The Effect of Methanol on the Micellar Properties of Dodecyltrimethylammonium Bromide (DTAB) in Aqueous Medium at Different Temperatures

Journal of Surfactants and Detergents - Tập 19 Số 1 - Trang 201-207 - 2016
Shah, Sujit Kumar1, Chatterjee, Sujeet Kumar1, Bhattarai, Ajaya1
1Department of Chemistry, M. M. A. M. C, Tribhuvan University, Biratnagar, Nepal

Tóm tắt

The micellar properties of dodecyltrimethylammonium bromide (DTAB) in water and methanol water mixtures at different temperatures have been studied by conductivity and surface tension measurements. The critical micelle concentrations (CMC), degree of ionization (α), standard Gibbs free energy of micellization ( $$ \Delta G_{\text{m}}^{\text{o}} $$ ), standard enthalpy of micellization ( $$ \Delta H_{\text{m}}^{\text{o}} $$ ), standard entropy of micellization ( $$ \Delta S_{\text{m}}^{\text{o}} $$ ) and free energy of transfer ( $$ \Delta G_{\text{trans}}^{\text{o}} $$ ) were evaluated from conductivity data. The CMC, maximum excess surface concentration ( $$ \varGamma_{ \hbox{max} } $$ ), area occupied per surfactant molecule ( $$ A_{ \hbox{min} } $$ ), surface pressure at the CMC ( $$ {\pi}_{\text{cmc}} $$ ), packing parameter (P) and standard free energy interfacial adsorption $$ (\Delta G_{\text{ads}}^{\text{o}} $$ ) were estimated from surface tension measurements. The CMC of DTAB was found to increase with increasing volume fraction of methanol and increasing temperature. Thermodynamic parameters and surface properties revealed that the addition of methanol changes the relevant physicochemical properties which affect the process of micellization.

Tài liệu tham khảo

citation_journal_title=J Coll Sci; citation_title=The critical micelle concentration of sodiumdodecyl sulfate in ethanol-water mixtures; citation_author=BD Flockhart; citation_volume=12; citation_publication_date=1957; citation_pages=557-565; citation_doi=10.1016/0095-8522(57)90061-2; citation_id=CR1

citation_title=The hydrophobic effect-formation of micelles and biological membranes; citation_publication_date=1980; citation_id=CR2; citation_author=C Tanford; citation_publisher=Wiley

citation_journal_title=Thermochemica Acta; citation_title=Aggregation behavior of quaternary salt based cationic surfactants; citation_author=J Mata, D Varade, P Bahadur; citation_volume=428; citation_publication_date=2005; citation_pages=147-155; citation_doi=10.1016/j.tca.2004.11.009; citation_id=CR3

citation_journal_title=J Mol Liq; citation_title=Mixed micellization of tetradecyltrimethylammonium bromide and Triton X-100 in water-ethanol mixtures, using potentiometric and surface tension techniques; citation_author=AA Rafati, H Maleki; citation_volume=135; citation_publication_date=2007; citation_pages=128-134; citation_doi=10.1016/j.molliq.2006.11.011; citation_id=CR4

citation_journal_title=J Chem Eng Data; citation_title=Isothermal compressibility and isobaric thermal expansivity of linear and branched hexanols at 298.15 K; citation_author=G Tardajos, E Junquera, E Aicart; citation_volume=39; citation_publication_date=1994; citation_pages=349-350; citation_doi=10.1021/je00014a034; citation_id=CR5

citation_journal_title=Colloid Polym Sci; citation_title=The counterion releasing effect and the partition coefficient of branched alkanols in ionic micellar solution; citation_author=M Manabe, A Tokunaga, H Kawamura, M Shiomi, K Hiramatsu; citation_volume=280; citation_publication_date=2002; citation_pages=929-935; citation_doi=10.1007/s00396-002-0710-3; citation_id=CR6

citation_journal_title=Adv Colloid Interface Sci; citation_title=Aqueous surfactant-alcohol systems: a review; citation_author=R Zana; citation_volume=57; citation_publication_date=1995; citation_pages=1-64; citation_doi=10.1016/0001-8686(95)00235-I; citation_id=CR7

citation_journal_title=J Polym Res; citation_title=The effects of concentration, relative permittivity and temperature on the transport properties of sodium polystyrenesulfonate in methanol-water mixed solvent media; citation_author=A Bhattarai, P Nandi, B Das; citation_volume=13; citation_publication_date=2006; citation_pages=475-482; citation_doi=10.1007/s10965-006-9070-x; citation_id=CR8

