Efficient degradation of diclofenac by LaFeO3-Catalyzed peroxymonosulfate oxidation---kinetics and toxicity assessment

Al-Hamadani, 2018, Sonocatalytic degradation of carbamazepine and diclofenac in the presence of graphene oxides in aqueous solution, Chemosphere, 205, 719, 10.1016/j.chemosphere.2018.04.129 Anipsitakis, 2006, Cobalt-mediated activation of peroxymonosulfate and sulfate radical attack on phenolic compounds. Implications of chloride ions, Environ. Sci. Technol., 40, 1000, 10.1021/es050634b Ball, 1956, The kinetics and mechanism of the decomposition of caros acid.1, J. Am. Chem. Soc., 78, 1125, 10.1021/ja01587a011 Baran, 2006, Toxicity and biodegradability of sulfonamides and products of their photocatalytic degradation in aqueous solutions, Chemosphere, 65, 1295, 10.1016/j.chemosphere.2006.04.040 Ben Hammouda, 2017, Degradation and mineralization of phenol in aqueous medium by heterogeneous monopersulfate activation on nanostructured cobalt based-perovskite catalysts ACoO(3) (A = La, Ba, Sr and Ce): characterization, kinetics and mechanism study, Appl. Catal. B Environ., 215, 60, 10.1016/j.apcatb.2017.05.051 Chan, 2009, Degradation of atrazine by cobalt-mediated activation of peroxymonosulfate: different cobalt counteranions in homogenous process and cobalt oxide catalysts in photolytic heterogeneous process, Water Res., 43, 2513, 10.1016/j.watres.2009.02.029 Chen, 2018, Accelerated photocatalytic degradation of diclofenac by a novel CQDs/BiOCOOH hybrid material under visible-light irradiation: dechloridation, detoxicity, and a new superoxide radical model study, Chem. Eng. J., 332, 737, 10.1016/j.cej.2017.09.118 Chen, 2016, Effective mineralization of Diclofenac by catalytic ozonation using Fe-MCM-41 catalyst, Chem. Eng. J., 304, 594, 10.1016/j.cej.2016.06.139 Corcoran, 2010, Pharmaceuticals in the aquatic environment: a critical review of the evidence for health effects in fish, Crit. Rev. Toxicol., 40, 287, 10.3109/10408440903373590 Delatorre, 1991, Nitrate-dependent O2 evolution in intact leaves, Plant Physiol., 96, 898, 10.1104/pp.96.3.898 Duan, 2018, Insights into perovskite-catalyzed peroxymonosulfate activation: maneuverable cobalt sites for promoted evolution of sulfate radicals, Appl. Catal. B Environ., 220, 626, 10.1016/j.apcatb.2017.08.088 EU, 2013, Directive 2013/39/EU of the European parliament and of the council amending directives 2000/60/EC and 2008/105/EC as regards priority substances in the field of water policy, Off. J. Eur. Commun., 226, 1 Flanagan, 1984, The active principle of caros acid, HSO5---X-ray crystal structure of KHSO5.H2O, J. Chem. Soc., Chem. Commun., 1574, 10.1039/C39840001574 Gavrilescu, 2015, Emerging pollutants in the environment: present and future challenges in biomonitoring, ecological risks and bioremediation, N. Biotech., 32, 147, 10.1016/j.nbt.2014.01.001 Goodman, 1963, Decomposition of inorganic peroxyacids in aqueous alkali, J. Chem. Soc., 2871, 10.1039/jr9630002871 Gray, 1959, Chemistry of free radicals containing oxygen. 2. Thermochemistry of the hydroxyl and hydroperoxyl radicals, Trans. Faraday Soc., 55, 408, 10.1039/TF9595500408 Guan, 2011, Influence of pH on the formation of sulfate and hydroxyl radicals in the UV/peroxymonosulfate system, Environ. Sci. Technol., 45, 9308, 10.1021/es2017363 Hao, 2014, Intensification of sonochemical degradation of ammonium perfluorooctanoate by persulfate oxidant, Ultrason. Sonochem., 21, 554, 10.1016/j.ultsonch.2013.09.016 Jaafarzadeh, 2017, Catalytic degradation of 2,4-dichlorophenoxyacetic acid (2,4-D) by nano-Fe2O3 activated peroxymonosulfate: influential factors and mechanism determination, Chemosphere, 169, 568, 10.1016/j.chemosphere.2016.11.038 Janzen, 1992, Stabilities of hydroxyl radical spin adducts of PBN-type spin traps, Free Radical Biol. Med., 12, 169, 10.1016/0891-5849(92)90011-5 Ji, 2013, Efficient performance of porous Fe2O3 in heterogeneous activation of peroxymonosulfate for decolorization of Rhodamine B, Chem. Eng. J., 231, 434, 10.1016/j.cej.2013.07.053 Kolthoff, 1951, The chemistry of persulfate.1. The kinetics and mechanism of the decomposition of the persulfate ion in aqueous medium, J. Am. Chem. Soc., 73, 3055, 10.1021/ja01151a024 Lau, 2007, The aqueous