Studies on Thermal Stability of Titanium Substituted Iron Molybdenum Spinel Oxide

Journal of Thermal Analysis - Tập 61 - Trang 839-847 - 2000
A. Roy1, J. Ghose1
1Department of Chemistry, Indian Institute of Technology, Kharagpur, India

Tóm tắt

The thermal stability of the solid solutions of Fe2Mo1–xTixO4 for x=0.0 to 1.0 in air, had been investigated in the temperature range 303–1173 K using differential thermal analysis and thermogravimetry (DTA and TG). The products obtained by heating the sample in air, at different temperatures, have been characterized by X-ray diffraction and IR-studies. The results show that all the ferrite samples undergo surface oxidation during initial heating. On heating to 823 K, the samples undergo oxidation of the octahedral site cations only and forma cation deficient spinel phase. On further heating in air, the ferrites undergo complete oxidation.

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