Bioethanol dehydration: State of the art

Theoretical Foundations of Chemical Engineering - Tập 44 - Trang 545-556 - 2010
A. K. Frolkova1, V. M. Raeva1
1Moscow State Academy of Fine Chemical Technology, Moscow, Russia

Tóm tắt

This article is a survey of the present-day methods of dehydration of ethanol resulting from fermentation processes. The existing separation techniques for water-ethanol mixtures of various compositions are compared, and the conditions under which each particular technique is preferable are formulated.

Tài liệu tham khảo

Tsarev, A.V., Balabin, R.M., Karpov, S.A., and Syunyaev, R.Z., Optimization of the Performance and Environmental Properties of Ethanol-Gasoline Fuels Using Microwave Treatment, Alternat. Energet. Ekol., 2007, vol. 52, no. 8, pp. 69–74.

Wasewar, K.L. and Pangarkar, V.G., Intensification of Recovery of Ethanol from Fermentation Broth Using Pervaporation: Economical Evaluation, Chem. Biochem. Eng. Q., 2006, vol. 20, no. 2, pp. 135–145.

www.abercade.ru/research/analysis/425.html, www.e-vid.ru/index-m-192-p-63-article-17596.htm

Serafimov, L.A. and Frolkova, A.K., Fundamental Principle of Concentration-Field Redistribution between Separation Regions as a Basis for the Design of Technological Systems, Teor. Osn. Khim. Tekhnol., 1997, vol. 31, no. 2, pp. 193–201 [Theor. Found. Chem. Eng. (Engl. Transl.), vol. 31, no. 2, pp. 159–166].

Frolkova, A.K., Theoretical Foundations of Multicomponent Multiphase Separation Using Functional Complexes, Doctoral (Eng.) Dissertation, Moscow: Moscow Inst. of Fine Chemical Technology, 2000.

Polyakov, A.M., Some Aspects of the Pervaporation Separation of Liquid Mixtures, Krit. Tekhnol. Membr., 2004, vol. 24, no. 4, pp. 29–44.

Makarov, V.V. Petrykin, A.A., Skvortsov, E.A., et al., RF Patent 2?265?473, Byull. Izobret., 2005, no. 34.

Ladisch, M.R., Voloch, M., Hong, J., et al., Cornmeal Adsorber for Dehydrating Ethanol Vapors, Ind. Eng. Chem. Proc. Des. Dev., 1983, vol. 23, pp. 437–445.

www.ethanolindia.net/molecular-sieves.html,vasatwiki.icrisat.org/index.php/Grain-alcohol#Purification

Knez, Z., Skerget, M., Ilic, L., and Liitge, C., VaporLiquid Equilibrium of CO2-Organic Binary Solvent Systems (Ethanol, Tetrahydrofuran, ortho-Xylene, meta-Xylene, para-Xylene), J. Supercrit. Fluids, 2008, vol. 43, no. 3, pp. 383–389.

Giivenc, A., Mehmetoglu, U., and Calimi, A., Supercritical Extraction of Ethanol, Turk. J. Chem., 1999, vol. 33, pp. 285–291.

L’vov, S.V., Nekotorye voprosy rektifikatsii binarnykh i mnogokomponentnykh smesei (Topics in the Distillation of Binary and Multicomponent Mixtures), Moscow: Akad. Nauk SSSR, 1960.

www.chemsite.ru/abstract-25040.htm

Timofeev, V.S. and Serafimov, L.A., Printsipy tekhnologii osnovnogo organicheskogo i neftekhimicheskogo sinteza (Principles of Basic Organic and Petrochemical Synthesis Technology), Moscow: Vysshaya Shkola, 2003.

Kogan, V.B., Azeotropnaya i ekstraktivnaya rektifikatsiya (Azeotropic and Extractive Distillation), Leningrad: Khimiya, 1971.

Brito, R.R., Maciel, M.R.W., and Meirelles, A.A., New Extractive Distillation Configuration for Separating Binary Azeotropic Mixtures, The First European Congress on Chemical Engineering, Florence, Italy, 1997, vol. 2, pp. 1333–1336.

Anokhina, E., Grigorieva, A., and Timoshenko, A., Ethanol Dehydration in the Complex Column with Refining Side Section, Proc. 35th Int. Conf. of Slovak Society of Chemical Engineering, Tatranske Matliare, Slovakia, 2008, p. 171.

Simoni, L.D., Lin, Y., Brennecke, J.F., and Stadtherr, M.A., Modeling Liquid-Liquid Equilibrium of Ionic Liquid Systems with NRTL, Electrolyte-NRTL, and UNIQUAC, Ind. Eng. Chem. Res., 2008, vol. 47, no. 1, pp. 256–272.

Hilmen, E.-K., Separation of Azeotropic Mixtures: Tools for Analysis and Studies on Batch Distillation Operation, Thesis Submitted for the Degree of Dr. Eng., Norwegian University of Science and Technology, Department of Chemical Engineering, 2001.

Zielinski, L., Bioethanol Dehydration in Pressure Swing Adsorption Proces, www.msuil.ru/unesco.forum.doc1/17doc

Kafarov, V.V., Gordeev, L.S., and Glebov, M.B., Separation of Azeotropic Mixtures in Membrane-Rectification Processes, Teor. Osn. Khim. Tekhnol., 1996, vol. 30, no. 2, pp. 180–187 [Theor. Found. Chem. Eng. (Engl. Transl.), vol. 30, no. 2, pp. 160–167].

Bologa, M.K. and Maksimuk, E.P., Recovery of Process Liquids in an Electric Field, Int. Conf. Fizikar 2005, Baku, 2005, no. 114, p. 430.