Degradation of Acid Azo Dyes Using Oxone Activated by Cobalt Titanate Perovskite
Tóm tắt
Chemical degradation by sulfate radicals from activation of Oxone is one of the most attractive advanced oxidation processes (AOPs) for treating toxic acid azo dyes. However, development of an effective and recyclable heterogeneous catalyst for activating Oxone is still highly desired. In this study, cobalt titanate perovskite (CoTiO3) was synthesized and employed as a heterogeneous catalyst for activating Oxone to degrade acid azo dyes, Acid Red 27 (AR), Acid Yellow 17 (AY), and Acid Blue 120 (AB). As CoTiO3 does not adsorb these azo dyes, and Oxone alone is ineffective to degrade them, the combination of CoTiO3 and Oxone tremendously improves degradation of acid azo dyes, validating that CoTiO3 can activate Oxone. The analyses of Co species before and after Oxone activation validate that the activation mechanism can attributed to Co2+ of CoTiO3, which transforms between Co2+ and Co3+ to activate Oxone. Through examining the effects of radical scavengers, the degradation of these azo dyes is primarily owing to sulfate radicals and derivative hydroxyl radicals to a lesser extent. In addition, CoTiO3-activated Oxone is much favorable at elevated temperature and under a neutral condition (pH = 7), while the addition of NaCl slightly slows the dye degradation kinetics by CoTiO3-activated Oxone. CoTiO3 can also be reused for multiple cycles (up to 5 cycles) and remains effective to activate Oxone. CoTiO3-activated Oxone exhibits the highest degradation efficiency for AR, followed by AB and finally AY, when AR, AB, and AY co-exist. This study demonstrates that CoTiO3 is a promising catalyst for activating Oxone to degrade typical acid azo dyes. The findings obtained here can provide further understanding and optimized parameters for using CoTiO3 to activate Oxone in treatments of acid azo dye-containing wastewater.
Tài liệu tham khảo
Abid, M. F., Zablouk, M. A., & Abid-Alameer, A. M. (2012). Experimental study of dye removal from industrial wastewater by membrane technologies of reverse osmosis and nanofiltration. Iranian Journal of Environmental Health Science & Engineering, 9(1), 17. https://doi.org/10.1186/1735-2746-9-17.
Andrew Lin, K.-Y., Chang, H.-A., & Chen, B.-J. (2016). Multi-functional MOF-derived magnetic carbon sponge. Journal of Materials Chemistry A, 4(35), 13611–13625. https://doi.org/10.1039/C6TA04619C.
Andrew Lin, K.-Y., & Hsu, F.-K. (2015). Magnetic iron/carbon nanorods derived from a metal organic framework as an efficient heterogeneous catalyst for the chemical oxidation process in water. RSC Advances, 5(63), 50790–50800. https://doi.org/10.1039/C5RA06043E.
Anipsitakis, G. P., & Dionysiou, D. D. (2004). Radical generation by the interaction of transition metals with common oxidants. Environmental Science & Technology, 38(13), 3705–3712. https://doi.org/10.1021/es035121o.
Aruna, P., & Naidu, M. P. (2013). Decolourization of selected procion dye using fungi, Acremonium chrysogenum a comparison with physical adsorbents. International Journal of Applied Biology and Pharmaceutical Technology, 4(3), 117–123.
Buxton, G. V., Greenstock, C. L., Helman, W. P., & Ross, A. B. (1988). Critical review of rate constants for reactions of hydrated electrons, hydrogen atoms and hydroxyl radicals·OH/·O− in aqueous solution. Journal of Physical and Chemical Reference Data, 17(2), 513–886. https://doi.org/10.1063/1.555805.
Cai, C., Zhang, H., Zhong, X., & Hou, L. (2015). Ultrasound enhanced heterogeneous activation of peroxymonosulfate by a bimetallic Fe–Co/SBA-15 catalyst for the degradation of Orange II in water. Journal of Hazardous Materials, 283, 70–79. https://doi.org/10.1016/j.jhazmat.2014.08.053.
Chuang, S.-H., Gao, R.-H., Wang, D.-Y., Liu, H.-P., Chen, L.-M., & Chiang, M. Y. (2010). Synthesis and characterization of ilmenite-type cobalt titanate powder. Journal of the Chinese Chemical Society, 57(4B), 932–937. https://doi.org/10.1002/jccs.201000129.
Daneshvar, N., Salari, D., & Khataee, A. R. (2003). Photocatalytic degradation of azo dye acid red 14 in water: investigation of the effect of operational parameters. Journal of Photochemistry and Photobiology A: Chemistry, 157(1), 111–116. https://doi.org/10.1016/S1010-6030(03)00015-7.
