Phương pháp nhạy cao để xác định Bisphenol A độc hại trong bao bì thực phẩm / đồ uống và giấy nhiệt sử dụng điện cực carbon thủy tinh được chỉnh sửa bằng hạt nano carbon đen

Food Analytical Methods - Tập 10 - Trang 3825-3835 - 2017
Martyna Ławrywianiec1, Joanna Smajdor1, Beata Paczosa-Bator1, Robert Piech1
1Faculty of Materials Science and Ceramics, AGH University of Science and Technology, Kraków, Poland

Tóm tắt

Một phương pháp voltammetric cho việc xác định nhanh chóng và nhạy cao Bisphenol A (BPA) đã được phát triển, sử dụng điện cực carbon thủy tinh (GC) được chỉnh sửa bằng hạt nano carbon đen (CB). Nghiên cứu voltammetry tuần hoàn trong dung dịch phosphate 0,1 M với pH = 7,0 đã cho một đỉnh anod duy nhất tại 578 mV. Quá trình oxi hóa BPA kiểm soát bởi hấp phụ được phát hiện là không khả hồi với sự tham gia của hai electron và hai proton. Điện cực CB/GC đề xuất đã cải thiện đáng kể dòng đỉnh oxi hóa của BPA so với điện cực không được chỉnh sửa. Dưới các điều kiện tối ưu, đường chuẩn có dạng tuyến tính trong khoảng nồng độ BPA từ 0,01 đến 3 × 10−6 mol L−1 với giới hạn phát hiện là 3,4 × 10−9 mol L−1. Hơn nữa, phương pháp được đề xuất đã được xác thực thành công bằng cách nghiên cứu khả năng thu hồi BPA trong các mẫu thường có sẵn: giấy nhiệt (biên lai, vé) và bao bì thực phẩm / đồ uống. Bài báo này giới thiệu carbon đen như một vật liệu mới, có triển vọng để chỉnh sửa điện cực được sử dụng trong voltammetry.

Từ khóa

#BPA #điện cực carbon thủy tinh #hạt nano carbon đen #phương pháp voltammetric #bao bì thực phẩm #giấy nhiệt

