Recent developments on anode materials for magnesium-ion batteries: a review

Rare Metals - Tập 40 - Trang 290-308 - 2020
Qi Guo1, Wen Zeng1, Shi-Lin Liu1, Yan-Qiong Li2, Jun-Yao Xu1, Jin-Xing Wang1, Yu Wang3
1College of Materials Science and Engineering, Chongqing University, Chongqing, China
2School of Electronic and Electrical Engineering, Chongqing University of Arts and Sciences, Chongqing, China
3Shanghai Urban Construction Vocational College, Shanghai, China

Tóm tắt

In recent years, there has been significant growth in the demand for secondary batteries, and researchers are increasingly taking an interest in the development of next-generation battery systems. Magnesium-ion batteries (MIBs) have been recognized as the optimal alternative to lithium-ion batteries (LIBs) due to their low cost, superior safety, and environment-friendliness. However, research and development on rechargeable MIBs are still underway as some serious problems need to be resolved. One of the most serious obstacles is the generation of an irreversible passivation layer on the surface of the Mg anode during cycling. In addition to exploring new electrolytes for MIBs, alternative anode materials for MIBs might be an effective solution to this issue. In this review, the composition and working principle of MIBs have been discussed. In addition, recent advances in the area of anode materials (metals and their alloys, metal oxides, and two-dimensional materials) available for MIBs and the corresponding Mg-storage mechanisms have also been summarized. Further, feasible strategies, including structural design, dimension reduction, and introduction of the second phase, have been employed to design high-performance MIB anodes.

Tài liệu tham khảo

Liang X, Chen X, Zhao H, Yang Z, Wei F, Tu H. Preparation methods of nano-Ti02 electron transport layers and properties for perovskite solar cells. Chin J Rare Met. 2019;43(2):164.

Emsley J. Nature’s Building Blocks: an AZ Guide to the Elements. Oxford: Oxford University Press; 2011. 699.

Bucur CB. Challenges of a Rechargeable Magnesium Battery: a Guide to the Viability of this Post Lithium-ion Battery. Cham: Springer; 2018. 11.

Liu B, Luo T, Mu G, Wang X, Chen D, Shen G. Rechargeable Mg-ion batteries based on WSe2 nanowire cathodes. ACS Nano. 2013;7(9):8051.

Choi SH, Kim JS, Woo SG, Cho W, Choi SY, Choi J, Lee KT, Park MS, Kim YJ. Role of Cu in Mo6S8 and Cu mixture cathodes for magnesium ion batteries. ACS Appl Mater Interfaces. 2015;7(12):7016.

Luo J, Maggard PA. Hydrothermal synthesis and photocatalytic activities of SrTiO3-coated Fe2O3 and BiFeO3. Adv Mater. 2006;18(4):514.

Usui H, Yoshioka S, Wasada K, Shimizu M, Sakaguchi H. Nb-doped rutile TiO2: a potential anode material for Na-ion battery. ACS Appl Mater Interfaces. 2015;7(12):6567.

Lee J, Monserrat B, Seymour ID, Liu Z, Dutton SE, Grey CP. An ab initio investigation on the electronic structure, defect energetics, and magnesium kinetics in Mg3Bi2. J Mater Chem A. 2018;6(35):16983.

Wu Q, Xu J, Yang X, Lu F, He S, Yang J, Fan HJ, Wu M. Ultrathin anatase TiO2 nanosheets embedded with TiO2–B nanodomains for lithium-ion storage: capacity enhancement by phase boundaries. Adv Energy Mater. 2015;5(7):1401756.

Chen C, Xu H, Zhou T, Guo Z, Chen L, Yan M, Mai L, Hu P, Cheng S, Huang Y. Integrated intercalation-based and interfacial sodium storage in graphene-wrapped porous Li4Ti5O0 nanofibers composite aerogel. Adv Energy Mater. 2016;6(13):1600322.

Chen C, Wang J, Zhao Q, Wang Y, Chen J. Layered Na2Ti3O7/MgNaTi3O7/Mg0.5NaTi3O7 nanoribbons as high-performance anode of rechargeable Mg-ion batteries. ACS Energy Lett. 2016;1(6):1165.

Luo L, Zhen Y, Lu Y, Zhou K, Huang J, Huang Z, Mathur S, Hong Z. Structural evolution from layered Na2Ti3O7 to Na2Ti6O13 nanowires enabling a highly reversible anode for Mg-ion batteries. Nanoscale. 2020;12(1):230.

Li H, Liu X, Zhai T, Li D, Zhou H. Li3VO4: a promising insertion anode material for lithium-ion batteries. Adv Energy Mater. 2013;3(4):428.