‐type alkaloids, 6–10, which are oxidized at a single benzylic position. We also report on the first marine, mixed‐ligand metal complex 5 and on the firs...... hiện toàn bộ
Über den Mechanismus der enzymatischen Verseifung von PektinstoffenHelvetica Chimica Acta - Tập 38 Số 1 - Trang 321-329 - 1955
J. Solms, H. Deuel
AbstractEs wird die Kinetik der enzymatischen Verseifung von verschiedenen Pektinstoffen durch Orangenpektinesterase untersucht. Die enzymatische Verseifung erfolgt stets unvollständig bis zu einem Veresterungsgrad von ca. 10%.