Tài liệu tham khảo

Bard AJ, Faulkner LR (2001) Electrochemical methods. In: Fundamental and applications, Second edn. John Wiley & Sons, New York Becerr V, Odermatt J (2012) Detection and quantification of traces of bisphenol A and bisphenol S in paper samples using analytical pyrolysis-GC/MS. Analyst 137:2250–2259 Chen Z, Tang C, Zeng Y, Liu H, Yin Z, Li L (2014) Determination of bisphenol A using an electrochemical sensor based on a molecularly imprinted polymer-modified multiwalled carbon nanotube paste electrode. Anal Lett 47:996–1014 Del Olmo M, Zafra A, Navas NA, V′llchez JL (1999) Trace determination of phenol, bisphenol A and bisphenol A diglycidyl ether in mixtures by excitation fluorescence following micro liquid–liquid extraction using partial least squares regression. Analyst 124:385–390 EFSA (2015) Explains the safety of bisphenol A. http://www.efsa.europa.eu/en/topics/factsheets/factsheetbpa150121 Accessed 01 Mar 2016 Frysz CA, Chung DDL (1997) Improving the electrochemical behavior of carbon black and carbon filaments by oxidation. Carbon 35:1111–1127 Geens T, Goeyens L, Kannan K, Neels H, Covaci A (2012) A levels of bisphenol-A in thermal paper receipts from Belgium and estimation of human exposure. Sci Total Environ 435:30–33 Gosser Jr DK (1993) Cyclic voltammetry. Simulation and analysis of reaction mechanisms. VCH Publishers, Inc Goulart LA, Cruz de Moraes F, Mascaro LH (2016) Influence of the different carbon nanotubes on the development of electrochemical sensors for bisphenol A. Mater Sci Eng C 58:768–773 Hormann AM, Vom Saal FS, Nagel SC, Stahlhut RW, Moyer CL, Ellersieck MR, Welshons MV, Toutain PL, Taylor JA (2014) Holding thermal receipt paper and eating food after using hand sanitizer results in high serum bioactive and urine total levels of bisphenol A (BPA). PLoS One 9:1–12. doi:10.1371/journal.pone.0110509 Huang W (2005) Voltammetric determination of bisphenol A using a carbon paste electrode based on the enhancement effect of cetyltrimethylammonium bromide (CTAB). Bull Kor Chem Soc 26:1560–1564 Inoue K, Kato K, Yoshimura Y, Makino T, Nakazawa H (2000) Determination of bisphenol A in human serum by high-performance liquid chromatography with multi-electrode electrochemical detection. J Chromatogr B Biomed Sci Appl 749:17–23 Jing P, Zhang X, Wu Z, Bao L, Xu Y, Liang C, Cao W (2015) Electrochemical sensing of bisphenol A by graphene-1-butyl-3-methylimidazolium hexafluorophosphate modified electrode. Talanta 141:41–46 Jordakova I, Dobias J, Voldrich M, Poustka J (2003) Determination of bisphenol A, bisphenol F, bisphenol A diglycidyl ether and bisphenol F diglycidyl ether migrated from food cans using gas chromatography-mass spectrometry. Czech J Food Sci 21:85–90 Jow JJ, Hsieh LY, Cho HP, Chen HR, Kuo CW (2013) Determination of surface area of carbon-black by simple cyclic-voltammetry measurements in aqueous H2SO4. Ind Eng Chem 19:1730–1734 Laviron E (1974) Adsorption autoinhibition and autocatalysis in polarography and in linear potential sweep voltammetry. J Electroanal Chem 52:355 Li J, Kuang D, Feng Y, Zhang F, Liu M (2011) Voltammetric determination of bisphenol A in food package by a glassy carbon electrode modified with carboxylated multi-walled carbon nanotubes. Microchim Acta 172:379–386 Li Y, Zhai X, Liu X, Wang L, Liu H, Wang H (2016) Electrochemical determination of bisphenol A at ordered mesoporous carbon modified nano-carbon ionic liquid paste electrode. Talanta 148:362–369 Markham DA, Waechter JM Jr, Wimber M, Rao N, Connolly P, Cren JC, Hentges S, Shiotsuka RN, Dimond S, Chappelle AH (2010) Development of a method for the determination of bisphenol A at trace concentrations in human blood and urine and elucidation of factors influencing method accuracy and sensitivity. J Anal Toxicol 34:293–303 Mendum T, Stoler E, Van Benschoten H, Warner JC (2011) Concentration of bisphenol A in thermal paper. Green Chem Lett Rev 2011:481–486 Miller JN, Miller JC (2010) Statistics and chemometrics for analytical chemistry, Sixth edn. Prentice Hall, New York Mirzajani H, Cheng C, Wu J, Chen J, Eda S, Aghdam EN, Ghavifekr HB (2017) A highly sensitive and specific capacitive aptasensor for rapid and label-free trace analysis of Bisphenol A (BPA) in canned foods. Biosens Bioelectron 89:1059–1067 Moraes FC, Silva