On steel protection with volatile corrosion inhibitors in H2S-containing media

Protection of Metals - Tập 36 - Trang 474-478 - 2000
Yu. I. Kuznetsov1, R. K. Vagapov1
1Institute of Physical Chemistry, Russian Academy of Sciences, Moscow, Russia

Tóm tắt

The corrosion behavior of aCt3-type steel in hydrogen sulfide media, including those containing CO2, is studied. The inhibition effects of a volatile, water-soluble inhibitor (IPKhAN-72) and the starting aliphatic amine for its synthesis are compared. IPKhAN-72 is found to be more effective, especially in the presence of CO2. In CO2-free hydrogen sulfide media, IPKhAN-72 functions as an anodic inhibitor. In the presence of CO2, it also decelerates the cathodic process.

Tài liệu tham khảo

Bregman, J.I.,Corrosion Inhibitors, New York: Mac-Millan, 1963. Translated under the titleIngibitory korrozii, Leningrad: Khimiya, 1966. Corrosion Inhibitors, Nathan, C.C., Ed., Houston, Texas: NACE, 1973. Antropov, L.I. and Panasenko, V.F.,Itogi Nauki Tekhn., Ser.: Korroz. Zashch. Korroz., 1975, vol. 4, p. 43. Gonik, A.A.,Korroziya neftepromyslovogo oborudovaniya i mery ee preduprezhdeniya (Corrosion of Oil-Extracting Equipment and its Prevention.), Moscow: Nedra, 1976. Kichigin, V.I., Sherstobitova, I.N., and Kuznetsov, V.V.,Elektrokhimiya, 1976, vol. 12, no. 10, p. 1596. Rozenfel’d, I.L., Frolova, L.V., and Brusnikina, V.M.,Sov. Sci. Rev., Sect. B, 1986, vol. 8, p. 115. Bulgakova, R.A., Dorfman, A.M., Kuznetsov, Yu.I.,et al., Zashch. Met., 1996, vol. 32, no. 1, p. 48. Andreev, N.N., Andreeva, N.P., Vartapetyan, R.Sh.et al., Zashch. Met., 1997, vol. 33, no. 5, p. 521. Kuznetsov Yu.I.,CORROSION’98, San Diego, 1998, Houston: NACE, 1998, Paper no. 242 Kuznetsov Yu., I., Fundamentals and Practice of Volatile Corrosion Inhibitors, inOchrone przed korozia (Wydanie specijalne) XLII, 1999, Proceedings, Event of the European Federation of Corrosion, Czestohowa, Poland, 1999, pp. 425–433. Andreev, N.N. and Kuznetsov Yu.I.,CORROSION-98, San Diego, 1998, Houston: NACE, Paper no. 241. Kuznetsov, Yu.I., Andreev, N.N., and Ibatullin, K.A.,Zashch. Met., 1999, vol. 35, no. 6, p. 586. Andreev, N.N., Vagapov, R.K., Ibatullin, K.A.,et al., Vestn. Tambov. Univ., Ser.: Estest. Tekh. Nauki, 1999, vol. 4, no. 2, p. 143. Moiseeva, L.S. and Kuznetsov, Yu.I.,Zashch. Met., 1996, vol. 32, no. 6, p. 565.