The Photoreactivity of Chlorine Dioxide

American Association for the Advancement of Science (AAAS) - Tập 268 Số 5216 - Trang 1443-1448 - 1995
Veronica Vaida1, John D. Simon2
1Department of Chemistry and Biochemistry, University of Colorado, Boulder, CO 80309 USA
2Department of Chemistry and Biochemistry, University of California at San Diego, La Jolla, CA 92093-0341, USA.

Tóm tắt

Determining the detailed photoreactivity of radicals that are of importance in atmospheric processes requires information from both laboratory and field measurements and theoretical calculations. Laboratory experiments and quantum calculations have been used to develop a comprehensive understanding of the photoreactivity of chlorine dioxide (OCIO). The photoreactivity is strongly dependent on the medium (gas phase, liquid solution, or cryogenic matrix). These data reveal details of the complex chemistry of OCIO. The potential role of this radical in stratospheric ozone depletion is discussed in accord with these laboratory measurements.

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American Association for the Advancement of Science (AAAS)

Tập 268 Số 5216

1443-1448

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