Preparation of colloidal silver nanoparticles by chemical reduction method

Korean Journal of Chemical Engineering - Tập 26 - Trang 153-155 - 2009
Ki Chang Song1, Sung Min Lee1, Tae Sun Park1, Bum Suk Lee2
1Department of Chemical and Biochemical Engineering, Konyang University, Chungnam, Korea
2Korea Institute of Energy Research, Daejeon, Korea

Tóm tắt

Colloidal silver nanoparticles were obtained by chemical reduction of silver nitrate in water with sodium borohydride (NaBH4) in the presence of sodium dodecyl sulfate (SDS) as a stabilizer. The obtained nanoparticles were characterized by their UV-vis absorption spectra and transmission electron micrograph (TEM) images. The UV-vis absorption spectra showed that NaBH4 served not only as a reducing agent but also as a stabilizer, which protects the aggregation of silver nanoparticles. The TEM images showed that the particles were dispersed better with increasing the NaBH4 concentration.

Tài liệu tham khảo

G. Carotenuto, G. P. Pepe and L. Nicolais, Eur. Phys. J. B, 16, 11 (2000). E. Stathatos and P. Lianos, Langmuir, 16, 2398 (2000). S.V. Kyriacou, W. J. Brownlow and X. N. Xu, Biochemistry, 43, 140 (2004). X. Feng, H. Ma, S. Huang, W. Pan, X. Zhang, F. Tian, C. Cao, Y. Cheng and J. Luo, J. Phys. Chem. B., 110, 12311 (2006). S. Choi, K. S. Kim, S. H. Yeon, J. H. Cha, H. Lee, C. J. Kim and I. D. Yoo, Korean J. Chem. Eng., 24, 856 (2007). M. Kawashita, S. Tsuneyama, F. Mijaji, T. Kokubo, H. Kozuka and K. Yamamoto, Biomaterials, 21, 393 (2000). J. R. Morones, J. L. Elechiguerra, A. Camacho, K. Holt, J. B. Kouri, J. T. Ramirez and M. J. Yacaman, Nanotechnology, 16, 2346 (2005). K. S. Chou, Y. C. Lu and H. H. Lee, Mater. Chem. Phys., 94, 429 (2005). W. C. Lin and M. C. Yang, Macromol. Rapid. Commun., 26, 1942 (2005). H. S. Shin, H. J. Yang, S. B. Kim and M. S. Lee, J. Colloid Interf. Sci., 274, 89 (2004). K. D. Kim, D. N. Han and H. T. Kim, Chem. Engin. J., 104, 55 (2004). S. Kapoor, Langmuir, 14, 1021 (1998). G. A. Ozin, Adv. Mater., 4, 612 (1992). B. G. Ershov and A. Henglein, J. Phys. Chem., 97, 3434 (1993). J. P. Chen and L. L. Lim, Chemosphere, 49, 363 (2002). D. L. V. Hyning and C. F. Zukoski, Langmuir, 14, 7034 (1998). J. Liu, J. B. Lee, D. H. Kim and Y. Kim, Colloids Surf. A, 302, 276 (2007).