The electrochemical hypochlorination of allyl chloride in dilute HCl solution

Journal of Applied Electrochemistry - Tập 12 - Trang 253-260 - 1982
Ch. Comninellis1, E. Plattner1
1Institut de génie chimique, Ecole Polytechnique Fédérale de Lausanne, Lausanne, Switzerland

Tóm tắt

The electrochemical hypochlorination of allyl chloride has been studied. It was found that the reaction is best effected using 1 to 1.5 N HCl as the electrolyte, introducing allyl chloride as an emulsion and working at low current density (< 150 mA cm−2).

Tài liệu tham khảo

J. Myszkowski and Z. Zielinski,Chimie et industrie 91 (1964) 654. Belgium Patent No 705.084, 1968. N. Ibl and A. Selvig,Chem. Ing. Tech. 42 (1970) 180. Ch. Comninellis and E. Plattner, unpublished work (1981).