Comparison and interpretation of isotherm models for the adsorption of dyes, proteins, antibiotics, pesticides and heavy metal ions on different nanomaterials and non-nano materials—a comprehensive review

Journal of Nanostructure in Chemistry - Tập 13 - Trang 43-65 - 2022
Mostafa Rajabi1,2, Shadi Keihankhadiv3, Suhas4, Inderjeet Tyagi5, Rama Rao Karri6, Monika Chaudhary4, Nabisab Mujawar Mubarak6, Shubham Chaudhary4, Praveen Kumar7, Pratibha Singh8
1Young Researchers and Elite Club, East Tehran Branch, Islamic Azad University, Tehran, Iran
2Department of Chemistry, Faculty of Science, Arak Branch, Islamic Azad University, Arak, Iran
3Department of Physical Chemistry and Technology of Polymers, Faculty of Chemistry, Silesian University of Technology, Gliwice, Poland
4Department of Chemistry, Gurukula Kangri (Deemed to be University), Haridwar, India
5Centre for DNA Taxonomy, Molecular Systematics Division, Zoological Survey of India, Kolkata, India
6Petroleum and Chemical Engineering, Faculty of Engineering, Universiti Teknologi Brunei, Mukim Gadong, Brunei
7Faculty of Chemistry and Chemical Technology, University of Ljubljana, Ljubljana, Slovenia
8Department of Chemistry, University of Delhi, Delhi, India

Tóm tắt

Adsorption is most commonly applied in water treatment, gas purification/separation, catalysis, etc. It is a very simple and inexpensive technique. However, the performance depends on the type of adsorbent and its dosage. Researchers across the world keep seeking low-cost and more effective adsorbents. As a result, millions of research publications on adsorption have been published yearly. Most of these publications report the synthesis of new adsorbents from various sources and their application in the remediation of several inorganic and organic pollutants from water bodies. Researchers attempt to fit their experimental results with various isotherm models to understand the adsorption mechanism. Some researchers fit data into linear isotherm models, while others add non-linear isotherm models for estimating the isotherm parameters. The fit of isotherm models differs for various adsorbents and contaminants. The present paper is comprehensive review compiling information on isotherm models that explain the intrinsic mechanisms of adsorptive removal of pollutants such as antibiotics, dyes, proteins, pesticides and heavy metal ions. Furthermore, a detailed characteristic property of numerous cationic dyes, anionic dyes, proteins, antibiotics, pesticides and heavy metal ions was also discussed. It is observed that based on the literature reviewed, it was found that the adsorption equilibrium data of cationic dyes and anionic dyes were well defined with the Langmuir model. Additionally, in the case of the adsorption of proteins, antibiotics and heavy metal ions, the Langmuir model is well matched among all applications.

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Thông tin xuất bản

Journal of Nanostructure in Chemistry

Tập 13

43-65

Thông tin tác giả