A review of the innovations in metal- and carbon-based catalysts explored for heterogeneous peroxymonosulfate (PMS) activation, with focus on radical vs. non-radical degradation pathways of organic contaminants

Feng, 2015, Efficient degradation of sulfamethazine with CuCo2O4 spinel nanocatalysts for peroxymonosulfate activation, Chem. Eng. J., 280, 514, 10.1016/j.cej.2015.05.121

Huang, 2018, Enhanced peroxymonosulfate activation for phenol degradation over MnO2 at pH 3.5–9.0 via Cu(II) substitution, J. Hazard. Mater., 360, 303, 10.1016/j.jhazmat.2018.08.028

Chen, 2018, Degradation of norfloxacin by CoFe2O4-GO composite coupled with peroxymonosulfate: A comparative study and mechanistic consideration, Chem. Eng. J., 334, 273, 10.1016/j.cej.2017.10.040

Fanaei, 2019, The enhanced catalytic potential of sulfur-doped MgO (S-MgO) nanoparticles in activation of peroxysulfates for advanced oxidation of acetaminophen, Chem. Eng. J., 371, 404, 10.1016/j.cej.2019.04.007

Yao, 2017, Enhanced degradation performance of sulfisoxazole using peroxymonosulfate activated by copper-cobalt oxides in aqueous solution: Kinetic study and products identification, Chem. Eng. J., 330, 345, 10.1016/j.cej.2017.07.155

Ding, 2016, Efficient degradation of carbamazepine by easily recyclable microscaled CuFeO2 mediated heterogeneous activation of peroxymonosulfate, J. Hazard. Mater., 317, 686, 10.1016/j.jhazmat.2016.06.004

Rodriguez-Chueca, 2019, Solar-assisted bacterial disinfection and removal of contaminants of emerging concern by Fe2+-activated HSO5- vs. S2O82- in drinking wáter, Appl. Catal. B: Environ., 248, 62, 10.1016/j.apcatb.2019.02.018

Ren, 2015, Effect of sulfate radical oxidation on disintegration of waste activated sludge, Int. Biodeterior. Biodegrad., 104, 384, 10.1016/j.ibiod.2015.07.008

Tian, 2017, A novel singlet oxygen involved peroxymonosulfate activation mechanism for degradation of ofloxacin and phenol in water, Chem. Commun., 53, 6589, 10.1039/C7CC02820B

Oh, 2016, Generation of sulfate radical through heterogeneous catalysis for organic contaminants removal: Current development, challenges and prospects, Appl. Catal. B, 194, 169, 10.1016/j.apcatb.2016.04.003

Wang, 2017, Activation of peroxymonosulfate by Al2O3-based CoFe2O4 for the degradation of sulfachloropyridazine sodium: Kinetics and mechanism, Sep. Purif. Technol., 189, 176, 10.1016/j.seppur.2017.07.046

He, 2020, Synergistic multiple active species for the degradation of sulfamethoxazole by peroxymonosulfate in the presence of CuO@FeOx@Fe0, Chem. Eng. J., 380, 122568, 10.1016/j.cej.2019.122568

Zhu, 2020, Activation of peroxymonosulfate by magnetic Co-Fe/SiO2 layered catalyst derived from iron sludge for ciprofloxacin degradation, Chem. Eng. J., 384, 123298, 10.1016/j.cej.2019.123298

Fan, 2020, Degradation mechanisms of ofloxacin and cefazolin uing peroxymonosulfate activated by reduced graphene oxide-CoFe2O4 composites, Chem. Eng. J., 383, 10.1016/j.cej.2019.123056

Guan, 2011, Influence of pH on the Formation of Sulfate and Hydroxyl Radicals in the UV/Peroxymonosulfate System, Environ. Sci. Technol., 45, 9308, 10.1021/es2017363

Giannakis, 2021, A review of the recent advances on the treatment of industrial wastewaters by Sulfate Radical-based Advanced Oxidation Processes (SR-AOPs), Chem. Eng. J., 406, 127083, 10.1016/j.cej.2020.127083

Tan, 2019, Novel activation of peroxymonosulfate by an easily recyclable VC@Fe3O4 nanoparticles for enhanced degradation of sulfadiazine, Chem. Eng. J., 363, 318, 10.1016/j.cej.2019.01.145

J. Deng, S. Feng, K. Zhang, J. Li, H. Wang, T. Zhang, X. Ma, Heterogeneous activation of peroxymonosulfate using ordered mesoporous Co3O4 for the degradation of chloramphenicol at neutral pH, Chem. Eng. J. 308 (2017) 505-515. https://doi.org/10.1016/j.cej.2016.09.075.

Chen, 2019, Rational design and synthesis of hollow Co3O4@Fe2O3 core-shell nanostructure for the catalytic degradation of norfloxacin by coupling with peroxymonosulfate, Chem. Eng. J., 359, 373, 10.1016/j.cej.2018.11.120

Lashkaryani, 2019, Activation of peroxymonosulfate into amoxicillin degradation using cobalt ferrite nanoparticles anchored on graphene (CoFe2O4@Gr), Tokin Rev., 1

Li, 2019, Peroxymonosulfate activation for efficient sulfamethoxazole degradation by Fe3O4/β-FeOOH nanocomposites: Coexistence of radical and non-radical reactions, Chem. Eng. J., 356, 904, 10.1016/j.cej.2018.09.064

Shao, 2017, Synergetic Activation of Peroxymonosulfate by Co3O4 Modified g-C3N4 for Enhanced Degradation of Diclofenac Sodium under Visible Light Irradiation, Appl. Catal. B: Environ., 218, 810, 10.1016/j.apcatb.2017.07.016

Liu, 2020, Enhanced thermal activation of peroxymonosulfate by activated carbon for efficient removal of perfluorooctanoic acid, Chem. Eng. J., 399, 125722, 10.1016/j.cej.2020.125722

Khan, 2017, Synergistic degradation of phenols using peroxymonosulfate activated by CuO-Co3O4@MnO2 nanocatalyst, J. Hazard. Mater., 329, 262, 10.1016/j.jhazmat.2017.01.029

Han, 2020, The oxidative degradation of diclofenac using the activation of peroxymonosulfate by BiFeO3 microspheres—Kinetics, role of visible light and decay pathways, Sep. Purif. Technol., 232, 115967, 10.1016/j.seppur.2019.115967

Y. Wang, H. Sun, H. M. Ang, M. O. Tade, S. Wang, Facile synthesis of hierarchically structured magnetic MnO2/ZnFe2O4 hybrid materials and their performance in heterogeneous activation of peroxymonosulfate, ACS Appl. Mater. Interfaces. 22 (2014) 19914-19923. https://doi.org/10.1021/am505309b.

Yang, 2020, Rapid removal of tetrabromobisphenol A by α-Fe2O3-x@Graphene@Montmorillonite catalyst with oxygen vacancies through peroxymonosulfate activation: Role of halogen and α-hydroxyalkyl radicals, Appl. Catal. B, 260, 118129, 10.1016/j.apcatb.2019.118129

X. Dong, X. Duan, Z. Sun, X. Zhang, C. Li, S. Yang, B. Ren, S. Zheng, D. D. Dionysiou, Natural illite-based ultrafine cobalt oxide with abundant oxygen-vacancies for highly efficient Fenton-like catalysis, Appl. Catal. B: Environ. 261 (2020) 118214. https://doi.org/j.apcatb.2019.118214.

