Circular dichroism spectra of synthetic amethyst crystals

Crystallography Reports - Tập 50 - Trang 461-464 - 2005
V. I. Burkov1, A. V. Egorysheva2, Yu. F. Kargin2, A. A. Mar’in3, E. V. Fedotov1
1Moscow Institute of Engineering Physics, Moscow, Russia
2Kurnakov Institute of General and Inorganic Chemistry, Russian Academy of Sciences, Moscow, Russia
3All-Russia Research Institute for Synthesis of Mineral Raw Materials, Aleksandrov, Moscow oblast, Russia

Tóm tắt

The axial circular-dichroism spectrum of a synthetic amethyst crystal has been studied for the first time. Bands both of the positive and negative signs are revealed. New information on the color centers of amethyst and their electronic structure is obtained.

Tài liệu tham khảo

V. S. Balitskii, V. E. Khadzhi, B. A. Dorogovin, et al., Synthesis of Minerals (VNIISIMS, Aleksandrov, 2000), Vol. 1. G. R. Rossman, Rev. Mineral. 29, 433 (1994). G. Lehmann, Z. Naturforch. A 22(12), 2080 (1967). R. T. Cox, J. Phys. C: Solid State Phys. 9, 3355 (1976). R. T. Cox, J. Phys. C: Solid State Phys. 10(22), 4631 (1977). V. I. Burkov, A. V. Egorysheva, and Yu. F. Kargin, Zh. Neorg. Khim. 48(4), 620 (2003). G. Cressey, C. M. B. Henderson, and G. van der Lann, Phys. Chem. Mineral. 20, 111 (1993). M. F. Vereshchak, A. K. Zhetbaev, D. K. Kaipov, and K. K. Satpaev, Fiz. Tverd. Tela (Leningrad) 14(10), 3082 (1972) [Sov. Phys. Solid State 14, 2638 (1972)]. C. Frondel, The System of Mineralogy, 7th ed. (Wiley, New York, 1962), Vol. 3. N. M. Melankholin and L. I. Tsinober, Kristallografiya 7(1), 110 (1963) [Sov. Phys. Crystallogr. 7, 97 (1963)]. T. I. Barry, P. McNamara, and W. J. Moore, J. Chem. Phys. 42(7), 2599 (1965). S. Pancharatnam, Proc. Indian Acad. Sci., Sect. A 40(6), 196 (1954). L. G. Chentsova, L. I. Tsinober, and M. I. Samoilovich, Kristallografiya 11(2), 236 (1966) [Sov. Phys. Crystallogr. 11, 219 (1966)]. A. Lever, Inorganic Electronic Spectroscopy (Elsevier, Amsterdam, 1984; Mir, Moscow, 1987), Part 1. L. E. Halliburton, L. A. Kappers, A. F. Armington, and J. Larkin, J. Appl. Phys. 51(4), 2193 (1980). V. A. Kizel’ and V. I. Burkov, Crystal Gyrotropy (Nauka, Moscow, 1980) [in Russian].