Fast formation of NaA zeolite membrane in the microwave field

Science China Press., Co. Ltd. - Tập 45 - Trang 1179-1181 - 2000
Xiaochun Xu1, Weishen Yang1, Jie Liu1, Liwu Lin1
1State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, China

Tóm tắt

NaA zeolite membrane was successfully synthesized on the porous α-Al2O3 support by microwave heating. The synthesis of NaA zeolite membrane in the microwave field only needs 15 min and the synthesis time is 10 times shorter than that by conventional heating. SEM characterization indicates that the zeolite crystals in the NaA zeolite membrane synthesized by microwave heating are uniform in size; the membrane thickness is about 4 μm and is thinner than that of the NaA zeolite membrane synthesized by conventional heating. Gas permeation studies indicate that the permeances of the NaA zeolite membrane synthesized by microwave heating are 3–4 times higher than those of the NaA zeolite membrane synthesized by conventional heating, while their permselectivities are comparable.

Tài liệu tham khảo

Lu, M. W., Hu, W. X., Yun, L. H., The progress in the organic microwave chemistry, Youji Huaxue (Organic Chemistry, in Chinese), 1995, 15: 561. Strauss, C. R., Trainor, R. W., Developments in microwave assisted organic chemistry, Aust. J. Chem., 1995, 48: 1165. Chu, P., Dwyer, F. G., Clark, V. J., Crystallization of zeolites using microwave radiation, Eur. Pat., 1990, 358 827. Arafat, A., Jansen, J. C., Ebaid, A. R. et al., Microwave preparation of zeolite Y and ZSM-5 zeolite, Zeolites, 1993, 13: 162. Du, H. B., Fang, M., Xu, W., Preparation by microwave irradiation of nanometre-sized ALPO4-5 molecular sieve, J. Mater. Chem., 1997.7: 551. Wu, C. G., Bein, T., Microwave synthesis of molecular sieve MCM-41, Chem. Commun., 1996: 925. Tsai, T. G., Shin, H. C., Liao, S. J. et al., Well-aligned SAPO-5 membrane: preparation and characterization, Microporous and Mesoporous Mater., 1998, 22: 333. Mintova, S., Mo, S., Bein, T., Nanosized AlPO4-5 molecular sieves and ultrathin films prepared by microwave synthesis, Chem. Mater., 1998, 10: 4030. Xu, X. C., Liu, J., Fang, L. Q. et al., Synthesis of NaA zeolite membrane from clear solution and its gas permeation properties, Chinese J. Catal., 1999, 20: 396. Xu, X. C., Cheng, M. J., Yang, W. S. et al., Synthesis and gas permeation properties of Silicalite-1 zeolite membrane, Science in China, Ser. B, 1998, 41: 325.