citation_journal_title=J Chem Eng Data; citation_title=Physicochemical studies on the micellization of cationic, anionic, and nonionic surfactants in water-polar organic solvent mixtures; citation_author=S Das, S Mondal, S Ghosh; citation_volume=58; citation_publication_date=2013; citation_pages=2586-2595; citation_doi=10.1021/je4004788; citation_id=CR9

citation_journal_title=J Am Chem Soc; citation_title=Calibration of conductance cells at 25 °C with aqueous Solutions of potassium chloride; citation_author=JE Lind, JJ Zwolenik, RM Fuoss; citation_volume=81; citation_publication_date=1959; citation_pages=1557-1559; citation_doi=10.1021/ja01516a010; citation_id=CR10

citation_journal_title=J Biochem Biophys Methods; citation_title=Survismeter type I and II for surface tension, viscosity measurements of liquids for academic, research and development studies; citation_author=M Singh; citation_volume=67; citation_publication_date=2006; citation_pages=151-161; citation_doi=10.1016/j.jbbm.2006.02.008; citation_id=CR11

citation_journal_title=J Chem Eng Data; citation_title=Influence of urea on shifting hydrophilic to hydrophobic interactions of Pr(NO3)3, Sm(NO3)3, and Gd(NO3)3 with BSA in aqueous citric acid: a volumetric, viscometric, and surface tension study; citation_author=D Kumar, A Chandra, M Singh; citation_volume=59; citation_publication_date=2014; citation_pages=3643-3651; citation_doi=10.1021/je5005388; citation_id=CR12

citation_journal_title=J Solution Chem; citation_title=Studies of micellization of cationic-anionic surfactant system in water and methanol-water mixed solvents; citation_author=A Bhattarai; citation_volume=44; citation_publication_date=2015; citation_pages=2090-2105; citation_doi=10.1007/s10953-015-0391-4; citation_id=CR13

citation_journal_title=J Chem Eng Data; citation_title=Excess properties of the binary liquid system propylene carbonate + acetonitrile; citation_author=GD Moumouzias, K Panopoulos, G Ritzoulis; citation_volume=36; citation_publication_date=1991; citation_pages=20-23; citation_doi=10.1021/je00001a006; citation_id=CR14

citation_journal_title=J Surface Sci Technol; citation_title=Conductrometric and surface tension studies on the micellization of some cationic surfactants in water-organic solvent mixed media; citation_author=H Naorem, SD Devi; citation_volume=22; citation_publication_date=2006; citation_pages=89-100; citation_id=CR15

citation_journal_title=J Surfact Deterg; citation_title=Physicochemical studies on the interfacial and micellization behavior of CTAB in aqueous polyethylene glycol media; citation_author=K Manna, AK Panda; citation_volume=14; citation_publication_date=2011; citation_pages=563-576; citation_doi=10.1007/s11743-011-1261-8; citation_id=CR16

citation_journal_title=J Colloid Interface Sci; citation_title=Ionization of cationic micelles: effect of the detergent structure; citation_author=R Zana; citation_volume=78; citation_publication_date=1980; citation_pages=330-337; citation_doi=10.1016/0021-9797(80)90571-8; citation_id=CR17

citation_journal_title=Chem Phys Lett; citation_title=Surfactant-alcohol mixed-micelle formation: cetyltrimethylammonium bromide-1 butanol system; citation_author=P Lianos, R Zana; citation_volume=72; citation_publication_date=1980; citation_pages=171-175; citation_doi=10.1016/0009-2614(80)80267-3; citation_id=CR18

citation_journal_title=J Colloid Interface Sci; citation_title=Effect of alcohol on the properties of micellar systems; citation_author=R Zana, S Yiv, C Strazielle, P Lianos; citation_volume=80; citation_publication_date=1981; citation_pages=208-223; citation_doi=10.1016/0021-9797(81)90177-6; citation_id=CR19

citation_journal_title=J Colloid Interface Sci; citation_title=Effect of head group size, temperature and counterion specificity on cationic micelles; citation_author=A Michele, L Brinch, P Profio, R Germani, G Savelli, G Onori; citation_volume=358; citation_publication_date=2011; citation_pages=160-166; citation_doi=10.1016/j.jcis.2010.12.028; citation_id=CR20

citation_journal_title=Colloid Surf B; citation_title=Self-association behavior of amitriptyline hydrochloride as a function of temperature and additive (inorganic salts and urea) concentration; citation_author=N Kabir-ud-Din, MA Rub, AZ Naqvi; citation_volume=82; citation_publication_date=2011; citation_pages=87-94; citation_doi=10.1016/j.colsurfb.2010.08.024; citation_id=CR21

citation_journal_title=Turk J Phys; citation_title=Excess properties of alcohol-water system at 298.15 K; citation_author=H Yilmaz; citation_volume=26; citation_publication_date=2002; citation_pages=243-246; citation_id=CR22

