Kinetics of cutinase catalyzed transesterification in AOT reversed micelles: modeling of a batch stirred tank reactor

Bru, 1989, A theoretical study on the expression of enzymic activity in reverse micelles, Biochem. J., 259, 355, 10.1042/bj2590355 Carvalho, C.M.L., 1999. Optimization of a Reversed Micellular System with micron capsilated cutinase: stabilization, kinetics and operation in reactors. PhD Thesis, Instituto Superior Técnico, Lisboa. Carvalho, 1997, Application of factorial design to the study of transesterification reactions using cutinase in AOT reversed micelles, Enzyme Microb. Technol., 21, 117, 10.1016/S0141-0229(96)00245-1 Carvalho, 1999, Cutinase stability in AOT reversed micelles: system optimization using the factorial design methodology, Enzyme Microb. Technol., 24, 569, 10.1016/S0141-0229(98)00163-X Carvalho, 1999, Cutinase: from molecular level to bioprocess development, Biotechnol. Bioeng., 66, 17, 10.1002/(SICI)1097-0290(1999)66:1<17::AID-BIT2>3.0.CO;2-F Carvalho, C.M.L., Aires-Barros, M.R., Cabral, J.M.S., 2000. An integrated model for enzymatic reactions in reversed micellar system: nominal and effective substrate concentrations Langmuir 16, 3082–3092. Cornish-Bowden, 1981 Crooks, 1995, Comparison of hydrolysis and esterfication behavior of Humicola lanuginosa and Rhizomucor miehei lipases in AOT-stabilized water-in-oil microemulsions: I. effect of pH and water content on reaction kinetics, Biotechnol. Bioeng., 48, 78, 10.1002/bit.260480111 Fletcher, 1984, Reactivity of α-chymotrypsin in water-in-oil microemulsions, Coll. Surf., 10, 193, 10.1016/0166-6622(84)80020-7 Fletcher, 1985, Kinetic properties of α-chymotrypsin in water-in-oil microemulsions: studies with a variety of substrates and microemulsion systems, Biochim. Biophys. Acta, 832, 204, 10.1016/0167-4838(85)90333-4 Gupte, 1995, Enzymatic oxidation in reversed micelles, Ind. Eng. Chem. Res., 34, 2910, 10.1021/ie00047a045 Janssen, 1999, Kinetics of lipase-catalysed esterification in organic media: correct model and solvents effects on parameters, Enzyme Microb. Technol., 24, 463, 10.1016/S0141-0229(98)00134-3 Kabanov, A.V., Levashov, A.V., Klyachko N.L., Namyotkin, S.N., Pshezhetsky, A.V., 1988. Enzymes entrapped in reversed micelles of surfactants in organic solvents: a theoretical treatment of the catalytic activity regulation. J. Theor. Biol. 133, 327–343. Khmel’nitskii, 1984, A microheterogeneous medium for chemical (enzymic) reactions based on a colloidal solution of water in an organic solvent, Russ. Chem. Rev., 53, 319, 10.1070/RC1984v053n04ABEH003052 Khmelnitsky, 1990, Kinetic theory of enzymatic reactions in reversed micellar systems: application of pseudophase approach for partitioning substrates, Eur. J. Biochem., 190, 155, 10.1111/j.1432-1033.1990.tb15559.x Lauwereys, 1991, Cloning, expression and characterization of cutinase, a fungal lipolytic enzyme, 243 Marangoni, 1995, Engineering triacylglycerols: the role of interesterification, Trends Food Sci. Technol., 6, 329, 10.1016/S0924-2244(00)89167-0 Martinez, 1994, Cutinase, a lipolytic enzyme with a preformed oxyanion hole, Biochemistry, 33, 83, 10.1021/bi00167a011 Page, 1990, Enzyme catalysis, 45 Pinto-Sousa, 1996, Stability of a Fusarium solani pisi recombinant cutinase in phosphatidylcholine reversed micelles, Biotechnol. Lett., 18, 583, 10.1007/BF00140207 Papadimitriou, 1996, EPR studies of cutinase in microemulsions, Ann. NY Acad. Sci., 799, 275, 10.1111/j.1749-6632.1996.tb33213.x Sebastião, 1993, Synthesis of fatty acid esters by a recombinant cutinase in reversed micelles, Biotechnol. Bioeng., 42, 326, 10.1002/bit.260420309 Shield, 1986, Enzymes in reversed micelles as catalysts for organic-phase synthesis reactions, Ind. Eng. Chem. Fundam., 25, 603, 10.1021/i100024a022 Tsai, 1995, Surfactant effects on lipase-catalysed hydrolysis of olive oil in AOT/isooctane reverse micelles, Biocat. Biotrans., 13, 89, 10.3109/10242429509015215 Verhaert, 1990, Description of enzyme kinetics in reversed micelles, Theory. Eur. J. Biochem., 187, 59, 10.1111/j.1432-1033.1990.tb15277.x Yang, 1995, A comparison of lipase-catalysed ester hydrolysis in reverse micelles, organic solvents, and biphasic systems, Biotechol. Bioeng., 47, 60, 10.1002/bit.260470108