13C NMR spectra of 8‐aryl‐8‐azabicyclo[3.2.1]oct‐3‐en‐2‐ones and related compounds

Wiley - Tập 12 Số 6 - Trang 357-361 - 1979
Alan R. Katritzky1, N. DENNIS1, Gebran J. Sabongi1
1School of Chemical Sciences, University of East Anglia, Norwich NR4 7TJ, UK

Tóm tắt

AbstractCarbon‐13 NMR spectra of various 8‐aryl‐8‐azabicyclo[3.2.1]oct‐3‐en‐2‐ones and other related compounds, including tropinone, were determined, and the predominant conformation at the bridgehead nitrogen was established. The full assignment of resonances from proton decoupled and coupled spectra was based on the analysis of the splitting pattern and characteristic chemical shifts. The use of the determined 13C NMR spectra in the assignment of 13C NMR data in related but more complicated structures is also proposed.

Từ khóa


Tài liệu tham khảo

10.1002/anie.197600011

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Ebel H. F., 1974, Monographs in Modern Chemistry, 154

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Thông tin
Thông tin xuất bản

Wiley

Tập 12 Số 6

357-361

Thông tin tác giả