New methods of generation of electrophilic iodine in neutral and weakly acidic media

E.A. Krasnokutskaja1, Y.A. Lesina1, V.D. Filimonov1, E.N. Diakonova1
1Department of Organic Chemistry, Tomsk Polytechnic University, Tomsk, Russia

Tóm tắt

We have developed new methods to generation of electrophilic iodine on the base iodine chloride and different salts: ICl+MeX/spl rarr/I/sup +/X/sup -/+MeCl, Me=Ag/sup +/, Pb/sup +/, Na/sup +/; X=CF/sub 3/COO/sup -/, CH/sub 3/COO/sup -/. Iodinating ability of obtained reagents has been studied on aromatic (including polycyclic) and heterocyclic compounds.

Từ khóa

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