Electrophilic and nucleophilic aromatic substitution: Analogous and complementary processes

Springer Science and Business Media LLC - Tập 45 - Trang 491-504 - 1996
M. Mąkosza1
1Institute of Organic Chemistry, Polish Academy of Sciences, Warsaw, Poland

Tóm tắt

Analysis of many variants of nucleophilic aromatic substitution of hydrogen proceeding according to an addition—elimination pattern reveals that this is the major reaction pathway, whereas nucleophilic replacement of halogen or another nucleofugal group is the secondary process, i.e.,ipso-substitution. In this respect electrophilic and nucleophilic aromatic substitution can be considered as analogous processes.

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