Salicylaldoxime: An old ligand with new faces
Tóm tắt
The paper is concerned with the interactions of salicylaldoxime with trivalent transition metal ions to yield di-, tri-, tetra- and hexanuclear complexes together with their low-lying electronic structures. Tri- and tetranuclear complexes are found to exhibit spin frustration. The importance of isostructural series of compounds with varyingd n electron configurations is indicated. Relevance of some of these compounds as models for metalloproteins is also shown.
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