Zhu, 2019, Persulfate Activation on Crystallographic Manganese Oxides: Mechanism of Singlet Oxygen Evolution for Nonradical Selective Degradation of Aqueous Contaminants, Environ. Sci. Technol., 53, 307, 10.1021/acs.est.8b04669

Luo, 2019, Singlet oxygen-dominated non-radical oxidation process for efficient degradation of bisphenol A under high salinity condition, Water Res., 148, 416, 10.1016/j.watres.2018.10.087

Saputa, 2020, carbon-supported manganese for heterogeneous activation of peroxymnosulfate for the decomposition of phenol in aqueous solution, Mater. Today. Chem., 16

Zhao, 2017, Metal-free carbon materials-catalyzed sulfate radical-based advanced oxidation processes: A review on heterogeneous catalysts and applications, Chemosphere, 189, 224, 10.1016/j.chemosphere.2017.09.042

Chen, 2018, Efficient heterogeneous activation of peroxyonosulfate by facilely prepared Co/Fe bimetallic oxides: Kinetics and mechanism, Chem. Eng. J., 345, 364, 10.1016/j.cej.2018.03.169

Oh, 2017, Hierarchically-structured Co–CuBi 2 O 4 and Cu–CuBi 2 O 4 for sulfanilamide removal via peroxymonosulfate activation, Catal. Today, 280, 2, 10.1016/j.cattod.2016.04.043

Duan, 2016, Occurrence of radical and nonradical pathways from aqueous and nonaqueous catalytic oxidation, Appl. Catal. B: Environ., 188, 98, 10.1016/j.apcatb.2016.01.059

Zhang, 2020, Glucose and melamine derived nitrogen-doped carbonaceous catalyst for nonradical peroxymonosufate activation, Carbon, 156, 399, 10.1016/j.carbon.2019.09.050

Ma, 2018, Non-radical-dominated catalytic degradation of bisphenol A by ZIF-67 derived nitrogen-doped carbon nanotubes frameworks in the presence of peroxymonosulfate, Chem. Eng. J., 336, 721, 10.1016/j.cej.2017.11.164

Frank, 2009, Heteroatoms Increase the Selectivity in Oxidative Dehydrogenation Reactions on Nanocarbons, Angew. Chem. Int. Ed., 48, 6913, 10.1002/anie.200901826

Li, 2020, Enhanced peroxymonosulfate activation by supported microporous carbón for degradation of tetracycline via non-radical mechanism, Sep. Purif. Technol., 240, 10.1016/j.seppur.2020.116617

Gao, 2020, New insight into the generation of singlet oxygen in the metal-free peroxymonosulfate activation process: Important role of electron-deficient carbon atoms, Environ. Sci. Technol., 54, 1232, 10.1021/acs.est.9b05856

Ye, 2020, Nitrogen-doped biochar fiber with graphitization from Boehmeria nivea for promoted peroxymonosulfate activation and non-radical degradation pathways with enhancing electron transfer, Appl. Catal. B, 269, 118850, 10.1016/j.apcatb.2020.118850

Huang, 2018, Superior performance of α@β-MnO2 or the toluene oxidation: Active interface and oxygen vacancy, Appl. Catal. A., 560, 195, 10.1016/j.apcata.2018.05.001

Zhu, 2017, Surface oxygen vacancy induced α-MnO 2 nanofiber for highly efficient ozone elimination, Appl. Catal. B, 209, 729, 10.1016/j.apcatb.2017.02.068

Wu, 2019, A novel magnetic heterogeneous catalyst oxygen-defective CoFe2O4−x for activating peroxymonosulfate, Appl. Surf. Sci., 480, 717, 10.1016/j.apsusc.2019.03.034

Tian, 2018, Controlled synthesis of dandelion-like NiCo2O4 microspheres and their catalytic performance for peroxymonosulfate activation in humic acid degradation, Chem. Eng. J., 331, 144, 10.1016/j.cej.2017.08.115

Guo, 2019, Activation of peroxymonosulfate by magnetic carbon supported Prussian blue nanocomposite for the degradation of organic contaminants with singlet oxygen and superoxide radicals, Chemosphere, 218, 1071, 10.1016/j.chemosphere.2018.11.197

C. Chen, L. Liu, Y. Li, W. Li, L. Zhou, Y. Lan, Y. Li, Insight into heterogeneous catalytic degradation of sulfamethazine by peroxymonosulfate activated with CuCo2O4 derived from bimetallic oxalate, Chem. Eng. J. 384 (2020) 123257. https://doi.org/10.106/j.cej.2019.123257.

J. Lu, Z. Xiong, Z. Xu, Y. Cai, Q. Wang, Activation of peroxymonosulfate with magnetic and recyclable Fe3O4@C/MnCo2O4 nanocomposites for the decolorization of Acid Orange II, Chem. Technol. Biotechnol. 92 (7) (2017) 1601-1612. https://doi.org/10.1002/jctb.5153.

H. Li, C. Shan, B. Pan, Fe(III)-doped g-C3N4 mediated peroxymonosulfate activation for selective degradation of phenolic compounds via high-valent Iron-Oxo species, Environ. Sci. Technol. 52 (4) (2018) 2197-2205. https://doi.org/10.1021/acs.est.7b05563.

Tan, 2014, Radical induced degradation of acetaminophen with Fe3O4 magnetic nanoparticles as heterogeneous activation of peroxymonosulfate, J. Hazard. Mater., 276, 452, 10.1016/j.jhazmat.2014.05.068

L. Zhang, T. Tong, N. Wang, W. Ma, B. Sun, J. Chu, K. A. Lin, Y. Du, Facile synthesis of yolk-shell Mn3O4 microspheres as a high-performance peroxymonosulfate activator for bisphenol A degradation, Ind. Eng. Chem. Res. 58 (47) (2019) 21304-21311. https://doi.org/10.1021/acs.iecr.9b03814.

Zhao, 2020, Oxygen vacancies induced heterogeneous catalysis of peroxymonosulfate by Ni-doped AgFeO2 materials: Evolution of reactive oxygen species and mechanism, Chem. Eng. J., 388, 124371, 10.1016/j.cej.2020.124371

Li, 2019, Singlet oxygen dominated peroxymonosulfate activation by CuO-CeO2 for organic pollutants degradation: Performance and mechanism, Chemosphere, 233, 549, 10.1016/j.chemosphere.2019.05.291

Zhao, 2019, Impact of crystal types of AgFeO2 nanoparticles on the peroxymonosulfate activation in the water, Environ. Sci. Technol., 53, 4500, 10.1021/acs.est.9b00658

Li, 2020, Structure-dependent catalysis of cuprous oxides in peroxymonosulfate activation via nonradical pathway with a high oxidation capacity, J. Hazard. Mater., 385, 121518, 10.1016/j.jhazmat.2019.121518

Wang, 2020, A stable and easily prepared copper oxide catalyst for degradation of organic pollutants by peroxymonosulfate activation, J. Hazard. Mater., 387, 121995, 10.1016/j.jhazmat.2019.121995

Chen, 2008, Performance of nano-Co3O4/peroxymonosulfate system: Kinetics and mechanism study using Acid Orange 7 as a model compound, Appl. Catal. B, 80, 116, 10.1016/j.apcatb.2007.11.009

Ji, 2013, Efficient performance of porous F2O3 in heterogeneous activation of peroxymonosulfate for decolorization of Rhodamine B, Chem. Eng. J., 231, 434, 10.1016/j.cej.2013.07.053

Wang, 2015, 3D-hierarchically structured MnO2 for catalytic oxidation of phenol solutions by activation of peroxymonosulfate: Structure dependence and mechanism, Appl. Catal. B, 164, 159, 10.1016/j.apcatb.2014.09.004

Gu, 2014, Solvent effect on the solvothermall synthesis of mesoporous NiO catalysts for activation of peroxymonosulfate to degrade organic dyes, ACS Omega, 4, 17672, 10.1021/acsomega.9b01883

Fan, 2018, Synthesis of different crystallographic FeOOH catalysts for peroxymonosulfate activation towards organic matter degradation, RSC Adv., 8, 7269, 10.1039/C7RA12615H

