Reaction of unsaturated compounds with the thiobisamine-SOHal2 system
Tóm tắt
A convenient method for the synthesis of di(β-haloalkyl)sulfides based on the reaction of unsaturated compounds with the thiobisamine-SOHal2 (Hal = Cl, Br) system was created. The reaction proceeds through an electrophilic mechanism with the formation of trans-addition products. Reactions with alkynes result in the formation of a mixture of regioisomeric divinyl sulfides.
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