Ehsan, M. A., Naeem, R., Khaledi, H., Sohail, M., Hakeem Saeed, A., & Mazhar, M. (2016). Fabrication of CoTiO3-TiO2 composite films from a heterobimetallic single source precursor for electrochemical sensing of dopamine. Dalton Transactions, 45(25), 10222–10232. https://doi.org/10.1039/C6DT01016D.
Eibenberger, H., Steenken, S., O'Neill, P., & Schulte-Frohlinde, D. (1978). Pulse radiolysis and electron spin resonance studies concerning the reaction of SO4.cntdot.—with alcohols and ethers in aqueous solution. The Journal of Physical Chemistry, 82(6), 749–750. https://doi.org/10.1021/j100495a028.
Ghanbari, F., & Moradi, M. (2017). Application of peroxymonosulfate and its activation methods for degradation of environmental organic pollutants: review. Chemical Engineering Journal, 310(Part 1), 41–62. https://doi.org/10.1016/j.cej.2016.10.064.
Ghanbari, F., Moradi, M., & Manshouri, M. (2014). Textile wastewater decolorization by zero valent iron activated peroxymonosulfate: compared with zero valent copper. Journal of Environmental Chemical Engineering, 2(3), 1846–1851. https://doi.org/10.1016/j.jece.2014.08.003.
Glaze, W. H., & Kang, J. W. (1989). Advanced oxidation processes. Description of a kinetic model for the oxidation of hazardous materials in aqueous media with ozone and hydrogen peroxide in a semibatch reactor. Industrial & Engineering Chemistry Research, 28(11), 1573–1580. https://doi.org/10.1021/ie00095a001.
Gong, F., Wang, L., Li, D., Zhou, F., Yao, Y., Lu, W., et al. (2015). An effective heterogeneous iron-based catalyst to activate peroxymonosulfate for organic contaminants removal. Chemical Engineering Journal, 267, 102–110. https://doi.org/10.1016/j.cej.2015.01.010.
Guo, W., Su, S., Yi, C., & Ma, Z. (2013). Degradation of antibiotics amoxicillin by Co3O4-catalyzed peroxymonosulfate system. Environmental Progress & Sustainable Energy, 32(2), 193–197. https://doi.org/10.1002/ep.10633.
Gupta, V. K., Jain, R., Mittal, A., Saleh, T. A., Nayak, A., Agarwal, S., et al. (2012). Photo-catalytic degradation of toxic dye amaranth on TiO2/UV in aqueous suspensions. Materials Science and Engineering: C, 32(1), 12–17. https://doi.org/10.1016/j.msec.2011.08.018.
Gupta, V. K., & Suhas, B. A. (2009). Application of low-cost adsorbents for dye removal—a review. Journal of Environmental Management, 90(8), 2313–2342. https://doi.org/10.1016/j.jenvman.2008.11.017.
Hu, P., & Long, M. (2016). Cobalt-catalyzed sulfate radical-based advanced oxidation: a review on heterogeneous catalysts and applications. Applied Catalysis B: Environmental, 181, 103–117. https://doi.org/10.1016/j.apcatb.2015.07.024.
Huang, Z., Bao, H., Yao, Y., Lu, W., & Chen, W. (2014). Novel green activation processes and mechanism of peroxymonosulfate based on supported cobalt phthalocyanine catalyst. Applied Catalysis B: Environmental, 154–155, 36–43. https://doi.org/10.1016/j.apcatb.2014.02.005.
Jain, R., Sharma, N., & Radhapyari, K. (2009). Electrochemical treatment of pharmaceutical azo dye amaranth from waste water. [journal article]. Journal of Applied Electrochemistry, 39(5), 577–582. https://doi.org/10.1007/s10800-008-9695-z.
Jiang, Y., Tan, P., Cheng, L., Shan, S.-F., Liu, X.-Q., & Sun, L.-B. (2016a). Selective adsorption and efficient regeneration via smart adsorbents possessing thermo-controlled molecular switches. Physical Chemistry Chemical Physics, 18(15), 9883–9887. https://doi.org/10.1039/C6CP00351F.
Jiang, Y., Tan, P., Kang, Y.-H., Xing, Z.-M., Cheng, L., Zhu, L., et al. (2016b). Fabrication of adsorbents with thermocontrolled molecular gates for both selective adsorption and efficient regeneration. Advanced Materials Interfaces, 3, 1500829. https://doi.org/10.1002/admi.201500829.
Kiron, M. I. (2012). Acid dyes | properties of acid dyes | mechanism of dyeing with acid dyes.
Lin, K.-Y. A., & Chang, H.-A. (2015). Zeolitic Imidazole Framework-67 (ZIF-67) as a heterogeneous catalyst to activate peroxymonosulfate for degradation of Rhodamine B in water. Journal of the Taiwan Institute of Chemical Engineers, 53, 40–45. https://doi.org/10.1016/j.jtice.2015.02.027.
