Syntheses of Novel Fe/S Clusters with μ‐Aminocarbyne Ligands

Zeitschrift fur Anorganische und Allgemeine Chemie - Tập 639 Số 10 - Trang 1791-1794 - 2013
Yao Shi1, Qiang Fu2
1College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225002, P. R. China, Fax: 86‐0514‐87857939
2College of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou, 225002, P.R. China

Tóm tắt

AbstractThe reaction of Fe3(CO)12 with (C3H5)2NCS2K in THF at room temperature afforded a red‐brown solution. Treatment of the thus‐obtained solution with MeI and PhCH2Br afforded clusters 1, (μ‐MeS)Fe2(CO)6(μ4‐S)Fe2(CO)6(μ‐CN(C3H5)2), and 2, (μ‐PhCH2CO)Fe2(CO)6(μ4‐S)Fe2(CO)6(μ‐CN(C3H5)2). Their structures were unambiguously determined by X‐ray crystallography. Therefore, this methodology provides a novel route for the syntheses of spiro‐S Fe/S clusters with aminocarbyne ligands.

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Zeitschrift fur Anorganische und Allgemeine Chemie

Tập 639 Số 10

1791-1794

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