Mechanism of catalysis and factors responsible for oxide catalyst activity in deep oxidation reactions

V. D. Sokolovskii1
1Institute of Catalysis, Novosibirsk, USSR

Tóm tắt

A general scheme for the deep oxidation mechanism on oxide catalysts including stepwise and concerted mechanisms as well as their mutual transformations is suggested. The principal factor responsible for the activity in the concerted mechanism region is the rate of oxygen binding. For the stepwise mechanism the main factor is the rate of catalyst interaction with oxidizable reactant.

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Tài liệu tham khảo

G. K. Boreskov: Heterogeneous Catalysis, Nauka, Moskva 1986.

G. I. Golodets: Heterogeneous Catalytic Reactions. Naukova Dumka, Kiev 1977.

V. V. Popovskii: Kinet. Katal.,13, 1190 (1972).

G. K. Boreskov, V. D. Sokolovskii: Izv. Akad. Nauk SSSR, ser. khim.,4, 46 (1976).

A. G. Anshits, V. D. Sokolovskii, G. K. Boreskov, A. A. Davydov: Dokl. Akad. Nauk SSSR,213, 607 (1973).

G. K. Boreskov, V. I. Marshneva, V. D. Sokolovskii: Dokl. Akad. Nauk SSSR,199, 1091 (1971).

V. D. Sokolovskii: React. Kinet. Catal. Lett.,35, 337 (1987).

V. I. Marshneva, G. K. Boreskov, V. D. Sokolovskii: Proc. 1st Soviet-Japanese Seminar on Catalysis, Preprint No 25, Inst. Katal., Novosibirsk 1971.