Deng, 2017, Degradation of ciprofloxacin using α-MnO2 activated peroxymonosulfate process: Effect of water constituents, degradation intermediates and toxicity evaluation, Chem. Eng. J., 330, 1390, 10.1016/j.cej.2017.07.137

Tang, 2015, Efficient activation of peroxymonosulfate by manganese oxide for the degradation of azo dye at ambient condition, J. Colloid Interface Sci., 454, 44, 10.1016/j.jcis.2015.05.009

Deng, 2016, Heterogeneous degradation of Orange II with peroxymonosulfate activated by ordered mesoporous MnFe2O4, Sep. Purif. Technol., 167, 181, 10.1016/j.seppur.2016.04.035

Huang, 2017, Degradation of bisphenol A by peroxymonosulfate catalytically activated with Mn1.8O1.2O4 nanospheres: Synthesis between Mn and Fe, Environ. Sci. Technol., 51, 12611, 10.1021/acs.est.7b03007

Zhou, 2018, Efficient degradation of 2,4-dichlorophenol in aqueous solution by peroxymonosulfate activated with magnetic spinel FeCo2O4 nanoparticles, Chemosphere, 197, 670, 10.1016/j.chemosphere.2018.01.079

Hu, 2018, Optimization of the catalytic activity of a ZnCo2O4 catalyst in peroxymonosulfate activation for bisphenol A removal using response surface methodology, Chemosphere, 212, 152, 10.1016/j.chemosphere.2018.08.065

Guan, 2013, Efficient degradation of atrazine by magnetic porous copper ferrite catalyzed peroxymonosulfate oxidation via the formation of hydroxyl and sulfate radicals, Water Res., 47, 5431, 10.1016/j.watres.2013.06.023

Xu, 2019, A novel combination of bioelectrochemical system with peroxymonosulfate oxidation for enhanced azo dye degradation and MnFe2O4 catalyst regeneration, Chemosphere, 217, 800, 10.1016/j.chemosphere.2018.11.077

Yao, 2015, Sulfate radicals iduced from peroxymonosulfate by cobalt manganese oxides (CoxMN3-xO4) for Fenton-like reaction in water, J. Hazard. Mater., 296, 128, 10.1016/j.jhazmat.2015.04.014

Qin, 2018, Mechanistic understanding of polychlorinated biphenyls degradation by peroxymonosulfate activated with CuFe2O4 nanoparticles: Key role of superoxide radicals, Chem. Eng. J., 348, 526, 10.1016/j.cej.2018.04.215

Fu, 2019, Activation of peroxymonosulfate by graphitized hierarchical porous biochar and MnFe2O4 magnetic nanoarchitecture for organic pollutants degradation: Structure dependence and mechanism, Chem. Eng. J., 360, 157, 10.1016/j.cej.2018.11.207

Jaafarzadeh, 2017, Efficient degradation of 2,4-dichlorophenoxyacetic acid by peroxymonosulfate/magnetic copper ferrite nanoparticles/ozone: A novel combination of advanced oxidation processes, Chem. Eng. J., 320, 436, 10.1016/j.cej.2017.03.036

Du, 2019, Facile preparation of porous Mn/Fe3O4 cubes as peroxymonosulfate activating catalyst for effective bisphenol A degradation, Chem. Eng. J., 376, 119193, 10.1016/j.cej.2018.05.177

Chen, 2020, Enhanced degradation of triclosan by cobalt manganese spinel-type oxide activated peroxymonosulfate oxidation process via sulfate radicals and singlet oxygen: Mechanisms and intermediates identification, Sci. Total Environ., 711, 134715, 10.1016/j.scitotenv.2019.134715

Othman, 2020, Catalytic activation of peroxymonosulfate using CeVO4 for phenol degradation: An insight into the reaction pathway, Appl. Catal. B, 266, 118601, 10.1016/j.apcatb.2020.118601

Li, 2020, Innovatively employing magnetic CuO nanosheet to activate peroxymonosulfate for the treatment of high-salinity organic wastewater, J. Environ. Sci., 88, 46, 10.1016/j.jes.2019.07.011

Zhou, 2020, Enhanced activation of peroxymonosulfate using oxygen vacancy-enriched FeCo2O4−x spinel for 2,4-dichlorophenol removal: Singlet oxygen-dominated nonradical process, Colloids Surf., A, 597, 124568, 10.1016/j.colsurfa.2020.124568

Liu, 2018, Heterogeneous activation of peroxymonosulfate by sillenite Bi25FeO40: Singlet oxygen generation and degradation for aquatic levofloxacin, Chem. Eng. J., 343, 128, 10.1016/j.cej.2018.02.125

Li, 2020, Heterogeneous activation of peroxymonosulfate by hierarchically porous cobalt/iron bimetallic oxide nanosheets for degradation of phenol solutions, Chemosphere, 256, 127160, 10.1016/j.chemosphere.2020.127160

Chen, 2020, Simultaneous removal of para-arsanilic acid and the released inorganic arsenic species by CuFe2O4 activated peroxymonosulfate process, Sci. Total Environ., 742, 140587, 10.1016/j.scitotenv.2020.140587

Deng, 2017, Mesoporous manganese Cobaltite nanocages as effective and reusable heterogeneous peroxymonosulfate activators for Carbamazepine degradation, Chem. Eng. J., 330, 505, 10.1016/j.cej.2017.07.149

Jawad, 2020, Tuning of Persulfate Activation from a Free Radical to a Nonradical Pathway through the Incorporation of Non-Redox Magnesium Oxide, Environ. Sci. Technol., 54, 2476, 10.1021/acs.est.9b04696

Chen, 2019, Novel magnetic MnO2/MnFe2O4 nanocomposite as a heterogeneous catalyst for activation of peroxymonosulfate (PMS) toward oxidation of organic pollutants, Sep. Purif. Technol., 213, 456, 10.1016/j.seppur.2018.12.049

Li, 2015, Catalytic degradation of bisphenol A by CoMnAl mixed metal oxides catalyzed peroxymonosulfate: Performance and mechanism, Chem. Eng. J., 279, 93, 10.1016/j.cej.2015.05.001

Stoyanova, 2014, Catalytic performance of supported nanosized cobalt and iron–cobalt mixed oxides on MgO in oxidative degradation of Acid Orange 7 azo dye with peroxymonosulfate, Appl. Catal. A, 476, 121, 10.1016/j.apcata.2014.02.024

Zhang, 2019, Efficient degradation of atrazine by LaCoO3/Al2O3 catalyzed peroxymonosulfate: Performance, degradation intermediates and mechanism, Chem. Eng. J., 372, 796, 10.1016/j.cej.2019.04.188

Zhang, 2020, Surface oxygen vacancy inducing peroxymonosulfate activation through electron donation of pollutants over cobalt-zinc ferrite for water purification, Appl. Catal. B, 270, 118874, 10.1016/j.apcatb.2020.118874

Du, 2016, Magnetic CoFe2O4 nanoparticles supported on titanate nanotubes (CoFe2O4/TNTs) as a novel heterogeneous catalyst for peroxymonosulfate activation and degradation of organic pollutants, J. Hazard. Mater., 308, 58, 10.1016/j.jhazmat.2016.01.035

Saputra, 2014, Shape-controlled activation of peroxymonosulfate by single crystal α-Mn2O3 for catalytic phenol degradation in aqueous solution, Appl. Catal. B, 154-155, 246, 10.1016/j.apcatb.2014.02.026

Shukla, 2011, Co-SBA-15 for heterogeneous oxidation of phenol with sulfate radical for wastewater treatment, Catal. Today, 175, 380, 10.1016/j.cattod.2011.03.005

Liu, 2015, Activation of peroxymonosulfate with magnetic Fe3O4–MnO2 core–shell nanocomposites for 4-chlorophenol degradation, Chem. Eng. J., 262, 854, 10.1016/j.cej.2014.10.043

