Effect of citric acid concentration as emulsifier on perovskite phase formation of nano‐sized SrMnO3 and SrCoO3 samples

Crystal Research and Technology - Tập 45 Số 10 - Trang 1064-1068 - 2010
Mohammad Khazaei1, Azadeh Malekzadeh Shafaroudi, Fariba Amini1, Yadollah Mortazavi2, Abbas Ali Khodadadi2
1School of Chemistry, Damghan University, Damghan, Iran
2Catalysis and Nanostructured Materials Research Laboratory, School of Chemical Engineering, University of Tehran, Tehran, Iran.

Tóm tắt

AbstractIn this study the effects of citric acid concentration, used as organic emulsifier, on the perovskite phase formation of the nano strontium manganite or cobaltite samples were studied. Stoichiometric perovskites in the absence and presence of citric acid were prepared by drying a solution containing molar ratio of Sr(NO3)2/Mn(NO3)2·4H2O and Sr(NO3)2/Co(NO3)2·6H2O = 1 followed by calcination at 900 °C for 5 h. Citric acid concentration, selected to be 0.0, 0.3, 0.6, 1.0, 1.3, 2.5 and 5 times of the total number of moles of the nitrate ions. The results revealed that increase in the citric acid concentration, larger than number of moles of the nitrate ions equivalent, deteriorates the perovskite phase formation. Instead, a new phase of carbonates and metal oxides are appeared. (© 2010 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim)

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Tài liệu tham khảo

10.1002/crat.200610807

10.1007/s10853-005-6961-x

10.1103/PhysRevB.72.172407

10.1006/jssc.1995.1035

10.1016/S0022-3697(01)00198-6

10.1007/BF00277987

10.1063/1.1455690

10.1111/j.1151-2916.1992.tb05465.x

10.1111/j.1151-2916.1997.tb03178.x

Duprat A. M., 1994, Chem. Phys., 37, 76

10.1557/JMR.1998.0101

10.1111/j.1151-2916.1984.tb19720.x

10.1016/0166-6622(90)80219-T

10.1016/S0272-8842(03)00069-5

10.1016/j.jssc.2005.03.006

10.1016/0032-5910(73)80005-1

10.1246/cl.1987.665

Abadian L., 2008, Iran. J. Chem. Chem. Eng., 27, 71

10.1002/crat.200711117

10.1016/j.materresbull.2008.09.009

10.5539/mas.v3n4p177

10.1016/j.matchemphys.2007.12.008

10.1016/0254-0584(94)01468-V

10.1016/j.jssc.2004.04.003

10.1016/j.matlet.2007.10.056

10.1063/1.2345036

10.1016/j.catcom.2007.05.047

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Thông tin xuất bản

Crystal Research and Technology

Tập 45 Số 10

1064-1068

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