Deacylation of aromatic acylamino compounds having a nitro group in the ortho or para position. Steric hindrance of resonance

Wiley - Tập 62 Số 8 - Trang 523-530 - 1943
P. H. Witjens, B. M. Wepster, P. E. Verkade

Tóm tắt

AbstractThe work on the deacylation of aromatic acylamino compounds having a nitro group in the ortho or para position, in alcoholic medium under the influence of sodium alcoholate as a catalyst was continued. In this reaction the ‐E‐effect of the nitro group, the tendency toward electromerization of the o‐ or p‐nitrophenylamino grouping plays a predominant part. Typical cases of steric hindrance of resonance could consequently be ascertained with the help of this reaction.

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Tài liệu tham khảo

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