Deng, 2017, Magnetic EDTA functionalized CoFe2O4 nanoparticles (EDTA-CoFe2O4) as a novel catalyst for peroxymonosulfate activation and degradation of Orange G, Environ Sci Pollut Res, 24, 11536, 10.1007/s11356-017-8811-1

Liang, 2012, Excellent performance of mesoporous Co3O4/MnO2 nanoparticles in heterogeneous activation of peroxymonosulfate for phenol degradation in aqueous solutions, Appl. Catal. B, 127, 330, 10.1016/j.apcatb.2012.09.001

Li, 2017, Peroxymonosulfate activation and pollutants degradation over highly dispersed CuO in manganese oxide octahedral molecular sieve, Appl. Surf. Sci., 422, 754, 10.1016/j.apsusc.2017.06.118

Hu, 2017, Facile synthesis of novel Co3O4-Bi2O3 catalysts and their catalytic activity on bisphenol A by peroxymonosulfate activation, Chem. Eng. J., 326, 1095, 10.1016/j.cej.2017.05.168

Deng, 2019, Iron-doped ordered mesoporous Co3O4 activation of peroxymonosulfate for ciprofloxacin degradation: Performance, mechanism and degradation pathway, Sci. Total Environ., 658, 343, 10.1016/j.scitotenv.2018.12.187

Yuan, 2018, Nanostructured Co3O4 grown on nickel foam: An efficient and readily recyclable 3D catalyst for heterogeneous peroxymonosulfate activation, Chemosphere, 198, 204, 10.1016/j.chemosphere.2018.01.135

J. Lim, Y. Yang, M. R. Hoffmann, Activation of Peroxymonosulfate by Oxygen Vacancies-Enriched Cobalt-Doped Black TiO2 Nanotubes for the Removal of Organic Pollutants, Environ. Sci. Technol. 53 (12) (2019) 6972-6980. https://doi.org/10.1021/acs.est.9b01449.

Zheng, 2019, Efficient degradation of atrazine with porous sulfurized Fe2O3 as catalyst for peroxymonosulfate activation, Appl. Catal. B, 259, 118056, 10.1016/j.apcatb.2019.118056

Yu, 2019, Stable incorporation of MnOx quantum dots into N-doped hollow carbon: A synergistic peroxymonosulfate activator for enhanced removal of bisphenol A, Sep. Purif. Technol., 213, 264, 10.1016/j.seppur.2018.12.044

Wang, 2017, Heterogeneous degradation of refractory pollutants by peroxymonosulfate activated by CoOx-doped ordered mesoporous carbon, Chem. Eng. J., 328, 1112, 10.1016/j.cej.2017.07.042

Yu, 2020, Oxygen-defective MnO2−x rattle-type microspheres mediated singlet oxygen oxidation of organics by peroxymonosulfate activation, Chem. Eng. J., 394, 124458, 10.1016/j.cej.2020.124458

Tokudome, 2016, Layered Double Hydroxide Nanoclusters: Aqueous, Concentrated, Stable, and Catalytically Active Colloids toward Green Chemistry, ACS Nano, 10, 5550, 10.1021/acsnano.6b02110

Ganiyu, 2017, A hierarchical CoFe-layered double hydroxide modified carbon-felt cathode for heterogeneous electro-Fenton process, J. Mater. Chem. A, 5, 3655, 10.1039/C6TA09100H

Zhao, 2018, Co-Mn layered double hydroxide as an effective heterogeneous catalyst for degradation of organic dyes by activation of peroxymonosulfate, Chemosphere, 204, 11, 10.1016/j.chemosphere.2018.04.023

Gong, 2017, Heterogeneous activation of peroxymonosulfate by Fe-Co layered doubled hydroxide for efficient catalytic degradation of Rhoadmine B, Chem. Eng. J., 321, 222, 10.1016/j.cej.2017.03.117

Hou, 2019, Heterogeneous activation of peroxymonosulfate using Mn-Fe layered double hydroxide: Performance and mechanism for organic pollutant degradation, Sci. Total Environ., 663, 453, 10.1016/j.scitotenv.2019.01.190

Zeng, 2018, Degradation of dyes by peroxymonosulfate activated by ternary CoFeNi-layered double hydroxide: Catalytic performance, mechanism and kinetic modeling, J. Colloid Interface Sci., 515, 92, 10.1016/j.jcis.2018.01.016

Lu, 2019, Efficient degradation of nitrobenzene by Cu-Co-Fe-LDH catalyzed peroxymonosulfate to produce hydroxyl radicals, Chem. Eng. J., 357, 140, 10.1016/j.cej.2018.09.111

Neta, 1977, Rate constants and mechanism of reaction of sulfate radical anion with aromatic compounds, J. Am. Chem. Soc., 99, 163, 10.1021/ja00443a030

Zou, 2016, Superior coagulation of graphene oxides on nanoscale layered double hydroxides and layered double oxides, Environ. Pollut., 219, 107, 10.1016/j.envpol.2016.10.052

Yao, 2017, Enhanced removal of methyl orange on calcined glycerol-modified nanocrystallined Mg/Al layered double hydroxides, Chem. Eng. J., 307, 476, 10.1016/j.cej.2016.08.117

Hong, 2019, Efficient degradation of atrazine by CoMgAl layered double oxides catalyzed peroxymonosulfate: Optimization, degradation pathways and mechanism, Chem. Eng. J., 370, 354, 10.1016/j.cej.2019.03.127

Hong, 2020, Heterogeneous activation of peroxymonosulfate by CoMgFe-LDO for degradation of carbamazepine: Efficiency, mechanism and degradation pathways, Chem. Eng. J., 391, 123604, 10.1016/j.cej.2019.123604

Shahzad, 2020, Non-radical PMS activation by the nanohybrid material with periodic confinement of reduced graphene oxide (rGO) and Cu hydroxides, J. Hazard. Mater., 392, 122316, 10.1016/j.jhazmat.2020.122316

Duan, 2018, Metal-Free Carbocatalysis in Advanced Oxidation Reactions, Acc. Chem. Res., 51, 678, 10.1021/acs.accounts.7b00535

Chen, 2019, Octadecylamine degradation through catalytic activation of peroxymonosulfate by Fe Mn layered double hydroxide, Sci. Total Environ., 695, 133963, 10.1016/j.scitotenv.2019.133963

Zhu, 2019, Efficient degradation of organic pollutants by peroxymonosulfate activated with MgCuFe-layered double hydroxide, RSC Adv., 9, 2284, 10.1039/C8RA09841G

Zhou, 2019, Heterogeneous co-activation of peroxymonosulfate by CuCoFe calcined layered double hydroxides and ultraviolet irradiation for the efficient removal of p-nitrophenol, J Mater Sci: Mater Electron, 30, 19009

Guo, 2020, Efficient degradation of sulfamethoxazole by CuCo LDH and LDH@fibers composite membrane activating peroxymonosulfate, Chem. Eng. J., 398, 125676, 10.1016/j.cej.2020.125676

Zeng, 2020, Development of oxygen vacancies enriched CoAl hydroxide@hydroxysulfide hollow flowers for peroxymonosulfate activation: A highly efficient singlet oxygen-dominated oxidation process for sulfamethoxazole degradation, J. Hazard. Mater., 400, 123297, 10.1016/j.jhazmat.2020.123297

L. Luo, Y. Wang, M. Zhu, X. Cheng, X. hang, X. Meng, X. Huang, H. Hao, Co–Cu–Al Layered Double Oxides as Heterogeneous Catalyst for Enhanced Degradation of Organic Pollutants in Wastewater by Activating Peroxymonosulfate: Performance and Synergistic Effect, Ind. Eng. Chem. Res. 58 (20) (2019) 8699-8711. https://doi.org/10.1021/acs.iecr.9b00167.

