Reaction of manganese peroxidase ofBjerkandera adusta with synthetic lignin in acetone solution

Springer Science and Business Media LLC - Tập 44 - Trang 486-490 - 1998
Shinichi Yoshida1, Akinobu Chatani1, Yoichi Honda1, Takashi Watanabe1, Masaaki Kuwahara1
1Wood Research Institute, Kyoto University, Uji, Japan

Tóm tắt

The reaction of manganese peroxidase (MnP) of the white-rot fungusBjerkandera adusta with synthetic lignin dehydrogenation polymer, DHP) in acetone medium was investigated. Gel-permeation chromatography of the DHP treated by MnP demonstrated depolymerization of syringyl DHP in the reaction mixture containing 70% acetone; moreover, concomitant repolymerization occurred to give highly polymerized products. Guaiacyl DHP was only repolymerized by MnP in the same acetone solution without giving degradation products. Addition of ascorbic acid to reaction mixtures containing acetone resulted in preferential depolymerization of syringyl DHP.

Tài liệu tham khảo

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