Kinetics and mechanisms of the low-temperature degradation of cellulose

Springer Science and Business Media LLC - Tập 1 Số 1 - Trang 26-56 - 1994
Alan Emsley1, G.C. Stevens2
1Department of Chemistry, University of Surrey, GU2 5XH, Guildford, Surrey
2Research & Engineering, National Power plc, Whitehall Way, SN5 6PB, Windmill Hill Business Park, Swinden

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Agrawal, R. K. (1985) Compensation effect in the pyrolysis of cellulose.Thermochim. Acta. 90, 347.

Anet, E. F. L. J. (1961) Degradation of carbohydrates.Aust. J. Chem. 14, 295.

Idem (1964)ibid 19, 181.

Blazej, A. and Kosik, M. (1985) Degradation reactions of cellulose and lignocellulose. InCellulose and its Derivatives (Kennedy, J. F., ed.). Chichester: Ellis Horwood.

Bouvier, B. (1970) Criteria for characterising the degradation of paper insulation.Rev. General Electrique 79(6), 489?496.

Broido, A. and Weinstein, M. (1971) Low temperature isothermal pyrolysis of cellulose.Proc. 3rd Int. Conf. on Thermal Analysis 3, 285?296.

Burgess, H. D. (1986) GPC-Use in estimating the effect of water washing on the long term stability of cellulsic fibre.Adv. Chem. Ser. 212, 363?376.

Burton, P. J., Carballiera, M., Duval, M., Fuller, C. W., Graham, J., de Pablo, A., Samat, J. and Spicar, E. (1988) Application of liquid chromatography to the analysis of electrical insulating materials.Proc. CIGRE Conf., Paris, Paper 15-08.

Butsena, A. Ya. and Kulkevits, A. Ya. (1986) Obtaining cellulose by the rapid thermolysis method: 2. Macrokinetics of the process of obtaining glucose from Xylose.Khimia Drevesiny 1, 69?72.

Byrne, G. A., Gardiner, D. and Holmes, F. H. (1966) Pyrolysis of cellulose and the action of flame retardants: further identification of products.J. Appl. Chem. 16, 81.

Calahorra, M. E., Cortazar, M., Eguiazabal, J. I. and Guzman, G. M. (1989) Thermogravimetric analysis of cellulose: Effect of molecular weight on thermal decomposition.J. Appl. Polymer Sci. 37, 3305?3314.

Chang, M. (1971) Folding chain model and annealing of cellulose.J. Polymer Sci. C 7(36), 343.

Chang, M. Y. (1974) Crystallite structure of cellulose.J. Polymer Sci. 12, 1349.

Chornet, E. and Roy, C. (1980) Compensation effect in the thermal decomposition of cellulosic material.Thermochim. Acta. 35(3), 389?393.

Conley, R. T. (1970) Thermal and thermo-oxidative degradation of cellulosic polymers.Monographs in Macromolecular Chemistry, Thermal Stabilization of Polymers 1, 523.

Cosgrove, J. D., Head, B. C., Lewis, T. J., Graham, S. G. and Warwicker, J. O., A GPC study of cellulose degradation. InCellulose and its Derivatives (Kennedy, J. F. ed.). Chichester: Ellis Horwood, pp. 143?151.

Darveniza, M., Saha, T. K., Hill, D. J. T. and Le, T. T., Assessment of insulation in aged power transformers by interfacial polarization spectra and correlation with chemical properties.Proc. 6th Int. DMMA Conf., Manchester, 1992, pp. 233?236.

David, P. K. (1987) Correlation of Arrhenius parameters: the electrochemical ageing compensation effect,IEEE Trans. Elec. Insul. E2?22(3), 229.

Ekamstam, A. (1936) The behaviour of cellulose in mineral acid solutions: Kinetics study of the decomposition of cellulose in acid solution.Ber. 69, 553.

Elema, R. J. (1973) A model for the degradation of cotton cellulose.J. Polymer Sci. Symp. 42, 1545.

Emsley, A. M. and Stevens, G. C. (1994) A review of chemical indicators of degradation of cellulosic electrical paper insulation in oil-filled transformers. IEE J. To be published.

