Spin-Dependent Interactions of Fe2On Clusters with H2 and O2 MoleculesRussian Journal of Inorganic Chemistry - Tập 67 - Trang 2003-2008 - 2022
K. V. Bozhenko, A. N. Utenyshev, L. G. Gutsev, S. M. Aldoshin, G. L. Gutsev
The geometry and electronic structure of the Fe2O, Fe2O3, and Fe2O5 clusters and the products of their interaction with H2 and O2 in the gas phase have been calculated by the density functional theory method in the generalized gradient approximation using the triple-ζ basis set. Trends in bond energies of H2 and O2 in the products of the Fe2O2 n + 1 + O2 and Fe2O2n + 1 + H2 (n = 0–2) reactions hav...... hiện toàn bộ
Limiting equivalent electrical conductivity of inorganic salt solutions and dielectric properties of a polar solventRussian Journal of Inorganic Chemistry - Tập 58 - Trang 968-971 - 2013
V. V. Shcherbakov, Yu. M. Artemkina
A relation has been found to exist between the limiting equivalent electrical conductivity of inorganic salt solutions, viscosity, temperature, and dielectric properties of the solvent. As temperature rises, the limiting equivalent electrical conductivity of aqueous solution of an inorganic salt has been shown to increase in direct proportion to the ratio of the dielectric permittivity to the dipo...... hiện toàn bộ
Thermodynamic Characteristics of Lithium Pivalate according to High-Temperature Mass Spectrometry DataRussian Journal of Inorganic Chemistry - Tập 66 - Trang 868-873 - 2021
D. B. Kayumova, I. P. Malkerova, M. A. Kiskin, A. S. Alikhanyan
The vaporization of lithium pivalate (CH3)3CCOOLi (LiPiv) was studied by the Knudsen effusion method with the mass spectral analysis of the gas phase. The saturated vapor consisted of polynuclear molecules (LiPiv)n, dominated by (LiPiv)2 and (LiPiv)4 molecules. The absolute values of the partial pressures of these molecules and their dependence on temperature were calculated. The standard enthalpi...... hiện toàn bộ
Electrospray mass spectra of aqueous solutions of 4f-3d heterometallic chelatesRussian Journal of Inorganic Chemistry - Tập 52 - Trang 1775-1780 - 2007
A. M. Makarevich, B. G. Kimel’, N. P. Kuz’mina
The composition of aqueous solutions of the heterometallic chelates MLnDTPA and Ln2M3(EDTA)3 (H5DTPA = diethylenetriaminepentaacetic acid; H4EDTA = ethylenediaminetetraacetic acid; Ln = Eu, La; M = Ni, Mn) and the monometallic chelates H3Ni(DTPA), HNi2(DTPA), H2La(DTPA), and H2Eu(DTPA) was studied by electrospray mass spectrometry (ESIMS). The mass spectra indicate that there is equilibrium betwee...... hiện toàn bộ