Anthropogenic dissolved and colloid/nanoparticle-bound samarium, lanthanum and gadolinium in the Rhine River and the impending destruction of the natural rare earth element distribution in rivers

Bau, 1996, Controls on the fractionation of isovalent trace elements in magmatic and aqueous systems: evidence from Y/Ho, Zr/Hf, and lanthanide tetrad effect, Contrib. Mineral. Petrol., V123, 323, 10.1007/s004100050159

Bau, 1996, Anthropogenic origin of positive gadolinium anomalies in river waters, Earth Planet. Sci. Lett., 143, 245, 10.1016/0012-821X(96)00127-6

Bau, 2006, Anthropogenic gadolinium as a micropollutant in river waters in Pennsylvania and in Lake Erie, northeastern United States, Chem. Erde, 66, 143, 10.1016/j.chemer.2006.01.002

Bruce, 1963, The acute mammalian toxicity of rare earth nitrates and oxides, Toxicol. Appl. Pharmacol, 5, 750, 10.1016/0041-008X(63)90067-X

Chen, 2003, Experimental study of subchronic toxicity of lanthanum nitrate on liver in rats, Nonlinearity Biol. Toxicol. Med., 1, 469, 10.1080/15401420390271074

Elbaz-Poulichet, 2002, Occurrence of an anthropogenic gadolinium anomaly in river and coastal waters of Southern France, Water Res., 36, 1102, 10.1016/S0043-1354(01)00370-0

Elderfield, 1990, The rare earth elements in rivers, estuaries, and coastal seas and their significance to the composition of ocean waters, Geochim. Cosmochim. Acta, 54, 971, 10.1016/0016-7037(90)90432-K

Emsley, 2011

Gaillardet, 2003, Trace elements in river waters, 225

Girard, 1980, Divalent lanthanide derivatives in organic synthesis. 1. Mild preparation of samarium iodide and ytterbium iodide and their use as reducing or coupling agents, J. Am. Chem. Soc., 102, 2693, 10.1021/ja00528a029

Haley, 1964, Pharmacology and toxicology of lutetium chloride, J. Pharm. Sci., 53, 1186, 10.1002/jps.2600531011

Haley, 1963, Pharmacology and toxicology of terbium, thulium, and ytterbium chlorides, Toxicol. Appl. Pharmacol., 5, 427, 10.1016/0041-008X(63)90014-0

Haley, 1964, Pharmacology and toxicology of praseodymium and neodymium chlorides, Toxicol. Appl. Pharmacol., 6, 614, 10.1016/0041-008X(64)90094-8

Haley, 1966, Pharmacology and toxicology of dysprosium, holmium, and erbium chlorides, Toxicol. Appl. Pharmacol., 8, 37, 10.1016/0041-008X(66)90098-6

Haley, 1961, Toxicological and pharmacological effects of gadolinium and samarium chlorides, Br. J. Pharmcol. Chemother., 17, 526, 10.1111/j.1476-5381.1961.tb01139.x

Hammond, 2011, The elements

Humphries, M., 2011. Rare Earth Elements: The Global Supply Chain. CRS Report for Congress R41347. Congressional Research Service, Washington DC. 〈http://www.fas.org/sgp/crs/natsec/R41347.pdf〉 (accessed 31.10.12).

Knappe, 2005, Positive gadolinium anomaly in surface water and ground water of the urban area Berlin, Germany, Chem. Erde, 65, 167, 10.1016/j.chemer.2004.08.004

Kulaksız, 2007, Contrasting behaviour of anthropogenic gadolinium and natural rare earth elements in estuaries and the gadolinium input into the North Sea, Earth Planet. Sci. Lett., 260, 361, 10.1016/j.epsl.2007.06.016

Kulaksız, 2011, Rare earth elements in the Rhine River, Germany: first case of anthropogenic lanthanum as a dissolved microcontaminant in the hydrosphere, Environ. Int., 37, 973, 10.1016/j.envint.2011.02.018

Kulaksız, 2011, Anthropogenic gadolinium as a microcontaminant in tap water used as drinking water in urban areas and megacities, Appl. Geochem., 26, 1877, 10.1016/j.apgeochem.2011.06.011

Künnemeyer, 2009, Speciation analysis of gadolinium chelates in hospital effluents and wastewater treatment plant sewage by a novel HILIC/ICP-MS method, Environ. Sci. Technol., 43, 2884, 10.1021/es803278n

Lawrence, 2010, Detection of anthropogenic gadolinium in the Brisbane River plume in Moreton Bay, Queensland, Australia, Mar. Pollut. Bull., 60, 1113, 10.1016/j.marpolbul.2010.03.027

Lawrence, 2006, Aquatic geochemistry of the rare earth elements and yttrium in the Pioneer River catchment, Australia, Mar. Freshwater Res., 57, 725, 10.1071/MF05229

