Kinetic studies of thermoset cure reactions: A review

Polymer Composites - Tập 18 Số 2 - Trang 157-168 - 1997
Azizeh‐Mitra Yousefi1, Pierre G. Lafleur1, R. Gauvin2
1Center for Applied Polymer Research, CRASP, Ecole Polytechnique, Chemical Engineering Department, Montreal, Quebec, Canada
2Center for Applied Polymer Research, CRASP, Ecole Polytechnique, Mechanical Engineering Department, Montreal, Quebec, Canada

Tóm tắt

AbstractThis article presents a review of the kinetic studies on the cure reactions of thermosetting resins. The emphasis is placed on those conducted using the thermal analysis by differential scanning calorimetry. Two important categories of kinetic models are discussed and some existing parameter estimation techniques are presented. A variety of factors affecting the cure reactions, including the formulation of cure and process variables, are discussed. At the end, two different approaches in modeling the chemoviscosity of polymeric reactive systems are presented and some existing chemorheological models developed based on these approaches are briefly reviewed.

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