Mechanochemical Synthesis of Double Hydroxides Tập 8 - Trang 251-253 - 2000
V. P. Isupov, L. E. Chupakhina, R. P. Mitrofanova
It has been demonstrated that the formation of magnesium-aluminium double
hydroxides [Mg(1 − X)Al X (OH)2] X+(A n− X/n ) • m H2O, (A–Cl−, NO− 3, SO2− 4)
occurs during mechanical activation of the mixture of magnesium hydroxide
(brucite) with aluminium chloride, nitrate and sulphate in high-energy
planetary-type activators. The effect of activation time on the formation of the
double hydroxide has ... hiện toàn bộ
MSR Reduction of Hexachlorobenzene Tập 8 - Trang 295-300 - 2000
M. Monagheddu, S. Doppiu, G. Cocco
This paper deals with the mechanochemical degradation of hexachlorobenzene over
Li, Na, K, Mg, Ca, Ba, Ti, and W. Apart from the mixtures containing Ti and W,
the other systems react in a combustive mode leading to the chlorides and the
carbides of the inorganic substrates. Reaction stoichiometries and heats were
experimentally determined. The activation time required to ignite the reaction
decrea... hiện toàn bộ
Reaction Bonding of Three-Layer Alumina-Based Composites Tập 7 - Trang 195-203 - 1999
Jihong She, Sven Scheppokat, Rolf Janssen, Nils Claussen
Three-layer alumina-based composites with Al2O3-containing mullite as the outer
layer and ZrO2-containing alumina as the inner layer were fabricated by
die-pressing and reaction bonding. The effects of the outer-layer compositions
on the densification behavior of three-layer composites were investigated. The
existence of residual stresses in the layers was verified using indentation
methods. Compa... hiện toàn bộ
Chemical Durability of Waste Fluorescent Glass and Shell–Derived Glass-Ceramics Tập 10 - Trang 37-42 - 2002
Y.-H. Yun, S.-B. Kim, B.-A. Kang, J.-S. Oh, K.-S. Hwang
In order to obtain glass-ceramics reinforced by β-wollastonite, pressed
specimens prepared by powdered waste fluorescent glass and refuse shell dumped
in the seashore were heat-treated at 800°C, 900°C, and 1000°C. Chemical
stability of the heat-treated specimens was analyzed by weight changes and by
observation of surface morphology and composition, by field-emission scanning
electron microscopy a... hiện toàn bộ
High-Pressure Processing and Characterization of Fe–High-C/N Alloys Tập 6 - Trang 147-154 - 1998
J. Rawers, G. Slavens, H. Du
A new process has been developed that results in (i) enhanced nitrogen addition
to ferritic iron–carbon alloys and (ii) melt-casting in a single operation. This
new processing technique enables Fe–C alloys to retain high nitrogen
interstitial concentrations and to reduce significantly, and possibly eliminate,
carbide formation. In this study two commercial-grade, steel alloys were cast
under eleva... hiện toàn bộ
Microwave Sintering of Alumina Using Four Single-Cavity Modes Tập 7 - Trang 159-166 - 1999
Ki-Yong Lee, Paul H. Dearhouse, Eldon D. Case
In this study, alumina ceramics were sintered with 2.45-GHz microwaves in a
cylindrical single-mode microwave cavity using four resonant cavity modes:
TM111, TE112, TE113, and TM013. The mass density and grain size of sintered
specimens were found to be relatively uniform with respect to both (i) the
radial position within a given specimen and (ii) the cavity mode used to sinter
the specimen. Howe... hiện toàn bộ
Combustion Synthesis of Glass (B2O3-Al2O3-MgO)-Ceramic (TiB2) Composites Tập 10 - Trang 163-174 - 2002
H. C. Yi, J. Y. Guigne, J. J. Moore, A. R. Manerbino, L. A. Robinson, F. D. Schowengerdt
The combustion synthesis, or self-propagating high temperature synthesis (SHS),
technique has been used to produce glass ceramic composites that have a glass
matrix based on B2O3-MgO-Al2O3and a crystalline ceramic phase of TiB2.
Conditions for producing glassy materials by the SHS technique are discussed and
the thermodynamics of these combustion reactions are analyzed. The combustion
characterist... hiện toàn bộ
Mössbauer Studies in the Mechanochemistry of Spinel Ferrites Tập 8 - Trang 155-166 - 2000
V. Šepelák, K. D. Becker
Mössbauer spectroscopy can provide information on a large variety of
mechanochemical processes in solids. In this overview, selected examples are
presented of Mössbauer studies of homogeneous and heterogeneous mechanochemical
reactions in spinel ferrites. Several interesting features are involved in the
work, e.g., mechanically induced cation redistributions, changes of
nearest-neighbor configurat... hiện toàn bộ