Li, 2020, Efficient degradation of tetracycline by CoFeLa-layered double hydroxides catalyzed peroxymonosulfate: Synergistic effect of radical and nonradical pathways, J. Hazard. Mater., 398, 122884, 10.1016/j.jhazmat.2020.122884

Duan, 2018, Insights into perovskite-catalyzed peroxymonosulfate activation: Maneuverable cobalt sites for promoted evolution of sulfate radicals, Appl. Catal. B, 220, 626, 10.1016/j.apcatb.2017.08.088

Hammouda, 2017, Degradation and mineralization of phenol in aqueous medium by heterogeneous monopersulfate activation on nanostructured cobalt based-perovskite catalysts ACoO 3 (A = La, Ba, Sr and Ce): Characterization, kinetics and mechanism study, Appl. Catal. B, 215, 60, 10.1016/j.apcatb.2017.05.051

Rao, 2019, Efficient degradation of diclofenac by LaFeO3-Catalyzed peroxymonosulfate oxidation---kinetics and toxicity assessment, Chemosphere, 218, 299, 10.1016/j.chemosphere.2018.11.105

Chu, 2018, Efficient removal of organic and bacterial pollutants by Ag-La0.8Ca0.2Fe0.94O3-δ perovskite via catalytic peroxymonosulfate activation, J. Hazard. Mater., 356, 53, 10.1016/j.jhazmat.2018.05.044

Lin, 2017, LaMO 3 perovskites (M=Co, Cu, Fe and Ni) as heterogeneous catalysts for activating peroxymonosulfate in water, Chem. Eng. Sci., 160, 96, 10.1016/j.ces.2016.11.017

Pang, 2016, LaCoO3 perovskite oxide activation of peroxymonosulfate for aqueous 2-phenyl-5-sulfobenzimidazole degradation: Effect of synthetic method and the reaction mechanism, Chem. Eng. J., 304, 897, 10.1016/j.cej.2016.07.027

Su, 2017, Mixed Conducting Perovskite Materials as Superior Catalysts for Fast Aqueous-Phase Advanced Oxidation: A Mechanistic Study, ACS Catal., 7, 388, 10.1021/acscatal.6b02303

Liu, 2019, Novel applications of perovskite oxide via catalytic peroxymonosulfate advanced oxidation in aqueous systems for trace L-cysteine detection, J. Colloid Interface Sci., 545, 311, 10.1016/j.jcis.2019.03.045

Wang, 2019, Enhanced degradation of atrazine by nanoscale LaFe1-xCuxO3-δ perovskite activated peroxymonosulfate: Performance and mechanism, Sci. Total Environ., 673, 565, 10.1016/j.scitotenv.2019.04.098

Hammouda, 2018, Sulfate radical-mediated degradation and mineralization of bisphenol F in neutral medium by the novel magnetic Sr2CoFeO6 double perovskite oxide catalyzed peroxymonosulfate: Influence of co-existing chemicals and UV irradiation, Appl. Catal. B, 233, 99, 10.1016/j.apcatb.2018.03.088

Lin, 2019, Preparation of size-controlled silver phosphate catalysts and their enhanced photocatalysis performance via synergetic effect with MWCNTs and PANI, Appl. Catal. B, 245, 71, 10.1016/j.apcatb.2018.12.048

Lin, 2017, Lanthanum cobaltite perovskite supported on zirconia as an efficient heterogeneous catalyst for activating Oxone in water, J. Colloid Interface Sci., 497, 325, 10.1016/j.jcis.2017.03.004

Wu, 2019, Enhanced activation of peroxymonosulfte by LaFeO3 perovskite supported on Al2O3 for degradation of organic pollutants, Chemosphere, 237, 124478, 10.1016/j.chemosphere.2019.124478

Lu, 2018, Heterogeneous activation of peroxymonosulfate by LaCo1-xCuxO3 perovskites for degradation of organic pollutants, J. Hazard. Mater., 353, 401, 10.1016/j.jhazmat.2018.04.021

Zhang, 2015, Generation of singlet oxygen over Bi(V)/Bi(III) composite and its use for oxidative degradation of organic pollutants, Chem. Eng. J., 264, 681, 10.1016/j.cej.2014.12.014

Chen, 2020, 3D hollow sphere-like Cu-incorporated LaAlO3 perovskites for peroxymonosulfate activation: Coaction of electron transfer and oxygen defect, Chem. Eng. J., 385, 123935, 10.1016/j.cej.2019.123935

Gao, 2019, Promoted peroxymonosulfate activation into singlet oxygen over perovskite for ofloxacin degradation by controlling the oxygen defect concentration, Chem. Eng. J., 359, 828, 10.1016/j.cej.2018.11.184

Cheng, 2020, Enhanced performance of LaFeO3 perovskite for peroxymonosulfate activation through strontium doping towards 2,4-D degradation, Chem. Eng. J., 384, 123377, 10.1016/j.cej.2019.123377

Zhan, 2020, Efficient Fenton-like Process for Pollutant Removal in Electron-Rich/Poor Reaction Sites Induced by Surface Oxygen Vacancy over Cobalt–Zinc Oxides, Environ. Sci. Technol., 54, 8333, 10.1021/acs.est.9b07245

Royer, 2014, Perovskites as Substitutes of Noble Metals for Heterogeneous Catalysis: Dream or Reality, Chem. Rev., 114, 10292, 10.1021/cr500032a

Lin, 2018, Degradation of Acid Azo Dyes Using Oxone Activated by Cobalt Titanate Perovskite, Water Air Soil Pollut, 229, 10.1007/s11270-017-3648-2

Luo, 2019, Ordered Mesoporous Cobalt Containing Perovskite as a High-Performance Heterogeneous Catalyst in Activation of Peroxymonosulfate, ACS Appl. Mater. Interfaces, 11, 35720, 10.1021/acsami.9b11322

Yin, 2020, Peroxymonosulfate enhancing visible light photocatalytic degradation of bezafibrate by Pd/g-C3N4 catalysts: The role of sulfate radicals and hydroxyl radicals, Chem. Eng. J., 390, 124532, 10.1016/j.cej.2020.124532

Wang, 2017, Insights into heterogeneous catalytic activation of peroxymonosulfate by Pd/g-C3N4: The role of superoxide radical and singlet oxygen, Catal. Commun., 102, 85, 10.1016/j.catcom.2017.08.016

Ahn, 2016, Activation of Peroxymonosulfate by Surface-Loaded Noble Metal Nanoparticles for Oxidative Degradation of Organic Compounds, Environ. Sci. Technol., 50, 10187, 10.1021/acs.est.6b02841

Ahn, 2019, Surface-loaded metal nanoparticles for peroxymonosulfate activation: Efficiency and mechanism reconnaissance, Appl. Catal. B, 241, 561, 10.1016/j.apcatb.2018.09.056

Li, 2016, Degradation of refractory dibutyl phthalate by peroxymonosulfate activated with novel catalysts cobalt metal-organic frameworks: Mechanism, performance, and stability, J. Hazard. Mater., 318, 154, 10.1016/j.jhazmat.2016.06.058

Li, 2019, Cu@Co-MOFs as a novel catalyst of peroxymonosulfate for the efficient removal of methylene blue, RSC Adv., 9, 9410, 10.1039/C9RA01143A

Li, 2018, Metal organic framework-derived CoMn2O4 catalyst for heterogeneous activation of peroxymonosulfate and sulfanilamide degradation, Chem. Eng. J., 337, 101, 10.1016/j.cej.2017.12.069

Li, 2016, FexCo3-xO4 nanocages derived from nanoscale metal–organic frameworks for removal of bisphenol A by activation of peroxymonosulfate, Appl. Catal. B: Environ., 181, 788, 10.1016/j.apcatb.2015.08.050

Yang, 2018, MOF-templated synthesis of CoFe2O4 nanocrystals and its coupling with peroxymonosulfate for degradation of bisphenol A, Chem. Eng. J., 353, 329, 10.1016/j.cej.2018.07.105

X. Zhang, J. Zhang, X. Huang, Q. P. Wu, C. H. Yan, J. F. Lu, Efficient peroxymonosulfate activation by Zn/Fe metal–organic framework‐derived ZnO/Fe3O4@carbon spheres for the degradation of Acid Orange 7, Water. Environ. Res. 91 (2019) 634-641. https://doi.org/10.1002/wer.1090.

