Composite hydrogel hai mạng poly(acrylic acid/acrylamide) gắn bạc nano để phân hủy hiệu quả các phẩm màu hữu cơ

Springer Science and Business Media LLC - Tập 17 - Trang 893-905 - 2023
Fan Zhang1, Ce Gao1, Shang-Ru Zhai1, Qing-Da An1
1Liaoning Key Lab of Lignocellulose Chemistry and BioMaterials, Liaoning Collaborative Innovation Center for Lignocellulosic Biorefinery, College of Light Industry and Chemical Engineering, Dalian Polytechnic University, Dalian, China

Tóm tắt

Một composite hydrogel alginate/poly(acrylic acid/acrylamide) mạng kép mới với các hạt nano bạc đã được chế tạo thành công bằng phương pháp sol-gel. Sự hiện diện của nhóm carboxyl và amide trong cấu trúc mạng đã cung cấp nhiều vị trí hoạt động cho việc phức hợp các ion bạc, tạo điều kiện cho quá trình khử và giam giữ hạt nano bạc tại chỗ. Trong các thí nghiệm theo lô, mức nạp bạc tối ưu là 20%, và 5 mmol·L−1 p-nitrophenol đã bị phân hủy hoàn toàn trong vòng 113 giây với giá trị hằng số tốc độ là 4.057 × 10−2 s−1. Trong hệ thống nước máy và hệ thống nước biển giả lập, thời gian phân hủy p-nitrophenol ở cùng một nồng độ lần lượt là 261 và 276 giây, với tỷ lệ chuyển đổi trên 99%. Trong thí nghiệm giường cố định, tỷ lệ chuyển đổi vẫn giữ ở mức trên 74% sau 3 giờ với lưu lượng 7 mL·min−1. Sau 8 thử nghiệm tuần hoàn, tỷ lệ chuyển đổi vẫn duy trì ở 98.7%. Hơn nữa, xúc tác đã thể hiện hiệu suất xuất sắc trong thí nghiệm phân hủy bốn loại phẩm màu hữu cơ điển hình.

Từ khóa

#alginate #poly(acrylic acid/acrylamide) #hydrogel #bạc nano #phân hủy hữu cơ #chất xúc tác

Tài liệu tham khảo

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