citation_journal_title=J Mol Liq; citation_title=Effects of glycol additives on the mixed micelle formation by hexadecyltrimethylammonium bromide + dodecylpyridinium chloride mixtures; citation_author=MS Bakshi, G Kaur; citation_volume=88; citation_publication_date=2000; citation_pages=15-32; citation_doi=10.1016/S0167-7322(00)00134-3; citation_id=CR23

citation_journal_title=J Surfact Deterg; citation_title=Hydrophobic hydration of cationic mixed micelles by alkoxyethanols in aqueous media; citation_author=MS Bakshi, H Doe; citation_volume=3; citation_publication_date=2000; citation_pages=497-504; citation_doi=10.1007/s11743-000-0149-5; citation_id=CR24

citation_journal_title=Colloids Surf A; citation_title=A model on the temperature dependence of critical micelle concentration; citation_author=H-U Kim, K-H Lim; citation_volume=235; citation_publication_date=2004; citation_pages=121-128; citation_doi=10.1016/j.colsurfa.2003.12.019; citation_id=CR25

citation_journal_title=Colloid Polym Sci; citation_title=Thermodynamics of micellization of tetradecyltrimethylammonium bromide in ethylene glycol-water binary mixtures; citation_author=CC Ruiz; citation_volume=277; citation_publication_date=1999; citation_pages=701-707; citation_doi=10.1007/s003960050443; citation_id=CR26

citation_journal_title=J Mol Liq; citation_title=Study of interaction between cationic surfactants and cresol red dye by electrical conductivity and spectroscopy methods; citation_author=A Ali, S Uzair, NA Malik, M Ali; citation_volume=196; citation_publication_date=2014; citation_pages=395-403; citation_doi=10.1016/j.molliq.2014.04.013; citation_id=CR27

citation_journal_title=Langmuir; citation_title=Theory of surfactant aggregation in water/ethylene glycol mixed solvents; citation_author=R Nagarajan, C-C Wang; citation_volume=16; citation_publication_date=2000; citation_pages=5242-5251; citation_doi=10.1021/la9910780; citation_id=CR28

citation_journal_title=Bull Korean Chem Soc; citation_title=Solubilization of alcohols in aqueous solution of cetylpyridinium chloride; citation_author=JJ Chung, SW Lee, YC Kim; citation_volume=13; citation_publication_date=1992; citation_pages=647-649; citation_id=CR29

citation_journal_title=Langmuir; citation_title=Thermodynamic study on surface adsorption and micelle formation of poly(ethylene-glycol) mono-n-tetradecyl ethers; citation_author=MN Islam, T Kato; citation_volume=19; citation_publication_date=2003; citation_pages=7201-7205; citation_doi=10.1021/la030112e; citation_id=CR30

citation_title=Surfactants and interfacial phenomenon; citation_publication_date=2004; citation_id=CR31; citation_author=MJ Rosen; citation_publisher=Wiley

citation_journal_title=J Colloid Interface Sci; citation_title=Tensiometric determination of Gibbs surface excess and micelle point: a critical revisit; citation_author=I Mukharjee, SP Moulik, K Rakshit; citation_volume=394; citation_publication_date=2013; citation_pages=329-336; citation_doi=10.1016/j.jcis.2012.12.004; citation_id=CR32

citation_journal_title=J Oleo Sci; citation_title=Adsorption and micelle formation of mixed surfactant systems in water II: a combination of cationic gemini-type surfactant with MEGA-10; citation_author=G Sugihara, A Miyazono, S Nagadome, T Oda, Y Hayasi, JS Ko; citation_volume=52; citation_publication_date=2003; citation_pages=449-461; citation_doi=10.5650/jos.52.449; citation_id=CR33

citation_journal_title=J Chem Soc, Faraday Trans; citation_title=Theory of self-assembly of hydrocarbon amphiphiles into micelles and bilayers; citation_author=JN Israelachivili, DJ Mitchell, BW Ninham; citation_volume=2; citation_issue=72; citation_publication_date=1976; citation_pages=1525-1568; citation_doi=10.1039/f29767201525; citation_id=CR34

citation_journal_title=Langmuir; citation_title=Amphiphile behavior in mixed solvent media I: self-aggregation and ion association of sodium dodecylsulfate in 1,4-dioxane-water and methanol-water media; citation_author=A Pan, B Naskar, GKS Prameela, KBVN Phani, AB Mandal, SC Bhattacharya, SP Moulik; citation_volume=28; citation_publication_date=2012; citation_pages=13830-13843; citation_doi=10.1021/la303281d; citation_id=CR35

Thông tin
Thông tin xuất bản

Journal of Surfactants and Detergents

Tập 19 Số 1

201-207

Thông tin tác giả