degradation of butylated hydroxyanisole by UV/S2O82-: study of reaction mechanisms via dimerization and mineralization, Environ. Sci. Technol., 41, 613, 10.1021/es061395a Lin, 2017, LaMO3 perovskites (M=Co, Cu, Fe and Ni) as heterogeneous catalysts for activating peroxymonosulfate in water, Chem. Eng. Sci., 160, 96, 10.1016/j.ces.2016.11.017 Maruthamuthu, 1977, Radiolytic chain decomposition of peroxomonophosphoric and peroxomonosulfuric acid, J. Phys. Chem., 81, 937, 10.1021/j100525a001 Miao, 2018, Nanostructured Co-Mn containing perovskites for degradation of pollutants: insight into the activity and stability, J. Hazard Mater., 349, 177, 10.1016/j.jhazmat.2018.01.054 Negri, 1998, Caroate delignification Part 4: the generation and role of hydroxyl radicals, Tappi J., 81, 241 Neta, 1988, Rate constants for reactions of inorganic radicals in aqueous solution, J. Phys. Chem. Ref. Data, 17, 1027, 10.1063/1.555808 Olmez-Hanci, 2013, Comparison of sulfate and hydroxyl radical based advanced oxidation of phenol, Chem. Eng. J., 224, 10, 10.1016/j.cej.2012.11.007 Olmez-Hanci, 2014, Investigation of the toxicity of common oxidants used in advanced oxidation processes and their quenching agents, J. Hazard Mater., 278, 330, 10.1016/j.jhazmat.2014.06.021 Osman, 1999, Role of nitrate in photosynthetic electron transport of Chlorella vulgaris, Photosynthetica, 36, 389, 10.1023/A:1007071902295 Pang, 2016, LaCoO3 perovskite oxide activation of peroxymonosulfate for aqueous 2-phenyl-5-sulfobenzimidazole degradation: effect of synthetic method and the reaction mechanism, Chem. Eng. J., 304, 897, 10.1016/j.cej.2016.07.027 Rao, 2016, Sonolytic and sonophotolytic degradation of Carbamazepine: kinetic and mechanisms, Ultrason. Sonochem., 32, 371, 10.1016/j.ultsonch.2016.04.005 Rao, 2018, Heterogeneous activation of peroxymonosulfate by LaFeO3 for diclofenac degradation: DFT-assisted mechanistic study and degradation pathways, Chem. Eng. J., 352, 601, 10.1016/j.cej.2018.07.062 Rao, 2014, Degradation of carbamazepine by Fe(II)-activated persulfate process, J. Hazard Mater., 268, 23, 10.1016/j.jhazmat.2014.01.010 Sein, 2008, Oxidation of diclofenac with ozone in aqueous solution, Environ. Sci. Technol., 42, 6656, 10.1021/es8008612 Servin, 2013, Synchrotron verification of TiO2 accumulation in cucumber fruit: a possible pathway of TiO2 nanoparticle transfer from soil into the food chain, Environ. Sci. Technol., 47, 11592, 10.1021/es403368j Solis, 2017, Removal of aqueous metazachlor, tembotrione, tritosulfuron and ethofumesate by heterogeneous monopersulfate decomposition on lanthanum-cobalt perovskites, Appl. Catal. B Environ., 200, 83, 10.1016/j.apcatb.2016.06.058 Su, 2017, Mixed conducting perovskite materials as superior catalysts for fast aqueous-phase Advanced oxidation: a mechanistic study, ACS Catal., 7, 388, 10.1021/acscatal.6b02303 Tan, 2014, Radical induced degradation of acetaminophen with Fe3O4 magnetic nanoparticles as heterogeneous activator of peroxymonosulfate, J. Hazard Mater., 276, 452, 10.1016/j.jhazmat.2014.05.068 Wang, 2011, Degradation of a xanthene dye by Fe(II)-mediated activation of Oxone process, J. Hazard Mater., 186, 1455, 10.1016/j.jhazmat.2010.12.033 Wang, 2011, Toxicity and internalization of CuO nanoparticles to prokaryotic alga Microcystis aeruginosa as affected by dissolved organic matter, Environ. Sci. Technol., 45, 6032, 10.1021/es2010573 Yang, 2010, Degradation efficiencies of azo dye Acid Orange 7 by the interaction of heat, UV and anions with common oxidants: persulfate, peroxymonosulfate and hydrogen peroxide, J. Hazard Mater., 179, 552, 10.1016/j.jhazmat.2010.03.039 Yang, 2014, Comparison of halide impacts on the efficiency of contaminant degradation by sulfate and hydroxyl radical-based advanced oxidation processes (AOPs), Environ. Sci. Technol., 48, 2344, 10.1021/es404118q Zhang, 2013, Production of sulfate radical from peroxymonosulfate induced by a magnetically separable CuFe2O4 spinel in water: efficiency, stability, and mechanism, Environ. Sci. Technol., 47, 2784, 10.1021/es304721g Zhou, 2018, Rapid decomposition of diclofenac in a magnetic field enhanced zero-valent iron/EDTA Fenton-like system, Chemosphere, 193, 968, 10.1016/j.chemosphere.2017.11.090