MEASUREMENT OF THE APPARENT DISSOCIATION CONSTANTS OF CARBONIC ACID IN SEAWATER AT ATMOSPHERIC PRESSURE1

Limnology and Oceanography - Tập 18 Số 6 - Trang 897-907 - 1973
C. Mehrbach1, Charles H. Culberson1, J. E. Hawley1, Ricardo M. Pytkowicx1
1School of Oceanography, Oregon State University, Corvallis 97331.

Tóm tắt

The apparent dissociation constants of carbonic acid in seawater were determined as functions of temperature (2–35°C) and salinity (19–43‰) at atmospheric pressure by measurement of K’x and the product K'� K'2. At 35%° salinity and 25°C the measured values were pK′1 = 6.000 and pK′2 = 9.115; at 35‰ and 2°C the measured values were pK′1 = 6.177 and pK′2 = 9.431.

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Limnology and Oceanography

Tập 18 Số 6

897-907

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