Preparation of Nitrate Bilayer Membrane Ion-Selective Electrode Modified by Pericarpium Granati-Derived Biochar and Its Application in Practical SamplesElectrocatalysis - Tập 14 - Trang 534-545 - 2023
Fozia, Guangyao Zhao, Yanhong Nie, Jianrong Jiang, Qian Chen, Chaogang Wang, Xu Xu, Ming Ying, Zhangli Hu, Hong Xu
In this study, a pericarpium granati-derived biochar with phosphoric acid
activation (PGCP) was prepared, characterized, and applied together with
polypyrrole (PPy) to modify a glass carbon electrode (GCE) to construct a
bilayer membrane nitrate ion-selective electrode (ISE, PPy/PGCP/GCE). The
morphological results showed that PGCP possessed a porous structures. X-ray
photoelectron spectroscopy an... hiện toàn bộ
Understanding the Influence of the Biomass-Derived Alcohols on the Activity and Stability of Pt Nanoparticles Supported on Graphene NanoribbonsElectrocatalysis - Tập 8 - Trang 151-163 - 2017
Rodrigo Teles, Ana Arenillas, Gabriel C. da Silva, Pablo S. Fernández, Eduardo S. F. Cardoso, Gilberto Maia, Cauê A. Martins
We produced Pt/GNRs by a one-step synthesis procedure and evaluated their
electroactivity and stability towards glycerol electrooxidation reaction (GEOR)
for the first time. We compared the electrocatalytic performance of GEOR with
methanol and ethanol electrooxidation on Pt/GNRs at identical experimental
conditions. The activities and stabilities for the electrooxidation of these
biomass-derived ... hiện toàn bộ
Functionalized Carbon Nanotubes for Highly Active and Metal-Free Electrocatalysts in Hydrogen Evolution ReactionElectrocatalysis - Tập 9 - Trang 573-581 - 2018
Tianhao Li, Daomei Tang, Zehua Cui, Bo Cai, Dalin Li, Qianyuan Chen, ChangMing Li
Six kinds of functionalized multiwalled carbon nanotubes (FCNTs) with different
functional moieties were utilized as metal-free electrocatalysts towards the
hydrogen evolution reaction for the first time. Ethylenediamine-functionalized
multiwalled carbon nanotubes (EDA-CNTs) delivered the best HER activity holding
a low-onset overpotential of 150 mV, a Tafel slope of 116 mV dec−1, and a
Faradaic e... hiện toàn bộ
Electrocatalytic Determination of Hg(II) by the Modified Carbon Paste Electrode with Sn(IV)-Clinoptilolite NanoparticlesElectrocatalysis - Tập 10 - Trang 466-476 - 2019
Tahmineh Tamiji, Alireza Nezamzadeh-Ejhieh
In this work, the electro-reduction of Hg(II) was studied by the modified carbon
paste electrode (CPE) with clinoptilolite nanoparticles (CNP) ion exchanged with
Sn(IV) cations (Sn(IV)-CNP/CPE). When the Sn(IV)-CNP/CPE electrode was immersed
in HCl as supporting electrolyte, the voltammetric peak currents were observed
for Sn(IV)/Sn(II) redox reactions in cyclic voltammetry. The reduction peak
cur... hiện toàn bộ
The “Particle Proximity Effect” in Three Dimensions: a Case Study on Vulcan XC 72RElectrocatalysis - Tập 7 - Trang 249-261 - 2016
Sebastian Proch, Kensaku Kodama, Masanori Inaba, Keiichiro Oishi, Naoko Takahashi, Yu Morimoto
The “particle proximity effect” is a hypothesis claiming that Pt nanoparticles
have higher ORR activity when they get closer to one another. In order to put
this hypothesis under scrutiny, the “tool-box” approach was investigated in each
process step by electron microscopy, ICP, and surface science methods. It is
shown that particle size stability is brought about by a NaCl shell which can
effecti... hiện toàn bộ
Electrochemical Deposited Amorphous Bimetallic Nickle-Iron (Oxy)hydroxides Electrocatalysts for Highly Efficient Oxygen Evolution ReactionElectrocatalysis - Tập 14 - Trang 429-436 - 2022
Zhichao Xu, Jianmin Wang, Jiajia Cai, Yitao He, Jing Hu, Haijin Li, Yongtao Li, Yong Zhou
The low-cost and high-performance electrocatalysts, especially metal
(oxy)hydroxides, for the oxygen evolution reaction (OER) have attracted
considerable attention due to their promising OER activity. Amorphous
electrocatalysts are often superior to their crystalline counterparts due to
their more actives and structural flexibility. However, using traditional
preparation techniques still presents ... hiện toàn bộ
Novel Carbon Quantum Dotted Reduced Graphene Oxide Nanosheets for Nano-molar Range Cadmium QuantificationElectrocatalysis - Tập 13 - Trang 435-446 - 2022
BarsanaBarvin RasulKhan, Sathish Kumar Ponnaiah, Jeyaprabha Balasubramanian, Prakash Periakaruppan
A carbon quantum dot (CQD)/reduced graphene oxide (rGO) nanocomposite modified
glassy carbon electrode (GCE) was developed as a novel system for
electrochemical detection of cadmium ion (Cd). The characterization of the
synthesized CQD/rGO nanocomposite was done by Fourier transform infrared,
high-resolution transmission electron microscopy, Raman, ultraviolet–visible,
and X-ray diffraction analys... hiện toàn bộ