A systematic study on chemically deposited cadmium sulfide (CdS) thin film

Journal of Theoretical and Applied Physics - Tập 14 - Trang 265-274 - 2020
Saiful Islam1,2, Tasnia Hossain3, Hasan Sarwar4, Mohammad Junaebur Rashid2
1Department of Information and Communication Technology, Bangladesh University of Professionals, Dhaka, Bangladesh
2Department of Electrical and Electronic Engineering, University of Dhaka, Dhaka, Bangladesh
3Department of Electrical and Electronic Engineering, University of Asia Pacific, Dhaka, Bangladesh
4Department of Computer Science and Engineering, United International University, Dhaka, Bangladesh

Tóm tắt

In this work, the conventional chemical bath deposition (CBD) technique and its growth parameters were systematically studied to deposit CdS thin films on the glass substrate. The samples were prepared using a simple aqueous solution containing cadmium sulfate (CdSO4·8H2O), thiourea [SC(NH2)2], ammonium sulfate [(NH4)2SO4] as a source of cadmium, sulfur, and a complexing agent, respectively. The deposited films were characterized to study the surface morphology, crystallographic structure, chemical composition, optical and electrical properties. Through this study, the structure was determined to cubic with (111) preferential orientation and the crystallinity of the films was improved with the increase of film thickness. The transmission spectra were recorded in the range of wavelength 300–600 nm. The optical bandgap of the optimized CdS films was varied from 2.43 to 2.74 eV. All the films exhibit n-type of conductivity which was found in the order of 10–4 to 10–5 (1/Ω-cm), suggesting that it would be suitable for the buffer layer in thin-film solar cells.

Tài liệu tham khảo

Niu, X., Zhu, H., Liang, X., Guo, Y., Li, Z., Mai, Y.: Air-annealing of Cu(In, Ga)Se2/CdS and performances of CIGS solar cells. Appl. Surf. Sci. 426, 1213–1220 (2017). https://doi.org/10.1016/j.apsusc.2017.07.212

Chander, S., Dhaka, M.S.: Optical and structural constants of CdS thin films grown by electron beam vacuum evaporation for solar cells. Thin Solid Films 638, 179–188 (2017). https://doi.org/10.1016/j.tsf.2017.07.048

Munirah, S.K., Mohd, A.A., Abdul, R.S., Raza, K.Z.: Spectroscopic studies of sol–gel grown CdS nanocrystalline thin films for optoelectronic devices. Mater. Sci. Semicond. Process. 16, 1894–1898 (2013). https://doi.org/10.1016/j.mssp.2013.07.010

Kumarage, W.G.C., Wijesundara, L.B.D.R.P., Seneviratne, V.A., Jayalath, C.P., Dassanayake, B.S.: Influence of bath temperature on CBD-CdS thin films. Procedia Eng. 139, 64–68 (2016). https://doi.org/10.1016/j.proeng.2015.09.215

Lisco, F., Kaminski, P.M., Abbas, A., Bass, K., Bowers, J.W., Claudio, G., Losurdo, M., Walls, J.M.: The structural properties of CdS deposited by chemical bath deposition and pulsed direct current magnetron sputtering. Thin Solid Films 582, 323–327 (2015). https://doi.org/10.1016/j.tsf.2014.11.062

Al-Fouadi, A.H.A., Hussain, D.H., Rahim, H.A.: Surface topography study of CdS thin film nanostructure synthesized by CBD. Optik 131, 932–940 (2017). https://doi.org/10.1016/j.ijleo.2016.11.175

Kumarage, W.G.C., Wijesundera, R.P., Seneviratne, V.A., Jayalath, C.P., Varga, T., Nandasiri, M.I., Dassanayake, B.S.: Growth and characterization of EDTA assisted CBD-CdS. Mater. Chem. Phys. 200, 1–8 (2017). https://doi.org/10.1016/j.matchemphys.2017.07.052

Zia, R., Riaz, M., Ain, Q., Anjum, S.: Study the effect of thiourea concentration on optical and structural properties of CdS-nanocrystalline thin films prepared by CBD technique. Opt. Int. J. Light Electron Opt. 127, 5407–5412 (2016). https://doi.org/10.1016/j.ijleo.2016.02.081

Islam, M.A., Hossain, M.S., Aliyu, M.M., Chelvanathan, P., Huda, Q., Karim, M.R., Sopian, K., Amin, N.: Comparison of structural and optical properties of CdS thin films grown by CSVT. CBD Sputter. Tech. Energy Procedia. 33, 203–213 (2013)

Popescu, V., Picǎ, E.M., Pop, I., Grecu, R.: Optical properties of cadmium sulfide thin films, chemically deposited from baths containing surfactants. Thin Solid Films 349, 67–70 (1999). https://doi.org/10.1016/S0040-6090(99)00177-7

Ikhmayies, S.J., Ahmad-Bitar, R.N.: A study of the optical bandgap energy and Urbach tail of spray-deposited CdS: In thin films. J. Mater. Res. Technol. 2, 221–227 (2013). https://doi.org/10.1016/j.jmrt.2013.02.012