Erofeev, B. V., Shishko, A. M., Volkovich, S. M., Pesnyakevich, L. G. and Matskevich, D. V. (1982) Reactivity of the amorphous regions of cellulose.Reports of the Academy of Sciences of the Byelorussian SSR, (Vestsi Akd. Navuk Ussr, Ser, Khim, Navuk 1, 12?16.

Fabre, J. and Pichon, A. (1960) Deteriorating processes and products of paper in oil,CIGRE Conference Paper 137.

Fallou, B. (1970) Synthesis of work carried out at LCIE on paper degradation.Rev. General Electrique 79, 645.

Feller, R. L., Lee, S. B. and Bogaard, J. Kinetics of cellulose deterioration.J. Adv. Chem. Ser. 212, 329.

Freedman A. N., Gaseous degradation products from the degradation of insulation materials used in electrical generators (1978)J. Chromatography 157(1), 85?96.

Freudenberg, K., Kuhn, W., Durr, W., Bolz, F. and Steinbrunn, G. (1930) Hydrolysis of polysaccharides.Ber. 63, 1510.

Fukuchi, H., Tsukai, S., Okada, K. and Tanimoto, T. (1977) Thermal degradation products of a glucose solution,Hiroshima J. Anesthesia 13(1), 3.

Fung, D. P. C. (1969) Kinetics and mechanisms of thermal degradation of cellulose in vacuo.TAPPI 52, 319.

Gibbons, J. A. M. and Schroff, D. H. (1988), private communication.

Glassner, S. and Pierce, A. R. (1965) Gas Chromatographic analysis of products from the controlled application of heat to cellulose and laevoglucosan.Anal. Chem. 37, 525.

Golova, O. P. and Krylova, R. G. (1957) Thermal decomposition of cellulose and its structure.Dokl. Akad. Nauk SSSR 116, 419.

Golova, O. P., Pakhomov, A. M., Andrievskaya, E. A. and Kryova, R. G. (1957) On the mechanisms of thermal decomposition of cellulose under vacuum and the formation of laevoglucosan.ibid 115, 809.

Hanna, A. A., Abd-el-Wahid, A. and Abbass, M. H. (1984) Thermal degradation of some celluloic materials.Cellulose Chem. Tech. 18, 11?20.

Hatakeyama, T., Ikeda, Y. and Hatakeyama, H. (1987) Structural change in the amorphous region of cellulose in the absence of water. InWood and Cellulosics (Kennedy, J. F. ed.). Ellis Horwood, Chichester, pp. 23?30.

Hernadi, S. (1976) Thermal ageing in oxygen of paper made from cellulose at different degrees of beating.Svensk Papperstidning 79(13), 418?423.

Hino, T. and Suganuma, T. (1972) Rapid measurement of deterioration of oil immersed paper.IEEE Trans. Elec. Insul. 7(3), 122?126.

Idem (1967) A mass spectroscopic/gas Chromatographic study of thermal degradation of electrical insulating papers in oil.Shinku Kagaku 15(2), 49?55.

Houminer, Y. and Patai, S. (1969) Pyrolytic reaction of carbohydrates: 2. Thermal decomposition of D-glucose.Israel. Chem. 7(4), 513.

Irklei, V. M., Reznik, K. Ya., Starunskay, T. P. and Krymov, A. V. (1982) Kinetics of degradation of alkali cellulose.Khimistry Volokna 3, 26?27.

Jackson, J. P., Arthurs, E., Schwalbe, L. A., Sega, R. M., Windisch, D. E., Long, W. H. and Stappaerts, E. A. (1988) Infrared laser heating for studies of cellulose degradation.Applied Optics 27(18), 3937.

Idem (1988) A new tool for cellulose degradation studies.Mat. Res. Soc. Symp. Proc. 123, 311?316.

Kato, K. and Komorita, H., Pyrolysis of cellulose 5: Isolation and identification of 3-deoxyglycosones from cellulose, glucose and xylose by heating (1968)Agricultural and Biol. Chem. 32(2), 715.

Kilzer, F. J. (1971) Thermal degradation of cellulose. InHigh polymers (Bikales, N. M. and Segal, L. eds.).5, Pt5, p. 1015.

Kilzer, F. J. and, Broido, A. (1965) Speculations on the nature of cellulose pyrolysis.Pyrodynamics 2, 151.

Kosik, M., Surina, I. and Blazej, A. (1983) Thermolytic reactions of cellulose.Chemia Listy 77, 178.