Liu, 2019, Coupling metal–organic frameworks and g-C3N4 to derive Fe@N-doped graphene-like carbon for peroxymonosulfate activation: Upgrading framework stability and performance, Appl. Catal. B: Environ., 255, 10.1016/j.apcatb.2019.117763

Li, 2017, Facile synthesis of nitrogen-doped graphene via low-temperature pyrolysis: The effects of precursors and annealing ambience on metal-free catalytic oxidation, Carbon, 115, 649, 10.1016/j.carbon.2017.01.058

Liang, 2017, An insight into metal organic framework derived N-doped graphene for the oxidative degradation of persistent contaminants: formation mechanism and generation of singlet oxygen from peroxymonosulfate, Environ. Sci.: Nano, 4, 315

Lin, 2015, Zeolitic Imidazole Framework-67 (ZIF-67) as a heterogeneous catalyst to activate peroxymonosulfate for degradation of Rhodamine B in water, J. Taiwan Inst. Chem. Eng., 53, 40, 10.1016/j.jtice.2015.02.027

Cong, 2017, Two Co-zeolite imidazolate frameworks with different topologies for degradation of organic dyes via peroxymonosulfate activation, J. Solid State Chem., 256, 10, 10.1016/j.jssc.2017.08.031

Wu, 2018, ZIF-67 supported on marcoscale resin as an efficient and convenient heterogeneous catalyst for Oxone activation, J. Colloid Interface Sci., 514, 262, 10.1016/j.jcis.2017.11.053

Zhang, 2020, Recyclable ZIF-9@CA-Fe3O4/RGO/cellulose composite membrane as efficient catalysts for activating peroxymonosulfate to degrade methylene blue, Cellulose, 27, 3287, 10.1007/s10570-020-02998-x

Bao, 2018, Surface-nucleated heterogeneous growth of zeolitic imidazolate framework – A unique precursor towards catalytic ceramic membranes: Synthesis, characterization and organics degradation, Chem. Eng. J., 353, 69, 10.1016/j.cej.2018.07.117

Chen, 2018, Effect of salinity on removal performance and activated sludge characteristics in sequencing batch reactors, Bioresour. Technol., 249, 890, 10.1016/j.biortech.2017.10.092

Fu, 2020, Enhanced peroxymonosulfate activation by coupling zeolite-supported nano-zero-valent iron with weak magnetic field, Sep. Purif. Technol., 230, 115886, 10.1016/j.seppur.2019.115886

Wang, 2015, Nitrogen-Doped Reduced Graphene Oxide as a Bifunctional Material for Removing Bisphenols: Synergistic Effect between Adsorption and Catalysis, Environ. Sci. Technol., 49, 6855, 10.1021/acs.est.5b01059

Abdul Nasir Khan, 2019, Metal-organic framework-derived hollow Co3O4/carbon as efficient catalyst for peroxymonosulfate activation, Chem. Eng. J., 363, 234, 10.1016/j.cej.2019.01.129

Zhu, 2020, Interfacial CoAl2O4 from ZIF-67@γ-Al2O3 pellets toward catalytic activation of peroxymonosulfate for metronidazole removal, Chem. Eng. J., 397, 125339, 10.1016/j.cej.2020.125339

Ma, 2018, Nitrogen, phosphorus, and sulfur tri-doped hollow carbon shells derived from ZIF-67@poly (cyclotriphosphazene-co-4, 4′-sulfonyldiphenol) as a robust catalyst of peroxymonosulfate activation for degradation of bisphenol A, Carbon, 137, 291, 10.1016/j.carbon.2018.05.039

Liu, 2021, Heterogeneous activation of peroxymonosulfate by cobalt-doped MIL-53(Al) for efficient tetracycline degradation in water: Coexistence of radical and non-radical reactions, J. Colloid Interface Sci., 581, 195, 10.1016/j.jcis.2020.07.100

Li, 2020, Yolk-shell ZIFs@SiO2 and its derived carbon composite as robust catalyst for peroxymonosulfate activation, J. Environ. Manage., 262, 110299, 10.1016/j.jenvman.2020.110299

Wu, 2020, A mechanistic study of amorphous CoSx cages as advanced oxidation catalysts for excellent peroxymonosulfate activation towards antibiotics degradation, Chem. Eng. J., 381, 122768, 10.1016/j.cej.2019.122768

Kohantorabi, 2017, AgPt nanoparticles supported on magnetic graphene oxide nanosheets for catalytic reduction of 4‐nitrophenol: Studies of kinetics and mechanism, Appl Organometal Chem, 31, 10.1002/aoc.3806

Lee, 2016, Activation of Persulfates by Graphitized Nanodiamonds for Removal of Organic Compounds, Environ. Sci. Technol., 50, 10134, 10.1021/acs.est.6b02079

Liu, 2017, Nitrogen-doped carbon material as a catalyst for the degradation of direct red23 based on persulfate oxidation, Sep. Purif. Technol., 184, 213, 10.1016/j.seppur.2017.04.045

Wu, 2017, Role of biochar on composting of organic wastes and remediation of contaminated soils—a review, Environ Sci Pollut Res, 24, 16560, 10.1007/s11356-017-9168-1

Ho, 2019, N-doped graphitic biochars from C-phycocyanin extracted Spirulina residue for catalytic persulfate activation toward nonradical disinfection and organic oxidation, Water Res., 159, 77, 10.1016/j.watres.2019.05.008

Lu, 2021, Preparation of nitrogen self-doped hierarchical porous carbon with rapid-freezing support for cooperative pollutant adsorption and catalytic oxidation of persulfate, Sci. Total Environ., 752, 142282, 10.1016/j.scitotenv.2020.142282

Du, 2020, Sulfate saturated biosorbent-derived Co-S@NC nanoarchitecture as an efficient catalyst for peroxymonosulfate activation, Appl. Catal. B, 262, 118302, 10.1016/j.apcatb.2019.118302

Liu, 2016, Nitrogen and sulfur co-doped CNT-COOH as an efficient metal-free catalyst for the degradation of UV filter BP-4 based on sulfate radicals, Appl. Catal. B, 187, 1, 10.1016/j.apcatb.2016.01.036

Duan, 2015, Sulfur and Nitrogen Co-Doped Graphene for Metal-Free Catalytic Oxidation Reactions, Small, 11, 3036, 10.1002/smll.201403715

Sun, 2013, Facile synthesis of nitrogen doped reduced graphene oxide as a superior metal-free catalyst for oxidation, Chem. Commun., 49, 9914, 10.1039/c3cc43401j

Gao, 2018, Electronic Structure Modulation of Graphitic Carbon Nitride by Oxygen Doping for Enhanced Catalytic Degradation of Organic Pollutants through Peroxymonosulfate Activation, Environ. Sci. Technol., 52, 14371, 10.1021/acs.est.8b05246

Zhang, 2008, Determination of folic acid by chemiluminescence based on peroxomonosulfate-cobalt(II) system, Talanta, 74, 1154, 10.1016/j.talanta.2007.08.027

Wu, 2020, High-performance porous carbon catalysts doped by iron and nitrogen for degradation of bisphenol F via peroxymonosulfate activation, Chem. Eng. J., 392, 123683, 10.1016/j.cej.2019.123683

Wang, 2019, Enhanced heterogeneous activation of peroxymonosulfate by Co and N codoped porous carbon for degradation of organic pollutants: the synergism between Co and N, Environ. Sci.: Nano, 6, 399

