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Phân tích quang phổ phân tử của kính matrix phosphat natri đồng kẽm được doping oxit coban
Tóm tắt
Một hệ thống kính gồm 40P2O5–(21−x) Na2O–38ZnO–x Co3O4–1CuO, trong đó (x = 1, 2, 3, 4 và 5), đã được chuẩn bị bằng kỹ thuật làm nguội nóng chảy. Mật độ của các loại kính đã được đo và thể tích mol được tính toán. Cấu trúc đã được nghiên cứu bằng phương pháp quang phổ hồng ngoại (IR). Phân tích quang phổ cho thấy sự bổ sung Co3O4 vào kính P2O5 có ảnh hưởng rõ ràng đến trật tự ngắn hạn của ma trận kính. Các phổ cũng chỉ ra sự hình thành các liên kết P–O–Co trong các loại kính thay thế cho các liên kết P–O−–Na+. Các kết quả này liên quan đến vai trò kép của ion coban như một thành phần tạo kính và điều chỉnh.
Từ khóa
#kính phốt phát #oxit coban #kính matrix #quang phổ hồng ngoại #trật tự ngắn hạnTài liệu tham khảo
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