Lawrence, 2007, Rare earth element concentrations in the Natural Water Reference Materials (NRCC) NASS-5, CASS-4 and SLEW-3, Geostand. Geoanal. Res., 31, 95, 10.1111/j.1751-908X.2007.00850.x

McLennan, 1989, Rare earth elements in sedimentary rocks; influence of provenance and sedimentary processes, Rev. Mineral. Geochem., 21, 169

Möller, 2000, Anthropogenic gadolinium as a conservative tracer in hydrology, J. Geochem. Explor., 69–70, 409, 10.1016/S0375-6742(00)00083-2

Möller, 2003, Anomalous gadolinium, cerium, and yttrium contents in the Adige and Isarco river waters and in the water of their tributaries (Provinces Trento and Bolzano/Bozen, NE Italy), Acta Hydrochim. Hydrobiol., 31, 225, 10.1002/aheh.200300492

Möller, 2002, Anthropogenic Gd in surface water, drainage system, and the water supply of the city of Prague, Czech Republic, Environ. Sci. Technol., 36, 2387, 10.1021/es010235q

Morteani, 2006, Input and fate of anthropogenic estrogens and gadolinium in surface water and sewage plants in the hydrological basin of Prague (Czech Republic), Environ. Geochem. Health, 28, 257, 10.1007/s10653-006-9040-6

Nozaki, 2000, Dissolved indium and rare earth elements in three Japanese rivers and Tokyo Bay: evidence for anthropogenic Gd and In, Geochim. Cosmochim. Acta, 64, 3975, 10.1016/S0016-7037(00)00472-5

Petelet-Giraud, 2009, Natural versus anthropogenic sources in the surface- and groundwater dissolved load of the Dommel river (Meuse basin): constraints by boron and strontium isotopes and gadolinium anomaly, J. Hydrol., 369, 336, 10.1016/j.jhydrol.2009.02.029

Rabiet, 2005, Deciphering the presence of wastewater in a medium-sized Mediterranean catchment using a multitracer approach, Appl. Geochem., 20, 1587, 10.1016/j.apgeochem.2005.04.005

Rabiet, 2009, Positive gadolinium anomalies in wastewater treatment plant effluents and aquatic environment in the Herault watershed (South France), Chemosphere, 75, 1057, 10.1016/j.chemosphere.2009.01.036

Schlosser, 2008, Application of cross-flow filtration for determining the solubility of iron species in open ocean seawater, Limnol. Oceanogr. Methods, 6, 630, 10.4319/lom.2008.6.630

Shi, 2006, Effects of samarium on liver and kidney of rats, J. Rare Earths, 24, 415, 10.1016/S1002-0721(07)60416-5

Shi, 2006, Influence of samarium on learning and memory function of rats, J. Rare Earths, 24, 419, 10.1016/S1002-0721(07)60417-7

Sholkovitz, 1992, Chemical evolution of rare earth elements: fractionation between colloidal and solution phases of filtered river water, Earth Planet. Sci. Lett., 114, 77, 10.1016/0012-821X(92)90152-L

Sholkovitz, 1995, The aquatic chemistry of rare earth elements in rivers and estuaries, Aquat. Geochem., 1, 1, 10.1007/BF01025229

Sun, 1996, Bioconcentration and elimination of five light rare earth elements in carp (Cyprinus carpio L.), Chemosphere, 33, 1475, 10.1016/0045-6535(96)00286-X

Tricca, 1999, Rare earth elements and Sr and Nd isotopic compositions of dissolved and suspended loads from small river systems in the Vosges mountains (France), the river Rhine and groundwater, Chem. Geol., 160, 139, 10.1016/S0009-2541(99)00065-0

Verheul, M., Klaver, G., Bakker, I., Petelet-Giraud, E, 2011. The Distribution of the Lanthanum Anomaly in the Dutch Branches of the Rhine River. Abstract H41H-1151 Presented at 2011 Fall Meeting, 5–9 December, AGU, San Francisco, California.

Verplanck, 2005, Aqueous stability of gadolinium in surface waters receiving sewage treatment plant effluent, Boulder Creek, Colorado, Environ. Sci. Technol., 39, 6923, 10.1021/es048456u

Weiss, 1975, Interactions between several rare-earth ions and calcium-ion in vascular smooth-muscle, J. Pharmacol. Exp. Ther., 195, 557

Zhang, 2010, Ecotoxicological assessment of lanthanum with Caenorhabditis elegans in liquid medium, Metallomics, 2, 806, 10.1039/c0mt00059k

Zhu, 2005, Fractional distributions of trace metals in surface water of Lake Biwa as studied by ultrafiltration and ICP-MS, Bull. Chem. Soc. Jpn., 78, 1970, 10.1246/bcsj.78.1970

Zhu, 2004, Gadolinium anomaly in the distributions of rare earth elements observed for coastal seawater and river waters around Nagoya City, Bull. Chem. Soc. Jpn., 77, 1835, 10.1246/bcsj.77.1835