Wang, 2019, Nitrogen-doped graphene as peroxymonosulfate activator and electron transfer mediator for the enhanced degradation of sulfamethoxazole, Chem. Eng. J., 375, 122041, 10.1016/j.cej.2019.122041

Yun, 2018, Identifying the Nonradical Mechanism in the Peroxymonosulfate Activation Process: Singlet Oxygenation Versus Mediated Electron Transfer, Environ. Sci. Technol., 52, 7032, 10.1021/acs.est.8b00959

Wang, 2017, Ferric carbide nanocrystals encapsulated in nitrogen-doped carbon nanotubes as an outstanding environmental catalyst, Environ. Sci.: Nano, 4, 170

Liu, 2019, Highly efficient removal of trimethoprim based on peroxymonosulfate activation by carbonized resin with Co doping: Performance, mechanism and degradation pathway, Chem. Eng. J., 356, 717, 10.1016/j.cej.2018.09.086

Xu, 2020, Improving PMS oxidation of organic pollutants by single cobalt atom catalyst through hybrid radical and non-radical pathways, Appl. Catal. B, 263, 118350, 10.1016/j.apcatb.2019.118350

Yang, 2020, Recycling of nitrogen-containing waste diapers for catalytic contaminant oxidation: Occurrence of radical and non-radical pathways, Chem. Eng. J., 384, 123246, 10.1016/j.cej.2019.123246

Qi, 2020, Three-dimensional porous graphene-like biochar derived from Enteromorpha as a persulfate activator for sulfamethoxazole degradation: Role of graphitic N and radicals transformation, J. Hazard. Mater., 399, 123039, 10.1016/j.jhazmat.2020.123039

Oh, 2019, Catalytically active nitrogen-doped porous carbon derived from biowastes for organics removal via peroxymonosulfate activation, Chem. Eng. J., 374, 947, 10.1016/j.cej.2019.06.001

Zaeni, 2020, In situ nitrogen functionalization of biochar via one-pot synthesis for catalytic peroxymonosulfate activation: Characteristics and performance studies, Sep. Purif. Technol., 241, 116702, 10.1016/j.seppur.2020.116702

Huong, 2020, Novel activation of peroxymonosulfate by biochar derived from rice husk toward oxidation of organic contaminants in wastewater, J. Water Process Eng., 33, 101037, 10.1016/j.jwpe.2019.101037

Wang, 2020, Red mud modified sludge biochar for the activation of peroxymonosulfate: Singlet oxygen dominated mechanism and toxicity prediction, Sci. Total Environ., 740, 140388, 10.1016/j.scitotenv.2020.140388

Wang, 2020, One-step preparation of ZVI-sludge derived biochar without external source of iron and its application on persulfate activation, Sci. Total Environ., 714, 136728, 10.1016/j.scitotenv.2020.136728

Gan, 2020, Sludge-derived biochar with multivalent iron as an efficient Fenton catalyst for degradation of 4-Chlorophenol, Sci. Total Environ., 725, 138299, 10.1016/j.scitotenv.2020.138299

Wang, 2020, Peroxymonosulfate activation by Co9S8@ S and N co‐doped biochar for sulfamethoxazole degradation, Chem. Eng. J., 385, 123933, 10.1016/j.cej.2019.123933

Hu, 2020, Hydrothermal route-enabled synthesis of sludge-derived carbon with oxygen functional groups for bisphenol A degradation through activation of peroxymonosulfate, J. Hazard. Mater., 388, 121801, 10.1016/j.jhazmat.2019.121801

Fang, 2015, Manipulation of Persistent Free Radicals in Biochar To Activate Persulfate for Contaminant Degradation, Environ. Sci. Technol., 49, 5645, 10.1021/es5061512

Kappler, 2014, Biochar as an Electron Shuttle between Bacteria and Fe(III) Minerals, Environ. Sci. Technol. Lett., 1, 339, 10.1021/ez5002209

Ouyang, 2019, Activation mechanism of peroxymonosulfate by biochar for catalytic degradation of 1,4-dioxane: Important role of biochar defect structures, Chem. Eng. J., 370, 614, 10.1016/j.cej.2019.03.235

Nguyen, 2019, Cobalt-impregnated biochar (Co-SCG) for heterogeneous activation of peroxymonosulfate for removal of tetracycline in water, Bioresour. Technol., 292, 121954, 10.1016/j.biortech.2019.121954

N. T. Nham, T. M. Al Tahtamouni, T. D. Nguyen, P. T. Huong, K. Jitae, N. M. Viet, N. V. Noi, N. T. M. Phuong, N. T. H. Anh, Synthesis of iron modified rice straw biochar toward arsenic from groundwater, Mater. Res. Express. 6 (2019) 115528. https://doi.org/10.1088/2053-1591/ab4b98.

Mian, 2020, Activation of peroxymonosulfate by chemically modified sludge biochar for the removal of organic pollutants: Understanding the role of active sites and mechanism, Chem. Eng. J., 392, 123681, 10.1016/j.cej.2019.123681

Tian, 2020, Amorphous Co3O4 nanoparticles-decorated biochar as an efficient activator of peroxymonosulfate for the removal of sulfamethazine in aqueous solution, Sep. Purif. Technol., 250, 117246, 10.1016/j.seppur.2020.117246

Mian, 2019, Facile synthesis of sludge-derived MnOx-N-biochar as an efficient catalyst for peroxymonosulfate activation, Appl. Catal. B, 255, 117765, 10.1016/j.apcatb.2019.117765

Fan, 2019, Mn-doped g-C3N4 composite to activate peroxymonosulfate for acetaminophen degradation: The role of superoxide anion and singlet oxygen, Chem. Eng. J., 359, 723, 10.1016/j.cej.2018.11.165

Yang, 2018, Efficient removal of bisphenol A by superoxide radical and singlet oxygen generated from peroxymonosulfate activated with Fe0-montmorillonite, Chem. Eng. J., 350, 484, 10.1016/j.cej.2018.04.175

Wang, 2018, Activation of persulfate (PS) and peroxymonosulfate (PMS) and application for the degradation of emerging contaminants, Chem. Eng. J., 334, 1502, 10.1016/j.cej.2017.11.059

Ma, 2015, Control of MnO2 nanocrystal shape from tremella to nanobelt for ehancement of the oxygen reduction reaction activity, J. Power Sources, 280, 526, 10.1016/j.jpowsour.2015.01.139

Li, 2018, Oxygen Vacancy-Mediated Photocatalysis of BiOCl: Reactivity, Selectivity, and Perspectives, Angew. Chem. Int. Ed., 57, 122, 10.1002/anie.201705628

Qin, 2020, Rational design of efficient metal-free catalysts for peroxymonosulfate activation: Selective degradation of organic contaminants via a dual nonradical reaction pathway, J. Hazard. Mater., 398, 122808, 10.1016/j.jhazmat.2020.122808

T. Zhang, H. B. Zhu, J. P. Croue, Production of Sulfate Radical from Peroxymonosulfate Induced by a Magnetically Separable CuFe2O4 Spinel in Water: Efficiency, Stability, and Mechanism, Environ. Sci. Technol. 47 (2013) 2784-2791. https://doi.org/10.1021/es304721g.