TA, Cesarino I, Machado SAS (2013) Effect of the surface organization with carbon nanotubes on the electrochemical detection of bisphenol A. Sensor Actuat B-Chem 177:14–18 Najafi M, Khalilzadeh MA, Karimi-Maleh H (2014) A new strategy for determination of bisphenol A in the presence of Sudan I using a ZnO/CNTs/ionic liquid paste electrode in food samples. Food Chem 158:125–131 Nikahd B, Khalilzadeh MA (2016) Liquid phase determination of bisphenol A in food samples using novel nanostructure ionic liquid modified sensor. J Mol Liq 215:253–257 Niu X, Yang W, Wang G, Ren J, Guo H, Gao J (2013) A novel electrochemical sensor of bisphenol A based on stacked graphene nanofibers/gold nanoparticles composite modified glassy carbon electrode. Electrochim Acta 98:167–175 Ntsendwana B, Mamba B, Sampath S, Arotiba OA (2012) Electrochemical detection of bisphenol A using graphene-modified glassy carbon electrode. Int J Electrochem Sci 7:3501–3512 Paczosa-Bator B (2012) All-solid-state selective electrodes using carbon black. Talanta 93:424–427 Rochester JR (2013) Bisphenol A and human health: a review of the literature. Reprod Toxicol 42:132–155 Rykowska I, Wasiak W (2006) Properties, threats, and analysis methods of bisphenol A and its derivatives. Acta Chtomatogr 16:7–27 Santana ER, De Lima CA, Piovesan JV, Spinelli A (2017) An original ferroferric oxide and gold nanoparticles-modified glassycarbon electrode for the determination of bisphenol A. Semsor Actuat B-Chem 240:487–496 Su B, Shao H, Li N, Chen X, Cai Z, Chen X (2017) A sensitive bisphenol A voltammetric sensor relying on AuPd nanoparticles/graphene composites modified glassy carbon electrode. Talanta 166:126–132 Sun Y, Wada M, Kuroda N, Hirayama K, Nakazawa H, Nakashima K (2001) Simultaneous determination of phenolic xenoestrogens by solid-phase extraction and high-performance liquid chromatography with fluorescence detection. Anal Sci 17:697–702 Szymański A, Rykowska I, Wasiak W (2006) Determination of bisphenol A in water and milk by micellar liquid chromatography. Acta Chromatogr 17:161–172 Takahashi Y, Shirai A, Segawa T, Takahashi T, Sakakibara K (2002) Why does a color developing phenomenon occur on thermal paper comprising of a fluoran dye and a color developer molecule. Bull Chem Soc Jpn 75:2225–2231. doi:10.1246/bcsj.75.2225 Tu X, Yan L, Luo X, Luo S, Xieb O (2009) Electroanalysis of bisphenol A at a multiwalled carbon nanotubes-gold nanoparticles modified glassy carbon electrode. Electroanalysis 21:2491–2494 Vandenberg NL, Maffini MV, Sonnenschein C, Rubin BS, Soto AM (2009) Bisphenol-A and the great divide: a review of controversies in the field of endocrine disruption. Endocr Rev 30:75–95 Wang J (2000) Analytical electrochemistry, Second edn. John Wiley & Sons, New York Wang A, Wei Y, Wang C (2015) Study on the Electrocatalytic oxidation of bisphenol A on Au nanoparticles/carbon nanotubes composite modified electrode. J Anal Chem 70:67–71 Wang Q, Zhu L, Chen M, Ma X, Wang X, Xia J (2017) Simultaneously determination of bisphenol A and its alternatives in sediment by ultrasound-assisted and solid phase extractions followed by derivatization using GC-MS. Chemosphere 169:709–715 Watabe Y, Kondo T, Morita M, Tanaka N, Hosoya K, Haginaka J (2004) Determination of bisphenol A in environmental water at ultra-low level by high-performance liquid chromatography with an effective on-line pretreatment device. J Chromatogr A 1032:45–49 Watabe Y, Kondo T, Morita M, Tanaka N, Hosoya K, Kubo T (2005) LC/MS determination of bisphenol A in river water using a surface-modified molecularly-imprinted polymer as an on-line pretreatment device. Anal Bioanal Chem 381:1193–1198 Wu X, Li Y, Zhu X, He C, Wang Q, Liu S (2017) Dummy molecularly imprinted magnetic nanoparticles for dispersive solidphase extraction and determination of bisphenol A in water samples and orange juice. Talanta 162:57–64 Zhou Q, Wang G, Xie G (2014) Preconcentration and determination of bisphenol A, naphthol and dinitrophenol from environmental water samples by dispersive liquid-phase microextraction and HPLC. Anal Methods 6:187–193 Wang Q, Wang Y, Liu S, Wang L, Gao F, Sun W (2012) Voltammetric detection of bisphenol a by a chitosan–graphene composite modified carbon ionic liquid electrode. Thin Solid Films 520:4459–4464