Krassig, H. (1985) Structure of cellulose and its relation to the properties of cellulose fibres. InCellulose and its Derivatives (Kennedy, J. F. ed.). Chichester: Ellis Horwood, pp. 3?26.

Kuhn, W. (1930) On the kinetics of reduction of high molecular weight chains.Ber. 63, p. 1503.

Lawther, J. M., White, C. A., Rivera, Z. S. and Jumel, K. (1990) Molecular weight determination of cellulose using high performance SEC, GPC and viscometry. Cellucon89.

Le Guennec, P. (1990), private communication.

Lewellen, P. C., Peters, W. A. and Howard, J. B. (1977) Cellulose combustion kinetics and char formatio mechanisms.Proc. Symp. Int. Combustion Conf. 16, 1471?1480.

Maciejewski, Z., Krol, P. and Rutkowska, E. (1981) Study of furfural formation from pentosans.Przemysl Chemiczny 60(4), 203?206.

MacKay, G. D. M., Mechanism of degradation of cellulose (1967)Canadian Department of Forestry publication, No. 1201.

Madorsky, S. L., Hart, V. E. and Strauss, S. (1956) Pyrolysis of cellulose.J. Res. NBS 56, 343.

Major, W. D. (1958) Degradation of cellulose in oxygen and nitrogen at high temperatures.TAPPI 41, 530.

Manley, R. (1963) Growth and morphology of single crystals of cellulose tri-acetate.J. Polymer Sci. Part A 1, 1875?1892.

Marx-Figini, M. and Coun-Matus, M. (1981) On the kinetics of hydrolytic degradation of native cellulose.Makromolecular Chem. 182, 3603.

Michie, R. I. C., Sharpies, A. and Walter, A. A. (1961) The nature of acid-sensitive linkages in cellulose.J. Polymer Sci. 51, 85.

Miyoshi, A. (1975) A new additive for improving the thermal ageing characteristics of insulating paper.IEEE Trans. Elec. Insul. E1?10(1), 13.

Montanari, G. C. (1990) A new thermal life model derived by the ageing compensation effect.ibid 25(2), 309.

Moser, H. P. and Dahinden, V. (1988)Transformerboard 2. H. Weidmann, AG, CH-8640 Rappers vil.

Moye, C. J. (1964) 5-hydroxy-methyl-furfural.Rev. Pure Appl. Chem. 14, 161.

Murphy, E. J. (1962) Thermal decomposition of natural cellulose in vacuo.J. Polymer Sci. 58, 649?665.

Nevell, T. P. (1985) Degradation of cellulose by acids, alkalis and mechanical means. InCellulose Chem and its Applications (Nevell, T. P. ed.). Ellis Horwood, pp. 225?241.

Noller, C. R. (1965),Chemistry of Organic Compounds. Philadelphia and London: W. B. Saunders.

Okamura, K. (1989) The structure of cellulose.J. Japanese Wood Res. Soc..35(7), 589?594.

Pacault, A. and Sauret, G. (1958) Study of thermal depolymerisation of cellulose.Compt. Rendue Acadamie des Sciences 246, 608.

Paloniemi, P. (1972) Isothermal differential calorimetry as a means of measuring insulation ageing down to operating temperatures.IEEE Trans. Elec. Insul. E1?7(3), 126.

Pavlath, A. E. and Gregorski, K. S. (1988) Carbohydrate pyrolysis: Formation of furfural and furfuryl alcohol during pyrolysis of hydrocarbons with acidic and basic catalysts.Conference on Research on Thermochemical Biomass Conversion, 1988, pp. 155?163.

Ranby, B. G. (1961) Weak links in polysaccharide chains related to modified groups.J. Polymer Sci. 53, 131.

Rogers, F. E. and Ohlemiller, F. (1980) Cellulosic insulation material: 1. Overall degradation kinetics and reaction heats.Combustion Sci. Tech..24(3/4), 129?137.

Rowland, S. P. and Roberts, E. J. (1972) The nature of accessible surfaces in the microstructure of native cellulose.J. Polymer Sci. A 10, 2447?2461.

Roze, I. M., Vedernikov, N. A., Alekhina, T. V. and Popov, S. S. (1988) Hydrolytic degradation of Birchwood polysaccharides.Khimia Drevesiny 2, 76?80.

