Russian Journal of Inorganic Chemistry

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Spin-Dependent Interactions of Fe2On Clusters with H2 and O2 Molecules
Russian Journal of Inorganic Chemistry - Tập 67 - Trang 2003-2008 - 2022
K. V. Bozhenko, A. N. Utenyshev, L. G. Gutsev, S. M. Aldoshin, G. L. Gutsev
The geometry and electronic structure of the Fe2O, Fe2O3, and Fe2O5 clusters and the products of their interaction with H2 and O2 in the gas phase have been calculated by the density functional theory method in the generalized gradient approximation using the triple-ζ basis set. Trends in bond energies of H2 and O2 in the products of the Fe2O2 n + 1 + O2 and Fe2O2n + 1 + H2 (n = 0–2) reactions hav...... hiện toàn bộ
Interaction of components in the RbI-CsI-CuI quasi-ternary system
Russian Journal of Inorganic Chemistry - - 2013
Т.О. Malakhovska, И. Е. Барчий, А.І. Погодін, A. P. Kokhan, I. P. Stercho, E. Yu. Peresh
Kinetics of the formation of precipitates and the physicochemical properties of technetium-99 and rhenium sulfides according to small-angle X-ray scattering and ultramicrocentrifugation data
Russian Journal of Inorganic Chemistry - - 2016
K. É. German, Ya. A. Obruchnikova, Alexey Safonov, V. E. Tregubova, А. В. Афанасьев, A. V. Kopytin, O. S. Kryzhovets, Frédéric Poineau, E. V. Abkhalimov, A. A. Shiryaev
Effects caused by glutamic acid and hydrogen peroxide on the morphology of hydroxyapatite, calcium hydrogen phosphate, and calcium pyrophosphate
Russian Journal of Inorganic Chemistry - - 2015
L. S. Skogareva, V. K. Ivanov, А. Е. Baranchikov, N. A. Minaeva, T. A. Tripol’skaya
To the Properties of Fluorosilicic Acid: Evolution of Views on the State in Aqueous Solutions (Overview)
Russian Journal of Inorganic Chemistry - - 2018
V. O. Gelmboldt
The views of different authors on equilibria in solutions of fluorosilicic acid are discussed. The model of the aid as an equilibrium system involving hexacoordinated complexes [SiF6–n(H2O)n]n–2 (n = 0–2) is believed to be the most adequate.
Perbrominated Sulfonium-Substituted closo-Decaborates with exo-Polyhedral Amino Groups [2-B10Br9S((CH2)nNH2)2]– (n = 1–3)
Russian Journal of Inorganic Chemistry - Tập 65 - Trang 1333-1342 - 2020
A. V. Golubev, A. S. Kubasov, E. S. Turyshev, A. Yu. Bykov, K. Yu. Zhizhin, N. T. Kuznetsov
A method for preparing fully brominated sulfonium derivatives of the closo-decaborate anion with functional amino groups (n-Bu4N)[2-B10Br9S((CH2)nNH2)2]– (n = 1–3) has been developed. The method is based on the interaction between sulfonium derivatives of the closo-decaborate anion with phthalimide groups (n-Bu4N)[2-B10Br9S((CH2)npht)2]– (n = 1–3) and elemental bromine in acetonitrile in an inert ...... hiện toàn bộ
Ammonia Borane in Nanotubes: The Preference of Eclipsed Conformation
Russian Journal of Inorganic Chemistry - - 2018
В. В. Кузнецов
Study of Hydrolysis Kinetic of New Laser Material [anti-B18H22]
Russian Journal of Inorganic Chemistry - Tập 64 - Trang 1359-1364 - 2019
Chun-hua Tan, Bao-kai Zhang, Jie Chen, Lin-na Zhang, Xu-guang Huang, Hong-yun Meng
[anti-B18H22] is a potential blue laser material. In order to study the stability of [anti-B18H22] in aqueous solution, the hydrolytic reaction kinetic of [anti-B18H22] at various pH values and temperatures was studied by fluorescence spectroscopy. The results showed that [anti-B18H22] hydrolysis rate was accelerated by increasing temperature, and the trend showed that [anti-B18H22] hydrolyzed fas...... hiện toàn bộ
Synthesis and chemical stability of (5,15-bis(2-thienyl)- and 5,15-diphenyl-3,7,13,17-tetramethyl-2,8,12,18-tetra-n-butyl-21H,23H-porphinato)copper(II)
Russian Journal of Inorganic Chemistry - Tập 59 - Trang 237-243 - 2014
M. E. Klyueva, A. A. Nikitin, T. N. Lomova, A. S. Semeikin
(5,15-Bis(2-thienyl)-and 5,15-diphenyl-3,7,13,17-tetramethyl-2,8,12,18-tetra-n-butyl-21H,23H-porphinato)copper(II) complexes were synthesized and the basicity, absorption spectra (UV-Vis, IR, 1H NMR) of the macrocyclic ligands and the stability of the complexes in AcOH-H2SO4 mixed solvents were studied with the aim to reveal the effect of 2-thienyl substituent on the properties of substituted porp...... hiện toàn bộ
Synthesis, crystal structure, and vibrational spectra of MVO(SO4)2 (M = Rb, Cs, or Tl)
Russian Journal of Inorganic Chemistry - Tập 58 - Trang 127-133 - 2013
V. N. Krasil’nikov, A. P. Tyutyunnik, L. A. Perelyaeva, I. V. Baklanova
A series of MVO(SO4)2 vanadium complexes, where M = Rb, Cs, or Tl, were prepared, and their crystal structures and physicochemical properties studied. The rubidium and thallium compounds of this series were found to be isostructural to each other and to crystallize, like KVO(SO4)2 and NH4VO(SO4)2, in orthorhombic system (space group P212121, No. 19, Z = 4) with the unit cell parameters a = 4.9735(...... hiện toàn bộ
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