Moscow University Chemistry Bulletin

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Forecasting the damaging factors during transport accidents with the participation of yellow phosphorus
Moscow University Chemistry Bulletin - Tập 68 Số 1 - Trang 41-46 - 2013
N. M. Ishmaev, E. S. Nikolina, Victor Andreevich Mamontov, N. I. Burdakov
X-ray fluorescence determination of lanthanum, cerium, praseodymium, and neodymium in technological solutions after preconcentration on DETATA cellulose filters
Moscow University Chemistry Bulletin - Tập 71 - Trang 178-181 - 2016
N. M. Sorokina, G. I. Tsysin
Sorption of some rare earth elements on filters with immobilized diethylenetriaminetetraacetate (DETATA) groups was studied. It was shown that the elements are quantitatively extracted from solutions with volume of 20–500 mL at pH values ranging between 3.5 and 5.5 and a flow rate from 1 to 8 mL/min. It was proposed to use masking agents such as sulfosalicylic acid and 1,10-phenanthroline for extr...... hiện toàn bộ
Boronated derivatives of protohemin IX with L-amino acids as potential anticancer agents
Moscow University Chemistry Bulletin - Tập 62 Số 5 - Trang 238-242 - 2007
Savchenko, A. N., Ol’shevskaya, V. A., Kalinin, V. N., Shtil, A. A.
New water-soluble conjugates of protohemin IX with an anionic 1-carba-closo-dodecaborate polyhedron and L-amino acids have been synthesized. In these compounds, the amino acid residues are bound to the porphyrin ring through the amide or ester bond. The new water-soluble amino acid derivatives of boronated protohemin IX show high antitumor activity for human tumor cell lines.
Application of Laser-Induced Breakdown Spectrometry for analysis of environmental and industrial materials
Moscow University Chemistry Bulletin - Tập 64 - Trang 366-377 - 2010
A. M. Popov, T. A. Labutin, N. B. Zorov
Actual state of affairs, main advantages and problems of Laser-Induced Breakdown Spectroscopy (LIBS) in analysis of industrial materials and environmental samples are discussed. Methods for LIBS sensitivity enhancement such as double-pulse ablation, a combination of LIBS with laser-induced fluorescence, the use of additional sources of excitation (spark) and confinement of plasma by magnetic field...... hiện toàn bộ
Biocatalytic Synthesis of Conducting Poly(3,4-Ethylenedioxythiophene) Using a Natural DNA Template
Moscow University Chemistry Bulletin - - 2019
И. С. Васильева, M. E. Khlupova, Г. П. Шумакович, Е. А. Зайцева, О. В. Морозова, A. I. Yaropolov
Reaction of unsaturated compounds with the thiobisamine-SOHal2 system
Moscow University Chemistry Bulletin - Tập 69 - Trang 254-265 - 2015
N. V. Zyk, A. Yu. Gavrilova, M. A. Nechaev, O. B. Bondarenko, N. S. Zefirov
A convenient method for the synthesis of di(β-haloalkyl)sulfides based on the reaction of unsaturated compounds with the thiobisamine-SOHal2 (Hal = Cl, Br) system was created. The reaction proceeds through an electrophilic mechanism with the formation of trans-addition products. Reactions with alkynes result in the formation of a mixture of regioisomeric divinyl sulfides.
Assessment of the Stability of a Mercury Film on a Glass–Ceramic Carbon Electrode when Determining Zinc in the Presence of Manganese by Anodic Stripping Voltammetry
Moscow University Chemistry Bulletin - Tập 73 - Trang 280-284 - 2019
I. P. Viter, A. I. Kamenev
The possibility of assessing the stability of operation of a mercury film graphite electrode in anodic stripping voltammetry using Shewhart control charts (CCs) is shown. The offered technique allows significantly increasing the efficiency of the voltammetric determination of zinc and manganese and taking measurements of analytes in samples during a working day without replacing the mercury film o...... hiện toàn bộ
Cairo tiling and the topology of layered hydrates
Moscow University Chemistry Bulletin - Tập 66 - Trang 159-160 - 2011
A. M. Banaru, G. A. Banaru
Cairo tiling, one of fifteen Laves regular nets, is the prototype of numerous water nets made of hydrogen bonds in crystalline hydrates. In this work, topological comparison of idealized and corrugated Cairo tilings is performed; their critical coordination numbers are calculated.
Infrared spectrum and structure of 2-thienyl-N-methylfulleropyrrolidine
Moscow University Chemistry Bulletin - Tập 62 - Trang 72-78 - 2007
V. I. Korepanov, A. A. Popov, V. M. Senyavin, M. A. Yurovskaya, E. S. Chernyshova
The IR and 1H NMR spectra of 2-thienyl-N-methylfulleropyrrolidine are studied. The complete interpretation of the spectra is carried out on the basis of density functional theory calculations. Conformational composition is analyzed by means of both computational and experimental methods.
New Solutions in Decarbonization Technology
Moscow University Chemistry Bulletin - Tập 78 - Trang 324-325 - 2023
L. A. Tjurina, E. A. Babakov, M. Ya. Melnikov
It is shown that the removal of CO2 from a gas can be implemented in a disk film absorber using water as an absorbent. The proposed technical solution is focused on solving various decarbonization problems.
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