Lin, K.-Y. A., Chang, H.-A., & Chen, R.-C. (2015). MOF-derived magnetic carbonaceous nanocomposite as a heterogeneous catalyst to activate oxone for decolorization of Rhodamine B in water. Chemosphere, 130, 66–72. https://doi.org/10.1016/j.chemosphere.2015.03.025.
Lin, K.-Y. A., & Chen, B.-J. (2017). Prussian blue analogue derived magnetic carbon/cobalt/iron nanocomposite as an efficient and recyclable catalyst for activation of peroxymonosulfate. Chemosphere, 166, 146–156. https://doi.org/10.1016/j.chemosphere.2016.09.072.
Lin, K.-Y. A., Chen, B.-J., & Chen, C.-K. (2016a). Evaluating Prussian blue analogues MII3[MIII(CN)6]2 (MII = Co, Cu, Fe, Mn, Ni; MIII = Co, Fe) as activators for peroxymonosulfate in water. RSC Advances, 6(95), 92923–92933. https://doi.org/10.1039/C6RA16011E.
Lin, K.-Y. A., Chen, Y.-C., & Huang, C.-F. (2016b). Magnetic carbon-supported cobalt prepared from one-step carbonization of hexacyanocobaltate as an efficient and recyclable catalyst for activating Oxone. Separation and Purification Technology, 170, 173–182. https://doi.org/10.1016/j.seppur.2016.06.048.
Liu, Y., Guo, H., Zhang, Y., Tang, W., Cheng, X., & Liu, H. (2016). Activation of peroxymonosulfate by BiVO4 under visible light for degradation of Rhodamine B. Chemical Physics Letters, 653, 101–107. https://doi.org/10.1016/j.cplett.2016.04.069.
Mohammadzadeh, S., Olya, M. E., Arabi, A. M., Shariati, A., & Khosravi Nikou, M. R. (2015). Synthesis, characterization and application of ZnO-Ag as a nanophotocatalyst for organic compounds degradation, mechanism and economic study. Journal of Environmental Sciences, 35, 194–207. https://doi.org/10.1016/j.jes.2015.03.030.
Mohan, S. V., Prasad, K. K., Rao, N. C., & Sarma, P. N. (2005). Acid azo dye degradation by free and immobilized horseradish peroxidase (HRP) catalyzed process. Chemosphere, 58(8), 1097–1105. https://doi.org/10.1016/j.chemosphere.2004.09.070.
Muhammad, S., Saputra, E., Sun, H., Izidoro, J. D. C., Fungaro, D. A., Ang, H. M., et al. (2012). Coal fly ash supported Co3O4 catalysts for phenol degradation using peroxymonosulfate. RSC Advances, 2(13), 5645–5650. https://doi.org/10.1039/C2RA20346D.
Ong, S.-A., Min, O.-M., Ho, L.-N., & Wong, Y.-S. (2012). Comparative study on photocatalytic degradation of mono azo dye acid orange 7 and methyl orange under solar light irradiation. Water, Air, & Soil Pollution, 223(8), 5483–5493. https://doi.org/10.1007/s11270-012-1295-1.
Pérez-Urquiza, M., & Beltrán, J. L. (2001). Determination of the dissociation constants of sulfonated azo dyes by capillary zone electrophoresis and spectrophotometry methods. Journal of Chromatography A, 917(1), 331–336. https://doi.org/10.1016/S0021-9673(01)00707-5.
Pang, X., Guo, Y., Zhang, Y., Xu, B., & Qi, F. (2016). LaCoO3 perovskite oxide activation of peroxymonosulfate for aqueous 2-phenyl-5-sulfobenzimidazole degradation: effect of synthetic method and the reaction mechanism. Chemical Engineering Journal, 304, 897–907. https://doi.org/10.1016/j.cej.2016.07.027.
Qi, F., Chu, W., & Xu, B. (2014). Modeling the heterogeneous peroxymonosulfate/Co-MCM41 process for the degradation of caffeine and the study of influence of cobalt sources. Chemical Engineering Journal, 235, 10–18. https://doi.org/10.1016/j.cej.2013.08.113.
Sadri Moghaddam, S., Alavi Moghaddam, M. R., & Arami, M. (2010). Coagulation/flocculation process for dye removal using sludge from water treatment plant: optimization through response surface methodology. Journal of Hazardous Materials, 175(1–3), 651–657. https://doi.org/10.1016/j.jhazmat.2009.10.058.
Safari, J., Mansouri Kafroudi, Z., & Zarnegar, Z. (2014). Co3O4-decorated carbon nanotubes as a novel efficient catalyst in the selective oxidation of benzoins. Comptes Rendus Chimie, 17(9), 958–963. https://doi.org/10.1016/j.crci.2013.09.003.
