Central European Journal of Physics

Thin films of copper selenide (CuSe) were physically deposited layer-by-layer up to 5 layers using thermal evaporation technique onto a glass substrate. Various film properties, including the thickness, structure, morphology, surface roughness, average grain size and electrical conductivity are studied and discussed. These properties are characterized by X-ray diffraction (XRD), atomic force microscopy (AFM), ellipsometer and 4 point probe at room temperature. The dependence of electrical conductivity, surface roughness, and average grain size on number of layers deposited is discussed.

The relationship between electronic spectral shifts and hydrogen-bonding dynamics in electronically excited states of the hydrogen-bonded complex is put forward. Hydrogen bond strengthening will induce a redshift of the corresponding electronic spectra, while hydrogen bond weakening will cause a blueshift. Time-dependent density function theory (TDDFT) was used to study the excitation energies in both singlet and triplet electronically excited states of Benzonitrile (BN), 4-aminobenzonitrile (ABN), and 4-dimethylaminobenzonitrile (DMABN) in methanol solvents. Only the intermolecular hydrogen bond C≡N...H-O was involved in our system. A fairly accurate forecast of the hydrogen bond changes in lowlying electronically excited states were presented in light of a very thorough consideration of their related electronic spectra. The deduction we used to depict the trend of the hydrogen bond changes in excited states could help others understand hydrogen-bonding dynamics more effectively.

In a certain sense a perfect fluid is a generalization of a point particle. This leads to the question as to what is the corresponding generalization for extended objects. Here the lagrangian formulation of a perfect fluid is much generalized by replacing the product of the co-moving vector which is a first fundamental form by higher dimensional first fundamental forms; this has as a particular example a fluid which is a classical generalization of a membrane; however there is as yet no indication of any relationship between their quantum theories.

One of most important issues in quantum information theory concerns transmission of information through noisy quantum channels. We discuss a few channel characteristics expressed by means of generalized entropies. Such characteristics can often be treated in line with more usual treatment based on the von Neumann entropies. For any channel, we show that the q-average output entropy of degree q ≥ 1 is bounded from above by the q-entropy of the input density matrix. The concavity properties of the (q, s)-entropy exchange are considered. Fano type quantum bounds on the (q, s)-entropy exchange are derived. We also give upper bounds on the map (q, s)-entropies in terms of the output entropy, corresponding to the completely mixed input.

A series of new red phosphors, MZr2(PO4)3:Eu3+; Bi3+ (M=Na; K), were synthesized using the solidstate reaction method, and their photoluminescence spectra were measured. The MZr2(PO4)3:Eu3+; Bi3+ (M=Na; K) phosphors were efficiently excited by an ultraviolet (UV; 395 nm) source, and showed intense orange-red emission at 595 nm. Further investigation of the concentration-dependent emission spectra indicated that the MZr2(PO4)3:Eu3+; Bi3+ (M=Na; K) phosphors exhibit the strongest luminescence intensity when y = 0.01 in NaZr2(0:95−y)(PO4)3:Eu 0.10 3+ , Bi 2 3+ and y = 0.09 in NaZr2(0.95−y)(PO4)3:Eu 0.10 3+ , Bi 2 3+ , whereas the relative PL intensity decreases with increasing Bi3+ concentration due to concentration quenching. The addition of Bi3+ widens the excitation band of NaZr2(0.95−y)(PO4)3:Eu 0.10 3+ , Bi 2 3+ around 320 nm, which provides the useful idea of broadening the excitation band around 300–350 nm to fit the ultraviolet chip.

In this study, we introduce a dual Hopf algebra in the sense of Sudbery for the quantum space(3) whose coordinates satisfy the commutation relations with two parameters and we show that the dual algebra is isomorphic to the quantum Lie algebra corresponding to the Cartan-Maurer right invariant differential forms on the quantum space(3). We also observe that the quantum Lie algebra generators are commutative as those of the undeformed Lie algebra and the deformation becomes apparent when one studies the Leibniz rules for the generators.

The effect of a nm-thick interlayer of copper phthalocyanine (CuPc) or perylene dye (MePTCDI) on currentvoltage characteristics of planar organic systems is discussed in this work. The MePTCDI layer in the ITO/MePTCDI/CuPc/Au system strongly reduces reverse dark current by blocking injection of holes from ITOinto CuPc leading to high values of rectification ratio. The CuPc interlayer in the ITO/CuPc/MePTCDI/Ag system causes a strong reduction in electron injection from ITOand reverses a forward polarity. Modification of current-voltage characteristics of illuminated systems with an interlayer of MePTCDI or CuPc is associated with a strong photovoltaic effect. This results from efficient excition dissociation at the CuPc/MePTCDI interface. Saturation current, determined by this process of charge carrier photogeneration, can be observed at particular voltage polarity.

The problem of determining the harmonic content in the voltage that appears on a superconducting wire carrying cosine-like AC current was resolved theoretically, using two approaches. First, the Fourier components of the voltage spectrum were found by numerical integration. Importance of individual terms was established, leading to two conclusions: a) it is the cosine component of the 3rd harmonic that represents the bulk of harmonic distortion, b) for the practical purposes it is sufficient to consider higher harmonics with n ≤ 7. Then, the analytical formulas were derived. While for the sine components a general expression containing an infinite series was found, closed-form formulas were derived for the cosine components of the harmonics 1, 3, 5, 7. Consequences of the results to the experimental technique used to study the AC transport properties of superconductors are discussed.

Fractional differential equations have attracted considerable interest because of their ability to model anomalous transport phenomena. Space fractional diffusion equations with a nonlinear reaction term have been presented and used to model many problems of practical interest. In this paper, a two-dimensional Riesz space fractional diffusion equation with a nonlinear reaction term (2D-RSFDE-NRT) is considered. A novel alternating direction implicit method for the 2D-RSFDE-NRT with homogeneous Dirichlet boundary conditions is proposed. The stability and convergence of the alternating direction implicit method are discussed. These numerical techniques are used for simulating a two-dimensional Riesz space fractional Fitzhugh-Nagumo model. Finally, a numerical example of a two-dimensional Riesz space fractional diffusion equation with an exact solution is given. The numerical results demonstrate the effectiveness of the methods. These methods and techniques can be extended in a straightforward method to three spatial dimensions, which will be the topic of our future research.

In this paper we study the excitation spectrum of the organic conductor tetrathiafulvalene-tetracyanoquinodimethane (TTF-TCNQ) using finite temperature calculations. The effect of electronelectron interaction is considered within the random phase approximation (RPA). Our results show the temperature dependent plasmon and dipolar mode corresponding qualitatively to the modes obtained previously using zero temperature formalism assigned to the observed excitations at 10 meV and 0.75 eV. These modes have an essential influence on the energy-loss function. The obtained results are in good qualitative agreement with the optical and EELS data of TTF-TCNQ.