Saad, S. M. and El-Khloy, A. E. (1980) Kinetic investigation of thermal ageing of unbleached Egyptian Kraft bagasse paper: Part 2 Effect of ageing on chemical and mechanical properties.Holzforschung 34(4), 147?149.

Saad, S. M., El-Anwar, I. M. and Metwally, N. E. (1979) Evaluation of unbleached Egyptian Kraft bagasse paper pulp.Holzforschung 33, 125.

Sarko, A. (1987) Cellulose ? How much do we know about its structure? InWood and Cellulosics (Kennedy, J. F. ed.) Ellis Horwood, pp. 55?70.

Schroff, D. H. and Stannett, A. W. (1985) Review of paper ageing in power transformers.IEE Proc. C., G.B.,132(6), 312?319.

Schultz, G. V. (1948) Kinetics of cellulose degradation and periodic structure of cellulose molecules.J. Polymer Sci. 3, 365.

Schwenker, R. F. and Beck, L. R. (1963) Study of the pyrolytic degradation of cellulose by gas chromatography.J. Polymer Sci. C 2, 331?340.

Shafizadeh, F. (1985) Thermal degradation of cellulose. InCellulose Chemistry and its Applications (Nevell, T. P. ed.). Ellis Horwood, pp. 266?289.

Shafizadei, F. and Bradbury, A. G. W. (1979) Thermal degradation of cellulose in air and nitrogen at low temperatures.J. Appl. Polymer Sci. 23, 1431.

Shafizadeh, F. and Lai, Y. Z. (1972) Thermal degradation of 1,6-anhydro-?-d-glucopyranose.J. Organic Chem. 37(2), 278.

Shafizadeh, F., Philpot, C. W. and Ostonjic, N. (1971) Thermal analysis of 1,6-anhydro-?-d-glucopyranose.Carbohydrate Res. 16, 279?287.

Shafizadeh, F., Furneaux, R. H., Cochran, T. G., Scholl, J. P. and Yoshio, S. (1979) Production of laevoglucosan and glucose from pyrolysis of cellullosic materials.J. Appl. Polymer Sci. 23(12), 3525?3539.

Shinouda, H. G. (1976) Kinetic study of the heterogeneous hyfrolysis of cellulose fibres.Cellulose Chem. Tech. 10, 479.

Shivadev, U. K. and Emmons, H. W. (1974) Thermal degradation and spontaneous ignition of paper sheets in air by irradiation.Combustion and Flame 22, 223.

Simon, I., Scheraga, H. A. and Manley, J. St. J. (1988a) Structure of cellulose 1: Low energy conformations of single chains.Macromolecules 21, 983?990.

Idem (1988b) Structure of cellulose 2: Low energy crystalline arrangements,ibid, 990?999.

Stamm, A. J. (1956) Thermal degradation of wood and cellulose.Ind. Eng. Chem. 48, 413.

Sugiyama, J., Harada, H. and Saiki, H. (1987) Crystalline structure of Valonis Macrophysa cellulose III, revealed by direct lattice imaging,Int. J. Biol. Macromolecules 9, 122.

Sugiyama, J., Persson, J. and Chanzy, H. (1991) Combined IR and electron diffraction study of the polymorphism of native cellulose.Macromolecules 24, 2461?2466.

Tamura, R., Anetai, H., Ishii, T. and Kawawmura, T. (1981) Diagnosis of ageing deterioration of insulating paper.IEE J. 101-A, 30?36.

Unsworth, J. and Mitchell, F. (1990) Degradation of electrical insulating material monitored with high performance chromatography.IEEE Trans., Elec. Insul. 25(4), 737.

Vergne, J., Chen, B., Grob, R., le Guennec, P., Rouvier, M. and Rigal, L. (1991), private communication.

Yoshida, H., Ishioka, Y., Suzuki, T., Yanari, T. and Teranishi, T. (1987) Degradation of insulating materials of transformers.IEEE Trans. Elec. Insul. E1?22(6), 795.

Zhilyaev, T. B., Linova, L. S., Granovskaya, V. N. and Golovan, N. I. (1983) Investigation of cellulosic electrical insulation materials.Electrotechnika (USSR)54(10), 74?77.