New methods of generation of electrophilic iodine in neutral and weakly acidic media
Proceedings 6th Russian-Korean International Symposium on Science and Technology. KORUS-2002 (Cat. No.02EX565) - Trang 314-316
Tóm tắt
We have developed new methods to generation of electrophilic iodine on the base iodine chloride and different salts: ICl+MeX/spl rarr/I/sup +/X/sup -/+MeCl, Me=Ag/sup +/, Pb/sup +/, Na/sup +/; X=CF/sub 3/COO/sup -/, CH/sub 3/COO/sup -/. Iodinating ability of obtained reagents has been studied on aromatic (including polycyclic) and heterocyclic compounds.