Wang, 2020, pH-dependent transformation products and residual toxicity evaluation of sulfamethoxazole degradation through non-radical oxygen species involved process, Chem. Eng. J., 390, 124512, 10.1016/j.cej.2020.124512

Rao, 2018, Heterogeneous activation of peroxymonosulfate by LaFeO3 for diclofenac degradation: DFT-assisted mechanistic study and degradation pathways, Chem. Eng. J., 352, 601, 10.1016/j.cej.2018.07.062

Li, 2018, Magnetic nitrogen-doped nanocarbons for enhanced metal-free catalytic oxidation: Integrated experimental and theoretical investigations for mechanism and application, Chem. Eng. J., 354, 507, 10.1016/j.cej.2018.08.043

Zhu, 2019, Durable activation of peroxymonosulfate mediated by Co-doped mesoporous FePO4 via charge redistribution for atrazine degradation, Chem. Eng. J., 375, 122009, 10.1016/j.cej.2019.122009

Guo, 2020, Scalable synthesis of Ca-doped ɑ-Fe2O3 with abundant oxygen vacancies for enhanced degradation of organic pollutants through peroxymonosulfate activation, Appl. Catal. B: Environ., 262, 10.1016/j.apcatb.2019.118250

Jiang, 2020, Enhanced activation of peroxymonosulfate with metal-substituted hollow MxCo3-xS4 polyhedrons for superfast degradation of sulfamethazine, Chem. Eng. J., 384, 123302, 10.1016/j.cej.2019.123302

Zhou, 2019, Degradation of organic pollutants by peroxymonosulfate activated by MnO2 with different crystalline structures: Catalytic performances and mechanisms, Chem. Eng. J., 374, 170, 10.1016/j.cej.2019.05.170

Wang, 2016, Activation of peroxymonosulfate by carbonaceous oxygen groups: experimental and density functional theory calculations, Appl. Catal. B, 198, 295, 10.1016/j.apcatb.2016.05.075

Duan, 2016, Unveiling the active sites of graphene-catalyzed peroxymonosulfate activation, Carbon, 107, 371, 10.1016/j.carbon.2016.06.016

Wang, 2017, Enhanced activation of peroxymonosulfate by nitrogen doped porous carbon for effective removal of organic pollutants, Carbon, 115, 730, 10.1016/j.carbon.2017.01.060

Su, 2012, Probing the catalytic activity of porous graphene oxide and the origin of this behavior, Nat. Commun., 3, 1298, 10.1038/ncomms2315

Xiao, 2015, Quantitative Structure–Activity Relationship (QSAR) for the Oxidation of Trace Organic Contaminants by Sulfate Radical, Environ. Sci. Technol., 49, 13394, 10.1021/acs.est.5b03078

Lee, 2020, Persulfate-Based Advanced Oxidation: Critical Assessment of Opportunities and Roadblocks, Environ. Sci. Technol., 54, 3064, 10.1021/acs.est.9b07082

Ding, 2020, Degradation of norfloxacin by CoFe alloy nanoparticles encapsulated in nitrogen doped graphitic carbon (CoFe@N-GC) activated peroxymonosulfate, Chem. Eng. J., 392, 123725, 10.1016/j.cej.2019.123725

Xie, 2018, Heterogeneous activation of peroxymonosulfate over monodispersed Co3O4/activated carbon for efficient degradation of gaseous toluene, Chem. Eng. J., 341, 383, 10.1016/j.cej.2018.02.045

Guan, 2020, Facile synthesis of pure g-C3N4 materials for peroxymonosulfate activation to degrade bisphenol A: Effects of precursors and annealing ambience on catalytic oxidation, Chem. Eng. J., 387, 123726, 10.1016/j.cej.2019.123726

Ziajka, 2007, Autoxidation of SIV inhibited by chlorophenols reacting with sulfate radicals, Environ. Chem., 4, 355, 10.1071/EN07045

Mandal, 2018, Reaction Rate Constants of Hydroxyl Radicals with Micropollutants and Their Significance in Advanced Oxidation Processes, J. Adv. Oxidation. Technol, 21, 178, 10.26802/jaots.2017.0075

K. J. Rudzinski, R. Szmigielski, Aqueous Reactions of Sulfate Radical-Anions with Nitrophenols in Atmospheric Context. Atmosphere, 10 (2019) 795. https://doi.org/10.3390/atmos10120795.

Liu, 2010, Aqueous 4-nitrophenol decomposition and hydrogen peroxide formation induced by contact glow discharge electrolysis, J. Hazard. Mater., 181, 1010, 10.1016/j.jhazmat.2010.05.115

Kong, 2021, A novel peroxymonosulfate activation process by periclase for efficient singlet oxygen-mediated degradation of organic pollutants, Chem. Eng. J., 403, 126445, 10.1016/j.cej.2020.126445

Pang, 2020, Facilely synthesized cobalt doped hydroxyapatite as hydroxyl promoted peroxymonosulfate activator for degradation of Rhodamine B, J. Hazard. Mater., 384, 121447, 10.1016/j.jhazmat.2019.121447

Long, 2019, Peroxymonosulfate activation for pollutants degradation by Fe-N-codoped carbonaceous catalyst: Structure-dependent performance and mechanism insight, Chem. Eng. J., 369, 542, 10.1016/j.cej.2019.03.097

Wilkinson, 1995, Rate Constants for the Decay and Reactions of the Lowest Electronically Excited Singlet State of Molecular Oxygen in Solution. An Expanded and Revised Compilation, J. Phys. Chem. Ref. Data, 24, 663, 10.1063/1.555965

Musa, 2009, Photodegradation mechanism of the common non-steroid anti-inflammatory drug diclofenac and its carbazole photoproduct, Phys. Chem. Chem. Phys., 11, 4601, 10.1039/b900144a

Mahdi Ahmed, 2012, Sulfate radical anion oxidation of diclofenac and sulfamethoxazole for water decontamination, Chem. Eng. J., 197, 440, 10.1016/j.cej.2012.05.040

Peller, 2009, Bisphenol A reactions with hydroxyl radicals: diverse pathways determined between deionized water and tertiary treated wastewater solutions, Res Chem Intermed, 35, 21, 10.1007/s11164-008-0012-6

Yuan, 2018, Rapid oxidation of paracetamol by Cobalt(II) catalyzed sulfite at alkaline pH, Catal. Today, 313, 155, 10.1016/j.cattod.2017.12.004

Shah, 2018, Solar light driven degradation of norfloxacin using as-synthesized Bi3+ and Fe2+ co-doped ZnO with the addition of HSO5−: Toxicities and degradation pathways investigation, Chem. Eng. J., 351, 841, 10.1016/j.cej.2018.06.111

Martinez, 1998, Fluoroquinolone Antimicrobials: Singlet Oxygen, Superoxide and Phototoxicity, Photochem Photobiol, 67, 399, 10.1111/j.1751-1097.1998.tb05217.x

Khan, 2014, Kinetic and mechanism investigation on the photochemical degradation of atrazine with activated H2O2, S2O82− and HSO5−, Chem. Eng. J., 252, 393, 10.1016/j.cej.2014.04.104

Yang, 2015, Production of Sulfate Radical and Hydroxyl Radical by Reaction of Ozone with Peroxymonosulfate: A Novel Advanced Oxidation Process, Environ. Sci. Technol., 49, 7330, 10.1021/es506362e

Canonica, 2019, Inhibitory Effect of Dissolved Organic Matter on the Transformation of Selected Anilines and Sulfonamide Antibiotics Induced by the Sulfate Radical, Environ. Sci. Technol., 53, 11783, 10.1021/acs.est.9b04105

Westerhoff, 2007, Electron Pulse Radiolysis Determination of Hydroxyl Radical Rate Constants with Suwannee River Fulvic Acid and Other Dissolved Organic Matter Isolates, Environ. Sci. Technol., 41, 4640, 10.1021/es062529n

Yang, 2009, Iron–cobalt mixed oxide nanocatalysts: Heterogeneous peroxymonosulfate activation, cobalt leaching, and ferromagnetic properties for environmental applications, Appl. Catal. B, 88, 462, 10.1016/j.apcatb.2008.10.013

Xu, 2018, A superior active and stable spinel sulfide for catalytic peroxymonosulfate oxidation of bisphenol S, Appl. Catal. B, 238, 557, 10.1016/j.apcatb.2018.07.058