Nano-sized transition-metal oxides as negative-electrode materials for lithium-ion batteries

Shodai, T., Okada, S., Tobishima, S. & Yamabi, J. Study of Li 3-xMxN (M = Co, Ni or Cu) system for use as anode in lithium rechargeable cells. Solid State Ionics 786, 86–88 (1996).

Takeda, Y. et al. Lithium secondary batteries using a lithium cobalt nitride, Li 2.6Co0.4N, as the anode. Solid State Ionics 130, 61–69 (2000).

Idota, Y., Kubota, T., Matsufuji, A., MaeKawa, Y. & Miyasaka, T. Tin-based amorphous oxide: A high-capacity lithium-ion storage material. Science 276, 1395–1397 (1997).

Kepler, K. D., Vaughey, J. T. & Thackeray, M. M. LixCu6Sn5 (0<x<13): An intermetallic insertion electrode for rechargeable lithium batteries. Electrochem. Solid State Lett. 7, 307– 309 (1999).

Mao, O., Dunlap, R. A. & Dahn, J. R. Mechanically alloyed Sn-Fe(-C) powders as anode materials for Li-ion batteries. I. The Sn2Fe-C system. J. Electrochem. Soc. 146, 405–413 ( 1999).

Idota, Y. et al. Nonaqueous secondary battery. US Patent No. 5,478,671 (1995).

Sigala, C., Guyomard, D., Piffard, Y. & Tournoux, M. Synthesis and performances of new negative electrode materials for ‘Rocking Chair’ lithium batteries. C.R. Acad. Sci. Paris II 320, 523–529 (1995).

Courtney, I. A., McKinnon, W. R. & Dahn, J. R. On the aggregation of tin in SnO composite glasses caused by the reversible reaction with lithium. J. Electrochem. Soc. 146, 59–68 ( 1999).

Denis, S., Baudrin, E., Touboul, M. & Tarascon, J.-M. Synthesis and electrochemical properties vs Li of amorphous vanadates of general formula RVO4 (R = In, Cr, Al, Fe, Y). J. Electrochem. Soc. 144, 4099–4109 (1997).

Guyomard, D. & Tarascon, J.-M. Rechargeable Li1+xMn 2O4/carbon cells with a new electrolyte composition. Potentiostatic studies and application to practical cells. J. Electrochem. Soc. 140, 3071–3081 ( 1993).

Gozdz, A. S., Tarascon, J.-M. & Schmutz, C. N. Rechargeable lithium interaction battery with flexible electrolyte. US Patent No. 5,296,318 (1994).

Amatucci, G. G., Tarascon, J.-M. & Klein, L. C. CoO2, the end member of the LixCoO 2 solid solution. J. Electrochem. Soc. 143 , 1114–1123 (1996).

Figlarz, M., Fievet, F. & Lagier, J.-P. Reduction process of metal-based inorganic precursors in liquid polyols to produce monodisperse metal particles. French patent No. 8,221,483 (1985).

Buffat, P. & Borel, J. P. Size effect on the melting temperature of gold particles. Phys. Rev. A 13, 2287 –2292 (1976).