Sarıkaya, R., Selvi, M., & Erkoç, F. (2012). Evaluation of potential genotoxicity of five food dyes using the somatic mutation and recombination test. Chemosphere, 88(8), 974–979. https://doi.org/10.1016/j.chemosphere.2012.03.032.
Shao, J., Wan, Z., Liu, H., Zheng, H., Gao, T., Shen, M., et al. (2014). Metal organic frameworks-derived Co3O4 hollow dodecahedrons with controllable interiors as outstanding anodes for Li storage. Journal of Materials Chemistry A, 2(31), 12194–12200. https://doi.org/10.1039/C4TA01966K.
Shi, P., Zhu, S., Zheng, H., Li, D., & Xu, S. (2013). Supported Co3O4 on expanded graphite as a catalyst for the degradation of Orange II in water using sulfate radicals. Desalination and Water Treatment, 52(16–18), 3384–3391. https://doi.org/10.1080/19443994.2013.796896.
Sudrajat, H., & Babel, S. (2015). Rapid photocatalytic degradation of the recalcitrant dye amaranth by highly active N-WO3. Environmental Chemistry Letters, 1–7. https://doi.org/10.1007/s10311-015-0538-y.
Taran, O. P., Ayusheev, A. B., Ogorodnikova, O. L., Prosvirin, I. P., Isupova, L. A., & Parmon, V. N. (2016). Perovskite-like catalysts LaBO3 (B = Cu, Fe, Mn, Co, Ni) for wet peroxide oxidation of phenol. Applied Catalysis B: Environmental, 180, 86–93. https://doi.org/10.1016/j.apcatb.2015.05.055.
Tsitonaki, A., Petri, B., Crimi, M., MosbÆK, H., Siegrist, R. L., & Bjerg, P. L. (2010). In situ chemical oxidation of contaminated soil and groundwater using persulfate: a review. Critical Reviews in Environmental Science and Technology, 40(1), 55–91. https://doi.org/10.1080/10643380802039303.
Xu, L. J., Chu, W., & Gan, L. (2015). Environmental application of graphene-based CoFe2O4 as an activator of peroxymonosulfate for the degradation of a plasticizer. Chemical Engineering Journal, 263, 435–443. https://doi.org/10.1016/j.cej.2014.11.065.
Xu, X., Liu, G., Randorn, C., & Irvine, J. T. S. (2011). g-C3N4 coated SrTiO3 as an efficient photocatalyst for H2 production in aqueous solution under visible light irradiation. International Journal of Hydrogen Energy, 36(21), 13501–13507. https://doi.org/10.1016/j.ijhydene.2011.08.052.
Yang, G., Yan, W., Wang, J., & Yang, H. (2014). Fabrication and characterization of CoTiO3 nanofibers by sol–gel assisted electrospinning. Materials Letters, 122, 117–120. https://doi.org/10.1016/j.matlet.2014.01.177.
Yang, Q., Choi, H., Al-Abed, S. R., & Dionysiou, D. D. (2009). Iron–cobalt mixed oxide nanocatalysts: heterogeneous peroxymonosulfate activation, cobalt leaching, and ferromagnetic properties for environmental applications. Applied Catalysis B: Environmental, 88(3–4), 462–469. https://doi.org/10.1016/j.apcatb.2008.10.013.
Yao, Y., Yang, Z., Sun, H., & Wang, S. (2012). Hydrothermal synthesis of Co3O4–graphene for heterogeneous activation of peroxymonosulfate for decomposition of phenol. Industrial & Engineering Chemistry Research, 51(46), 14958–14965. https://doi.org/10.1021/ie301642g.
Zhang, G., Li, C., Liu, J., Zhou, L., Liu, R., Han, X., et al. (2014). One-step conversion from metal-organic frameworks to Co3O4@N-doped carbon nanocomposites towards highly efficient oxygen reduction catalysts. Journal of Materials Chemistry A, 2(22), 8184–8189. https://doi.org/10.1039/C4TA00677A.
Zhou, G.-W., Lee, D. K., Kim, Y. H., Kim, C. W., & Kang, Y. S. (2006). Preparation and spectroscopic characterization of ilmenite-type CoTiO3 nanoparticles. Bulletin of the Korean Chemical Society, 27(3), 368–372.
Zhu, J., Ding, J.-J., Liu, X.-Q., Tan, P., & Sun, L.-B. (2016). Realizing both selective adsorption and efficient regeneration using adsorbents with photo-regulated molecular gates. Chemical Communications, 52(21), 4006–4009. https://doi.org/10.1039/C5CC10634F.
Zhu, M.-X., Lee, L., Wang, H.-H., & Wang, Z. (2007). Removal of an anionic dye by adsorption/precipitation processes using alkaline white mud. Journal of Hazardous Materials, 149(3), 735–741. https://doi.org/10.1016/j.jhazmat.2007.04.037.
Zollinger, H. (1998). Color chemistry. Weinheim: VCH.