Prospects for Alkaline Anion‐Exchange Membranes in Low Temperature Fuel Cells Tập 5 Số 2 - Trang 187-200 - 2005
John R. Varcoe, Robert C. T. Slade
AbstractThis article introduces the radical approach of applying alkaline
anion‐exchange membranes (AAEMs) to meet the current challenges with regards to
direct methanol fuel cells (DMFCs). A review of the literature is presented with
regards to the testing of fuel cells with alkaline membranes (fuelled with
hydrogen or methanol) and also to candidate alkaline anion‐exchange membranes
for such an ... hiện toàn bộ
PBI‐Based Polymer Membranes for High Temperature Fuel Cells – Preparation, Characterization and Fuel Cell Demonstration Tập 4 Số 3 - Trang 147-159 - 2004
Qingfeng Li, Ronghuan He, Jens Oluf Jensen, Niels Bjerrum
AbstractProton exchange membrane fuel cell (PEMFC) technology based on
perfluorosulfonic acid (PFSA) polymer membranes is briefly reviewed. The newest
development in alternative polymer electrolytes for operation above 100 °C is
summarized and discussed. As one of the successful approaches to high
operational temperatures, the development and evaluation of acid doped
polybenzimidazole (PBI) membra... hiện toàn bộ
The Chemical and Structural Nature of Proton Exchange Membrane Fuel Cell Properties Tập 5 Số 2 - Trang 213-229 - 2005
Michael A. Hickner, Bryan S. Pivovar
AbstractThe chemical and structural (morphological) features of proton exchange
membranes are directly tied to their fuel cell relevant transport properties. A
large body of research has focused on characterizing the structure or
investigating the properties of Nafion® and other proton exchange membranes, but
few studies have linked chemical composition to membrane morphology, and
resulting transp... hiện toàn bộ
Synthesis and Characterization of Pyridine‐Based Polybenzimidazoles for High Temperature Polymer Electrolyte Membrane Fuel Cell Applications Tập 5 Số 2 - Trang 287-295 - 2005
Liuling Xiao, H. Zhang, Tushar Jana, Eugene Scanlon, Ruitai Chen, E. W. Choe, L. S. Ramanathan, Seonghan Yu, Brian C. Benicewicz
AbstractA series of polybenzimidazoles (PBIs) incorporating main chain pyridine
groups were synthesized from the pyridine dicarboxylic acids (2,4‐, 2,5‐, 2,6‐
and 3,5‐) and 3,3′,4,4′‐tetraaminobiphenyl, using polyphosphoric acid (PPA) as
both solvent and polycondensation reagent. A novel process, termed the PPA
process, has been developed to prepare phosphoric acid (PA) doped PBI membranes
by dire... hiện toàn bộ
Sodium Borohydride Hydrolysis as Hydrogen Generator: Issues, State of the Art and Applicability Upstream from a Fuel Cell Tập 10 Số 3 - Trang 335-350 - 2010
Umit B. Demirci, Ouardia Akdim, A. Khoury, J. Hannauer, Philippe Miele
AbstractToday there is a consensus regarding the potential of NaBH4 as a good
candidate for hydrogen storage and release via hydrolysis reaction, especially
for mobile, portable and niche applications. However as gone through in the
present paper two main issues, which are the most investigated throughout the
open literature, still avoid NaBH4 to be competitive. The first one is water
handling. Th... hiện toàn bộ
Synthetic Strategies for Controlling the Morphology of Proton Conducting Polymer Membranes Tập 5 Số 2 - Trang 171-186 - 2005
Yuan Yang, Steven Holdcroft
AbstractThe nanostructure and morphology of proton conducting polymers is of
considerable interest in the search for next generation materials and
optimization of existing ones. Synthetic methodologies for tailoring molecular
structures that promote nanoscopic phase separation of ionic and non‐ionic
domains, and the effect of phase separation on parameters such as proton
conductivity, are consider... hiện toàn bộ
Anion‐Exchange Membranes for Fuel Cells: Synthesis Strategies, Properties and Perspectives Tập 15 Số 6 - Trang 761-780 - 2015
Hongwei Zhang, Dongyang Chen, Yin Xianze, Shibin Yin
AbstractThis review focuses on various synthesis strategies of anion‐exchange
membranes (AEMs) for fuel cells, diverse methodologies of AEM‐forming, together
with relationship between structures and properties. AEMs are discussed from
seven categories, including (1) AEMs derived from Nafion precursors with
sulfonyl fluoride groups, which display excellent stability and well‐developed
morphologies ... hiện toàn bộ
Thin Film Microelectrodes in SOFC Electrode Research Tập 6 Số 3-4 - Trang 284-292 - 2006
Jürgen Fleig, F. Baumann, V. Brichzin, Hyungchul Kim, J. Jamnik, G. Cristiani, H.‐U. Habermeier, Joachim Maier
AbstractExperimental studies using conventional (porous) solid oxide fuel cell
(SOFC) electrodes are often rather difficult to interpret in terms of a
mechanistic understanding of the electrochemical polarization phenomena. Owing
to the complex morphology and structure of porous electrodes, a quantitative
determination of the properties of the electrochemical materials rather than of
the effective... hiện toàn bộ
Performance Improvement by Temperature Control of an Open‐Cathode PEM Fuel Cell System Tập 14 Số 3 - Trang 466-478 - 2014
Stephan Strahl, Attila Husar, Paul F. Puleston, Maria Serra
AbstractThe work presented in this article combines experimental analysis and
theoretical studies of temperature effects on the performance of an
open‐cathode, self‐humidified PEM fuel cell system for the design of optimal
control strategies. The experimental analysis shows the great potential of
improving the system performance by proper thermal management. The most
significant temperature depend... hiện toàn bộ