Mechanochemical Synthesis of Double Hydroxides Tập 8 - Trang 251-253 - 2000
V. P. Isupov, L. E. Chupakhina, R. P. Mitrofanova
It has been demonstrated that the formation of magnesium-aluminium double
hydroxides [Mg(1 − X)Al X (OH)2] X+(A n− X/n ) • m H2O, (A–Cl−, NO− 3, SO2− 4)
occurs during mechanical activation of the mixture of magnesium hydroxide
(brucite) with aluminium chloride, nitrate and sulphate in high-energy
planetary-type activators. The effect of activation time on the formation of the
double hydroxide has ... hiện toàn bộ
MSR Reduction of Hexachlorobenzene Tập 8 - Trang 295-300 - 2000
M. Monagheddu, S. Doppiu, G. Cocco
This paper deals with the mechanochemical degradation of hexachlorobenzene over
Li, Na, K, Mg, Ca, Ba, Ti, and W. Apart from the mixtures containing Ti and W,
the other systems react in a combustive mode leading to the chlorides and the
carbides of the inorganic substrates. Reaction stoichiometries and heats were
experimentally determined. The activation time required to ignite the reaction
decrea... hiện toàn bộ
Combustion Synthesis of Glass (B2O3-Al2O3-MgO)-Ceramic (TiB2) Composites Tập 10 - Trang 163-174 - 2002
H. C. Yi, J. Y. Guigne, J. J. Moore, A. R. Manerbino, L. A. Robinson, F. D. Schowengerdt
The combustion synthesis, or self-propagating high temperature synthesis (SHS),
technique has been used to produce glass ceramic composites that have a glass
matrix based on B2O3-MgO-Al2O3and a crystalline ceramic phase of TiB2.
Conditions for producing glassy materials by the SHS technique are discussed and
the thermodynamics of these combustion reactions are analyzed. The combustion
characterist... hiện toàn bộ
Reaction Bonding of Three-Layer Alumina-Based Composites Tập 7 - Trang 195-203 - 1999
Jihong She, Sven Scheppokat, Rolf Janssen, Nils Claussen
Three-layer alumina-based composites with Al2O3-containing mullite as the outer
layer and ZrO2-containing alumina as the inner layer were fabricated by
die-pressing and reaction bonding. The effects of the outer-layer compositions
on the densification behavior of three-layer composites were investigated. The
existence of residual stresses in the layers was verified using indentation
methods. Compa... hiện toàn bộ
Chemical Durability of Waste Fluorescent Glass and Shell–Derived Glass-Ceramics Tập 10 - Trang 37-42 - 2002
Y.-H. Yun, S.-B. Kim, B.-A. Kang, J.-S. Oh, K.-S. Hwang
In order to obtain glass-ceramics reinforced by β-wollastonite, pressed
specimens prepared by powdered waste fluorescent glass and refuse shell dumped
in the seashore were heat-treated at 800°C, 900°C, and 1000°C. Chemical
stability of the heat-treated specimens was analyzed by weight changes and by
observation of surface morphology and composition, by field-emission scanning
electron microscopy a... hiện toàn bộ
Optimization of the LENS Rapid Fabrication Process for In-Flight Melting of Feed Powder Tập 9 - Trang 223-233 - 2001
M. Grujicic, Y. Hu, G. M. Fadel, D. M. Keicher
A model for in-flight melting of feed-powder particles propelled through a laser
beam in the Laser-Engineered Net Shaping (LENS) process has been developed. The
model is next incorporated in an optimization analysis to determine optimum LENS
process parameters (laser power, particle velocity, and the angle between the
laser-beam axis and particle trajectory), which maximize the probability for
in-... hiện toàn bộ
Effects of Nanocrystalline Powders Additions on the Characteristics of Combustion Process, Phase- and Structure-Formation, and Properties of SHS Alloys on Titanium Carbide Base Tập 10 - Trang 231-236 - 2002
E. A. Levashov, O. V. Malochkin, A. E. Kudryashov, F. Gammel, R. Suchentrunk
A study was made of the effect of different nanocrystalline powders additives on
the macrokinetics of combusting Ti-Cr-C-Ni mixtures as well as on the
composition, structure, and physical-mechanical properties of SHIM-SB alloy
produced by the power SHS-compaction technique. An additive of nanocrystalline
powder is found to result in 2- to 5-fold modification of alloy structure and,
in most cases, ... hiện toàn bộ
Fabrication of Intermetallic Compounds by Spark Plasma Sintering Tập 7 - Trang 303-309 - 1999
Tae-Young Um, Toshihiko Abe, Shinichi Sumi
The characteristics of spark plasma sintering, a new method of powder
processing, were investigated. Four systems of intermetallic compounds—Ti-Al,
Ti-Al-Cr, Mo-Si, and Mo-Si-Nb—were fabricated, and the formation process of
compounds, the formed phases, and the microstructure of samples were observed.
During the sintering of all the compositions of mixed powders, most of the
compounds were formed ... hiện toàn bộ