High-efficiency GaInP∕GaAs∕InGaAs triple-junction solar cells grown inverted with a metamorphic bottom junction

Applied Physics Letters - Tập 91 Số 2 - 2007
John F. Geisz1, Sarah Kurtz1, M. W. Wanlass1, Jas S. Ward1, A. Duda1, Daniel J. Friedman1, J. M. Olson1, William E. McMahon1, T. Moriarty1, J. Kiehl1
1National Renewable Energy Laboratory, Golden, Colorado 80401

Tóm tắt

The authors demonstrate a thin, Ge-free III–V semiconductor triple-junction solar cell device structure that achieved 33.8%, 30.6%, and 38.9% efficiencies under the standard 1sun global spectrum, space spectrum, and concentrated direct spectrum at 81suns, respectively. The device consists of 1.8eV Ga0.5In0.5P, 1.4eV GaAs, and 1.0eV In0.3Ga0.7As p-n junctions grown monolithically in an inverted configuration on GaAs substrates by organometallic vapor phase epitaxy. The lattice-mismatched In0.3Ga0.7As junction was grown last on a graded GaxIn1−xP buffer. The substrate was removed after the structure was mounted to a structural “handle.” The current-matched, series-connected junctions produced a total open-circuit voltage over 2.95V at 1sun.

Từ khóa


Tài liệu tham khảo

2006, Proceedings of the Fourth World Conference on Photovoltaic Energy Conversion, Hawaii, 760

1990, Appl. Phys. Lett., 56, 623, 10.1063/1.102717

1997, Proceedings of the 26th IEEE Photovoltaic Specialists Conference, Anaheim, 875

2005, Appl. Phys. Lett., 86, 113506, 10.1063/1.1884267

1996, J. Cryst. Growth, 169, 649, 10.1016/S0022-0248(96)00665-3

2004, J. Electron. Mater., 33, 185, 10.1007/s11664-004-0178-7

2005, Proceedings of the 31st IEEE Photovoltaic Specialists Conference, Orlando, Florida, 530

2006, Proceedings of the Fourth World Conference on Photovoltaic Energy Conversion, Hawaii, 729

1996, Proceedings of the 25th IEEE Photovoltaic Specialists Conference, Washington, DC, 37

2004, J. Vac. Sci. Technol. B, 22, 1539, 10.1116/1.1669622

1998, J. Appl. Phys., 83, 5137, 10.1063/1.367331

2000, Appl. Phys. Lett., 76, 2131, 10.1063/1.126276

2000, Proceedings of the 28th IEEE Photovoltaic Specialists Conference, Anchorage, Alaska, 1126

2002, Proceedings of the 29th Photovoltaics Specialists Conference, 840

1994, Proceedings of the First World Conference on Photovoltaic Energy Conversion, Waikoloa, Hawaii, 1733

2003, Proceedings of the Third World Conference on Photovoltaic Energy Conversion, 745

2007, Prog. Photovoltaics, 15, 35, 10.1002/pip.741

2006, Proceedings of the Fourth World Conference on Photovoltaic Energy Conversion, Hawaii, 1757

2007, Appl. Phys. Lett., 90, 183516, 10.1063/1.2734507